Helioseismic ring analysis of CME source regions

We apply the ring diagram technique to source regions of halo coronal mass ejections (CMEs) to study changes in acoustic mode parameters before, during, and after the onset of CMEs. We find that CME regions associated with a low value of magnetic flux have line widths smaller than the quiet regions, implying a longer life-time for the oscillation modes. We suggest that this criterion may be used to forecast the active regions which may trigger CMEs.     

台湾-阿尔泰地学断面阿尔金-龙门山剖面的地壳纵波速度结构

通过分析阿尔金—龙门山地学断面的地震资料,建立了该剖面的地壳纵波速度结构。研究结果表明,阿尔金北侧的塔里木盆地地区莫霍面为50km,而在其南侧的祁连地块莫霍面突然加深至73km,在柴达木盆地莫霍面又抬升至58km左右,然后,在松潘甘孜地块莫霍面降至70km,并呈现为台阶状向龙门山方向抬升到60km左右,最低速层,而在其南部地区则没有低速层出现,推测低速层为地壳中部的局部熔融物质,阿尔金—龙门山剖面上的两个莫霍面坳陷区分别与祁连地块和松潘—甘孜地块上的两个莫霍面坳陷区相对应,指示出这个两个地块具有较深的山根,青藏高原北部的巨厚地壳很可能是由于中生代以来发生的印度板块与亚洲板块碰撞时受到来自东西及南北方向的挤压,使地壳缩短所致。     

Reassessing the invasion of South African waters by the European shore-crab Carcinus maenas

The European shore-crab Carcinus maenas has been present in South Africa since 1983. Despite this species’ international reputation as a biological invader, its distribution in this region has only been considered by three outdated ‘snapshot surveys.’ The present study is the most comprehensive to date, providing an update on the species’ range and the first temporal assessment of its abundance and demographics. Along South Africa's Cape Peninsula and surrounding areas, C. maenas was absent from 12 intertidal sites surveyed, except for Sea Point, and no crabs were found during subtidal surveys along the open coastline. Subtidal harbour populations were recorded in the Cape Town harbours of Table Bay and Hout Bay (previously estimated as comprising approximately 164 200 and 6 500 individuals, respectively). Table Bay was surveyed monthly for one year, using baited traps, crab condos and postlarvae settlement collectors, to assess size distributions and reproductive seasonality of the crab. Reproductive females were recorded throughout most of the year. These results suggest that the harbour populations could be targeted by control programmes, but provide no strong evidence to support the initiation of management action during a particular season. The lack of detection of postlarval settlement, even among well-established populations, suggests this will not be a useful monitoring tool for detecting incursions.     

Iceberg discharge to the Chukchi shelf during the Younger Dryas

The extent of glaciation in northwestern Alaska, the source of sediment supply to the Chukchi shelf and slope, and the movement of sea ice and icebergs across the shelf during the last glacial maximum (LGM) remain poorly constrained. Here we present geophysical and geological data from the outer Chukchi margin that reveal a regionally extensive, heavily ice-scoured surface ∼ 5-8 m below the modern seafloor. Radiocarbon dating of this discrete event yields age estimates between 10,600 and 11,900 ¹⁴C yr BP, indicating the discharge event occurred during the Younger Dryas. Based on mineralogy of the ice-rafted debris, the icebergs appear to be sourced from the northwestern Alaskan margin, which places important constraints on the ice extent in northern Alaska during the LGM as well as existing circulation models for the region.     

Biogeochemical sampling for mineral exploration in arid terrains: Tanami Gold Province,Australia

Vegetation sampling is an effective mineral exploration technique in areas of transported cover in the Tanami Gold Province where other techniques have been of limited success. This research tests the ability of plants to show signatures of mineralisation as well as the optimum scale of sampling for first-pass mineral exploration surveys. The semi-arid Tanami Gold Province in northern Australia encompasses nearly 160,000 km² and is a highly prospective yet under-explored region due to transported cover masking mineralisation. Various dominant plant species were sampled along transects across four sites of Au mineralisation in the Tanami (Larranganni, Hyperion, Coyote and Titania). Snappy gum (Eucalyptus brevifolia) gave a geobotanical (plant distribution) and lithological (S and Zn) signature of an underlying geological structure known to host Au mineralisation at the Coyote Prospect. Soft spinifex (Triodia pungens) provided an Au, As, ± Zn, ± S, and ± Ce expression of buried Au mineralisation at Coyote and Titania. At the Hyperion prospect, mineralisation is located at the contact between granite and dolerite, and biogeochemical signatures from snappy gum and dogwood (Acacia coriacea) show elevated ± Au, Ce, S and Zn that corresponded to the contact. Biogeochemistry is able to determine the location of mineralisation at each site, except at Hyperion where the sample density was too low. It is able to identify underlying substrate differences, however, background knowledge relating to regolith, geology, hydrology and geophysics are important in aiding the interpretation of the elemental data. It was found that having too few samples (at Hyperion) there was insufficient useful information for mineral exploration. Grid coverage of an area (at Titania) provided information on mineralisation and groundwater dispersion plumes; however, in this case a single transect over the same area would have been sufficient for a first-pass mineral exploration survey.     

Effects of changing solution chemistry on Fe/Fe isotope fractionation in aqueous Fe-Cl solutions

The range in ⁵⁶Fe/⁵⁴Fe isotopic compositions measured in naturally occurring iron-bearing species is greater than 5‰. Both theoretical modeling and experimental studies of equilibrium isotopic fractionation among iron-bearing species have shown that significant fractionations can be caused by differences in oxidation state (i.e., redox effects in the environment) as well as by bond partner and coordination number (i.e., nonredox effects due to speciation).To test the relative effects of redox vs. nonredox attributes on total Fe equilibrium isotopic fractionation, we measured changes, both experimentally and theoretically, in the isotopic composition of an Fe²⁺-Fe³⁺-Cl-H₂O solution as the chlorinity was varied. We made use of the unique solubility of FeCl₄⁻ in immiscible diethyl ether to create a separate spectator phase against which changes in the aqueous phase could be quantified. Our experiments showed a reduction in the redox isotopic fractionation between Fe²⁺- and Fe³⁺-bearing species from 3.4‰ at [Cl⁻] = 1.5 M to 2.4‰ at [Cl⁻] = 5.0 M, due to changes in speciation in the Fe-Cl solution. This experimental design was also used to demonstrate the attainment of isotopic equilibrium between the two phases, using a ⁵⁴Fe spike.To better understand speciation effects on redox fractionation, we created four new sets of ab initio models of the ferrous chloride complexes used in the experiments. These were combined with corresponding ab initio models for the ferric chloride complexes from previous work. At 20 °C, 1000 ln β (β = ⁵⁶Fe/⁵⁴Fe reduced partition function ratio relative to a dissociated Fe atom) values range from 6.39‰ to 5.42‰ for Fe(H₂O)₆²⁺, 5.98‰ to 5.34‰ for FeCl(H₂O)₅⁺, and 5.91‰ to 4.86‰ for FeCl₂(H₂O)₄, depending on the model. The theoretical models predict ferric-ferrous fractionation about half as large (depending on model) as the experimental results.Our results show (1) oxidation state is likely to be the dominant factor controlling equilibrium Fe isotope fractionation in solution and (2) nonredox attributes (such as ligands present in the aqueous solution, speciation and relative abundances, and ionic strength of the solution) can also have significant effects. Changes in the isotopic composition of an Fe-bearing solution will influence the resultant Fe isotopic signature of any precipitates.     

Komatiites and nickel sulfide ores of the Black Swan area,Yilgarn Craton,Western Australia. 2: Geology and genesis of the orebodies

The Black Swan Ultramafic Succession hosts a number of magmatic Fe–Ni–Cu–PGE sulfide ore shoots, ranging from high grade massive ore to low grade disseminated sulfides. Of these, the most economically significant is the Silver Swan massive sulfide orebody, associated with the basal contact of the succession. The deposit varies in thickness between 5 and 20 m, reaches a N–S strike length of 75 m, extends for at least 1.2 km of vertical plunge and is open at depth. Overlying matrix (net-textured) ore is rare. Inclusions of dacite are abundant within the lower 5 m of the massive sulfide. They range from angular fragments through smooth sinuous and plumose morphologies to fine lace-like intergrowths with the sulfide matrix, and comprise variable proportions of cores of porphyritic dacite and carapaces with skeletal plagioclase phenocrysts. Dynamic crystallisation and kinetic melting textures in the carapaces indicate that the inclusions have been heated to various temperatures, some well above their liquidus temperature. The composition of the inclusions ranges from a perfect match with the immediate footwall dacites to mixtures of dacite with up to 30% komatiite. The consistent thickness of the inclusion-bearing basal layer within the massive sulphide is interpreted as the extent of 3-D physical connectivity between the inclusions and a partially molten underlying hybrid layer. Primary contacts between the Silver Swan massive sulfide orebody and overlying ultramafic rocks are marked by thin rinds containing coarse-grained chevron-textured chromites with skeletal textures. Compositions of these chromites match those from Kambalda, Perseverance and other localities, and are inconsistent with a metamorphic origin. They are interpreted as markers of primary magmatic contacts. The combination of this feature with the general paucity of matrix ore implies that the massive ore accumulated and solidified before the accumulation of the overlying thick sequence of olivine cumulates. Taken together with observations on the internal fractionation of platinum group elements within the massive ores, these observations are consistent with a model where the massive ore were emplaced at the floor of a small partially drained lava tube. The floor of the tube had been previously heated by passage of large volumes of lava, such that it had reached its melting range. The felsic inclusions within the ore are the result of buoyant ascent of partially molten substrate into the ore magma. This constitutes strong evidence for the operation of thermo-mechanical erosion during ore emplacement. The disseminated Cygnet and Black Swan orebodies show a number of distinctive features. Cygnet contains a assemblage of clasts and inclusions which are interpreted as the result of rip-up, transport and redeposition of sulfides from a pre-existing massive sulfide orebody, of which Black Duck may be a remnant. The Black Swan orebody, by contrast, does not show xenolithic features, but is characterised by an association of sulfide blebs with segregation vesicles, and by unusually coarse-grained olivine. The Black Swan orebody is interpreted as the result of transport of sulfide droplets within a lava charged with a suspended load of coarse olivine crystals.Editorial handling: Peter Lightfoot     

Komatiites and nickel sulphide orebodies of the Black Swan area,Yilgarn Craton,Western Australia. 1. Petrology and volcanology of host rocks

The Black Swan Succession is a bimodal association of dacitic and komatiitic volcanic rocks located about 50 km NNE of Kalgoorlie, within the 2.7-Ga Eastern Goldfields greenstone province of the Yilgarn Craton. The komatiite stratigraphy comprises a steep dipping, east facing package about 700 m in maximum thickness and about 2.5 km in strike length (Fig. 1), which hosts a number of economically exploitable Ni sulphide orebodies including the Silver Swan massive ore shoot (approximately half a million tonnes at about 10.5% Ni). The sequence can be subdivided into a Lower Felsic Unit, comprising coherent and autobrecciated facies of multiple dacite lava flows; an upper Eastern and lower Western Ultramafic Unit, each showing marked lateral facies variation, and an Upper Felsic Unit coeval with the Eastern Ultramafic Unit. The komatiite sequence has been metamorphosed at sub-greenschist facies in the presence of high proportions of CO2-rich fluid, giving rise to pervasive talc–carbonate and talc–carbonate–quartz assemblages, with extensive preservation of pseudomorphed igneous textures. Cores of lizardite serpentinite are present in the thickest parts of the ultramafic succession. The degree of penetrative deformation is generally very low, and original stratigraphic relationships are largely intact in much of the sequence. The Eastern Ultramafic Unit and Western Ultramafic Unit are interpreted as components of a single large komatiite flow field, representing overlapping stages in the emplacement of a series of distributory lava pathways and flanking sheet flows. The Western Ultramafic Unit which hosts the bulk of the high-grade massive and disseminated ores is a sequence dominated by coarse-grained olivine cumulates, 2 km wide and up to 500 m thick, with major magma pathways represented by thick, homogenous olivine mesocumulate piles at its northern and southern ends: respectively 400 and 200 m thick. The sequence between the two major pathways consists of olivine orthocumulates (oOC) with minor spinifex-textured intervals. The Unit is capped by a persistent spinifex-textured crust less than 1 m thick, and is locally vesicular. The Eastern Ultramafic Unit contains the Black Swan Cumulate Zone, a 500-m thick sequence of very coarse-grained hopper-textured, locally vesicular oOC containing disseminated sulphides in its lower 200 m. The zone is flanked to the north and south by complexly interdigitated sequence of highly irregular, spinifex-capped, olivine cumulate-rich flow lobes between 1 and 100 m thick, and dacitic lavas and tuffs. The complexity of the 3-D spatial relationship of these units suggests a combination of simultaneous eruption of dacite and komatiite, combined with thermal or thermomechanical erosion. The Eastern and Western Units are interpreted as the result of more or less continuous prolonged eruption of olivine charged komatiite lava, which developed localised thermo-mechanical erosion channels in the dacitic substrate. Komatiite and dacite eruption was synchronous, giving rise to complex interdigitation and extensive contamination and hybridisation.Editorial handling: Peter Lightfoot     

Palaeointensity record through the Lower Mammoth reversal from the Waianae volcano, Hawaii

The normal to reverse Lower Mammoth reversal (3.33 Ma) has been recorded in several sequences of lava from the Waianae Volcano, the Island of Oahu, Hawaii. 137 samples from 29 flows from the Pu'u Paheehee section have been the subject of a palaeointensity study using the microwave technique. Duplicate sister samples from the directional study of Herrero-Bervera and Valet (Earth Planet. Sci. Lett. 171 (1999) 139–148) were used. Microwave demagnetisation was carried out on all samples and the directions compared to the published flow mean directions. Microwave palaeointensity experiments were carried out on all accepted samples using the 8.2 GHz and 14 GHz microwave systems. The perpendicular applied field palaeointensity method and a Coe analogue method were used. Eighty-four samples from 24 flows gave acceptable palaeointensity results. The results indicate that the geomagnetic field was low (mean 5.9±1.3 μT (N=7)) prior to the transitional directions. During the first stage of the reversal the field remains low. Results however could only be obtained from three transitional flows. The field then strongly recovers with very high intensity (70 μT) and reversed direction. After this the intensity decreases before the field becomes transitional again for a cluster of four flows. The field does not reduce as much as previously, rather it is about twice the pre reversal intensity. For the final section of reversed flows the intensity is more than twice the pre reversal mean value, 15.1±5.9 μT (N=7). Whilst some similarities are seen between this reversal and other reversals of different ages and locations there is not enough data at present to say whether there is any systematic behaviour.