Effectiveness of sulfate-reducing passive bioreactors for treating highly contaminated acid mine drainage: I. Effect of hydraulic retention time

Sulfate-reducing passive bioreactors have proved to be an effective technology for the treatment of acid mine drainage (AMD) contaminated waters over relatively short periods of time (1–5 a). However, long-term efficiency can be limited by several factors including problems related to the hydraulic properties of the reactive mixture. In this study, the effect of two hydraulic retention times (HRTs) of 7.3 d and 10 d on the performance of passive bioreactors was evaluated over an 11-month period for the treatment of a highly contaminated AMD. Evolution of the porosity and hydraulic conductivity of the reactive mixture was also evaluated during the 15-month operation of two bioreactors. Results indicated that bioreactors were effective at both HRTs for increasing the pH and alkalinity of contaminated water and for SO₄ and metal removal (60–82% for Fe and up to 99.9% for Cd, Ni and Zn). Although the quality of treated effluent was significantly improved with the 10 d HRT compared to the 7.3 d HRT, results showed that the higher HRT reduced the porosity and the permeability of the reactive mixture which might lead to hydraulic related problems and, eventually, to limited efficiency in long-term operation compared to a shorter HRT. The choice of HRT for a passive bioreactor must therefore consider both the desired quality of treated effluent and the potential for deterioration of hydraulic properties in the reactive mixture.     

Effectiveness of sulfate-reducing passive bioreactors for treating highly contaminated acid mine drainage: II. Metal removal mechanisms and potential mobility

Column bioreactors were used for studying mechanisms of metal removal, assessment of long-term stability of spent reactive mixtures, as well as potential metal mobility after treating highly contaminated acid mine drainage (AMD; pH 2.9–5.7). Several physicochemical, microbiological, and mineralogical analyses were performed on spent reactive mixtures collected from 4 bioreactors, which were tested in duplicate for two hydraulic retention times (7.3d and 10d), with downward flow over an 11-month period. Consistent with the high metal concentrations in the AMD feed, and with low metal concentrations measured in the treated effluent, the physicochemical analyses indicated very high concentrations of metals (Fe, Mn, Cd, Ni, and Zn) in the top and bottom layers of the reactive mixtures from all columns. Moreover, the concentrations of Fe (50.8–57.8 g/kg) and Mn (0.53–0.70 g/kg) were up to twice as high in the bottom layers, whereas the concentrations of Cd (6.77–13.3 g/kg), Ni (1.80–5.19 g/kg) and Zn (2.53–13.2 g/kg) were up to 50-times higher in the top layers. Chemical extractions and elemental analysis gave consistent results, which indicated a low fraction of metals removed as sulfides (up to 15% of total metals recovered in spent reactive mixtures). Moreover, Fe and Mn were found in a more stable chemical form (residual fraction was 42–74% for Mn and 30–77% for Fe) relative to Cd, Ni or Zn, which seemed more weakly bound (oxidisable/reducible fractions) and showed higher potential mobility. Besides identifying (oxy)hydroxide and carbonate minerals, the mineralogical analyses identified metal sulfides containing Fe, Cd, Ni and Zn. Metal removal mechanisms were, therefore, mainly adsorption and other binding mechanisms with organic matter (for Cd, Ni and Zn), and the precipitation as (oxy)hydroxide minerals (for Fe and Mn). After 15 months, however, the column bioreactors did not lose their capacity for removing metals from the AMD. Although the metals were immobile during the bioreactor treatment, their mobility could increase from spent reactive mixtures, if stored inappropriately. Metal recovery by acidic leaching of spent substrates at the end of bioreactor operation could be an alternative.     

Development and morphometry of sinkholes in coastal plains of Apulia, southern Italy. Preliminary sinkhole susceptibility assessment

Evolution of coastlines in karst areas may be strongly controlled by dissolution processes which favour the development of surface and subsurface landforms. The generation of caves in these environments is commonly favoured by the mixing between fresh and brackish waters. The sinkholes resulting from the upward propagation of the caves may interfere with the anthropogenic environment and cause damage to human elements (property and activities). To highlight the often underestimated importance of karst phenomena in coastal areas, we have analyzed a coastal stretch of Apulia, in southern Italy. The study area, covering an extension of about 6 km², is situated in the Ionian coast, and presents several interesting karst landforms that are generally connected to caves. Tens of sinkholes were mapped through field surveys, multi-year aerial-photographs (dating back to the 1940s) and archival research. We have performed a morphometric analysis of the sinkholes. The analysis describes the main parameters of the sinkholes (area, length, width, and depth), and the control exerted by the main discontinuity systems in the area. The detrimental effects derived from interaction between human environment and these karst landforms is also under consideration. A sinkhole susceptibility map, which may provide useful information for planners, developers and the insurance industry has eventually been produced through application of a decision tree model.     

Dissolution of calcitic marble and dolomitic rock in high iron concentrated acid mine drainage: application to anoxic limestone drains

Oxidation of sulphide mining waste can generate acid mine drainage (AMD) that has the potential to seriously affect the ecosystems. Acid mine drainage is characterised by a high acidity, high concentrations of sulphates and metals. To reduce the environmental impacts due to AMD, neutralisation using limestone drains is an option proposed in the literature and used around the world. The present study focuses on the influence of the carbonate rock mineralogy and their particle size on the neutralising capacity. The tests were performed in two different anoxic conditions: in batch reactors, and in columns having a hydraulic retention time of 15?h. The results showed that the neutralisation capacity of calcite was more important than for dolomitic rock, and smaller particle size gave higher alkalinity production (fine calcite dissolved faster in contact with AMD). A characterization of metal precipitate in sludge and in limestone coating was performed and demonstrated that gypsum, lepidocrocite and goethite were the predominant secondary minerals to be formed. Finally, this study underlines that anoxic limestone drain cannot be used alone to treat high iron concentrated AMD.     

Über Neue Ergebnisse Kleintektonischer Untersuchungen im Rheinischen Schiefergebirge

Zusammenfassung Zunächst wird die offenbar überragende Bedeutung der Diagonal-Störungen in den untersuchten Dachschiefer-Gruben dargelegt. Es ergeben sich ferner sehr spitzwinklig zum tektonischen Streichen verlaufende Drehverschiebungen, die zur gleichartigen Verformung führen, wie auch die örtlich festgestellten Auf- und Überschiebungen sowie Schieferung und Faltung (gleiche Deformationsellipse). — Die Schieferung führt in extremen Fällen zu einer fast völligen Umschichtung (tektonische Mischung).In einem Querprofil des Faltenspiegels zwischen Hunsrück und SE-Eifel kommt besonders die Moselmulde (Form und Schichtmächtigkeiten) zur Darstellung.     

Seasonal control of the Saint-Lawrence maximum turbidity zone by tidal-flat sedimentation

The core of the turbidity maximum zone in the Saint-Lawrence Estuary is located in the North Channel and oscillates in front of the large (3×10⁶ m²) intertidal flats and marshes of Cap Tourmente. It is shown that seasonal fluctuations in the intensity and the position of this core are mainly determined by suspended sediment exchanges between the channel and the marshes. Fine sediments, most of them found 20 km downstream in the channel off Cap Maillard in late winter and early spring, are advected upstream over the flats during the summer months by the tide. The deposition, favored by marsh plant growth, reaches 5×10⁵ metric tons in three months. A period of intense erosion, at a mean rate of 4,500 metric tons per tide, coincides with the destruction of the plant cover by migratory geese. The material removed fills up the Chenal de l’Île d’Orléans upstream and is flushed back into the water column during the next spring freshette. This rotating seasonal sediment circulation, although very localized, exerts a major influence on the distribution and storage time of suspended particles in the upper estuary.     

Über die Messung von Massensehwächungskoeffizienten bei der Phasenanalyse mit dem Zählrohrgoniometer

Zusammenfassung Es wird ein Verfahren angegeben, um bei der röntgenographischen Gemischanalyse mit dem Zählrohrgoniometer, dann wenn die Gefahr von Textureffekten nicht besteht, die Intensitäten der Analysenlinien und den Massenschäwachungskoeffizienten in demselben Präparat messen zu können; dazu wird in den Boden des Präparatträgers eine Einkristallplatte eingekittet und die Schwächung gemessen, die ein Reflex der Kristallplatte durch Einbringen der Präparatsubstanz erfährt.     

Contrasting sources of Late Paleozoic rhyolite magma in the Polish Lowlands: evidence from U–Pb ages and Hf and O isotope composition in zircon

International Journal of Earth Sciences - The Polish Lowlands, located southwest of the Teisseyre–Tornquist Zone, within Trans-European Suture Zone, were affected by bimodal, but dominantly...     

Geologische Problematik und Strukturanalyse Nikaraguas

The basement of northern Nicaragua is still a great problem stratigraphically. Enclosed tuffits (mainly basic, partly also intermediate to acid) appear of importance for both petrology and sedimentology. Not in the least they are guide horizons for a more accurate mapping. The vast regional distribution, commonly proved yet, suggests that the composition of the basement is considerably uniform and it seems that they do not belong to different periods and formations. Structurally the region is exceedingly complicated. The folding direction as regards plication and overthrusts is mainly to the North, but partly also to the East. Probably the “Totogalpa formation” (fanglomerates, conglomerates and sandstones, mainly reddish) which follows disconformably over the basement, already indicated, belongs to the sequence of tertiary tuffites, agglomerates, lavas etc. as they conformably form a formation of uniform composition. The relation of basement to lower Cretaceous (marine Albian; “Metapan”), which follows immediately to the south, is less clear. The lower Cretacious shows intensive and complicated folding at Siuna and it appears almost unmetamorphosed (? basement in a wider sense). The marine sediments (upper Cretacious - Miocene) of South Nicaragua are orogenetically only slightly efected (folding direction to E-N). To the North follows a thick serie of Tertiary and Quarternary volcanites (initially mainly submarinal, later on continental). Together with the NW/SE lineaments (Nicaragua depression, lines of volcanoes, coast line in the SW etc.) also NS directed ones clearly appear (coastline in the East). This direction can be found e. g. in the “granite ridge of Susucayan” and the accompanying faults in the vicinity. These latter structures may have taken an active part in the development of the flexured border of the Nicaraguan depression NW of Managua.     

Enregistrement de la variabilité hydroclimatique au cours des 6500 dernières années sur le littoral de Cabo Frio (Rio de Janeiro,Brésil)

This study concerns a core collected in Brejo do Espinho's lagoon from Cabo Frio littoral (Brazil) submitted to dry influence of local upwelling controlled by north-east trade winds from the South Atlantic and particularly strengthened during El Niño events. Diatoms study supported by sedimentological and isotopic analyses shows dry phases infrequent before 4000 yr, a highly variable climatic phase between 3600 and 2900 yr and from 2400 yr onward a dryness enhancement. To cite this article: B. Laslandes et al., C. R. Geoscience 338 (2006).