Precipitation as a proxy for climate variables: application for hydrological modelling

It has been proposed that linear regression curves can be used to estimate monthly climate variables from observed precipitation. This approach was explored by applying the MGB hydrological model to the Paraná Basin (Brazil). Linear regressions were obtained for 54 climate gauges, and most of them showed at least six months of significant correlation between monthly climate variables (sunlight hours and relative humidity) and precipitation. The regression equations were applied to 5201 raingauges to estimate monthly climate variables and evapotranspiration, and the results were compared with a scenario using long-term climate averages only. The main differences occurred in wetter periods, where negative correlations between monthly precipitation and evapotranspiration were obtained when using precipitation as a proxy. Long-term changes in the hydrological regime were assessed and showed that the effect of precipitation on relative humidity and sunlight hours seems to have a minor effect on the alterations observed in river discharge in the Paraná Basin.     

In vitro simulation of oxic/suboxic diagenesis in an estuarine fluid mud subjected to redox oscillations

Estuarine turbidity maxima (ETMs) are sites of intense mineralisation of land-derived particulate organic matter (OM), which occurs under oxic/suboxic oscillating conditions owing to repetitive sedimentation and resuspension cycles at tidal and neap-spring time scales. To investigate the biogeochemical processes involved in OM mineralisation in ETMs, an experimental set up was developed to simulate in vitro oxic/anoxic oscillations in turbid waters and to follow the short timescale changes in oxygen, carbon, nitrogen, and manganese concentration and speciation. We present here the results of a 27-day experiment (three oxic periods and two anoxic periods) with an estuarine fluid mud from the Gironde estuary. Time courses of chemical species throughout the experiment evidenced the occurrence of four distinct characteristic periods with very different properties. Steady oxic conditions were characterised by oxygen consumption rates between 10 and 40 μmol L⁻¹ h⁻¹, dissolved inorganic carbon (DIC) production of 9–12 μmol L⁻¹ h⁻¹, very low NH₄⁺ and Mn²⁺ concentrations, and constant NO₃⁻ production rates (0.4 - 0.7 μmol L⁻¹ h⁻¹) due to coupled ammonification and nitrification. The beginning of anoxic periods (24 h following oxic to anoxic switches) showed DIC production rates of 2.5–8.6 μmol L⁻¹ h⁻¹ and very fast NO₃⁻ consumption (5.6–6.3 μmol L⁻¹ h⁻¹) and NH₄⁺ production (1.4–1.5 μmol L⁻¹ h⁻¹). The latter rates were positively correlated to NO₃⁻ concentration and were apparently caused by the predominance of denitrification and dissimilatory nitrate reduction to ammonia. Steady anoxic periods were characterised by constant and low NO₃⁻ concentrations and DIC and NH₄⁺ productions of less than 1.3 and 0.1 μmol L⁻¹ h⁻¹, respectively. Mn²⁺ and CH₄ were produced at constant rates (respectively 0.3 and 0.015 μmol L⁻¹ h⁻¹) throughout the whole anoxic periods and in the presence of nitrate. Finally, reoxidation periods (24–36 h following anoxic to oxic switches) showed rapid NH₄⁺ and Mn²⁺ decreases to zero (1.6 and 0.8–2 μmol L⁻¹ h⁻¹, respectively) and very fast NO₃⁻ production (3 μmol L⁻¹ h⁻¹). This NO₃⁻ production, together with marked transient peaks of dissolved organic carbon a few hours after anoxic to oxic switches, suggested that particulate OM mineralisation was enhanced during these transient reoxidation periods. An analysis based on C and N mass balance suggested that redox oscillation on short time scales (day to week) enhanced OM mineralisation relative to both steady oxic and steady anoxic conditions, making ETMs efficient biogeochemical reactors for the mineralisation of refractory terrestrial OM at the land-sea interface.     

Benthic remineralization at the land–ocean interface: A case study of the Rhône River (NW Mediterranean Sea)

Biogeochemical processes in sediments under the influence of the Rhône River plume were studied using both in situ microelectrodes and ex situ sediment core incubations. Organic carbon (OC) and total nitrogen (TN) content as well as stable carbon isotopic composition of OC (δ¹³C_OC) were analysed in 19 surface sediments to determine the distribution and sources of organic matter in the Rhône delta system. Large spatial variations were observed in both the total O₂ uptake (5.2 to 29.3 mmol m⁻² d⁻¹) and NH₄⁺ release (−0.1 to −3.5 mmol m⁻² d⁻¹) rates at the sediment–water interface. The highest fluxes were measured near the Rhône River mouth where sedimentary OC and TN contents reached 1.81% and 0.23% respectively. Values of δ¹³C_OC ranged from −26.83‰ to −23.88‰ with a significant seawards enrichment tracing the dispersal of terrestrial organic matter on the continental shelf. The amount of terrestrial-derived OC reaches 85% in sediments close to the Rhône mouth decreasing down to 25% in continental shelf sediments. On the prodelta, high terrestrial OC accumulation rates support high oxygen uptake rates and thus indicating that a significant fraction of terrestrial OC is remineralized. A particulate organic carbon (POC) mass balance indicates that only 3% of the deposited POC is remineralized in prodelta sediments while 96% is recycled on the continental shelf. It was calculated that a large proportion of the Rhône POC input is either buried (52%) or remineralized (8%), mostly on the prodelta area. The remaining fraction (40%) is either mineralized in the water or exported outside the Rhône delta system in dissolved or particulate forms.     

Effects of hydrostatic pressure on microbial alteration of sinking fecal pellets

We used a new experimental device called PASS (PArticle Sinking Simulator) during MedFlux to simulate changes in in situ hydrostatic pressure that particles experience sinking from mesopelagic to bathypelagic depths. Particles, largely fecal pellets, were collected at 200 m using a settling velocity NetTrap (SV NetTrap) in Ligurian Sea in April 2006 and incubated in high-pressure bottles (HPBs) of the PASS system under both atmospheric and continuously increasing pressure conditions, simulating the pressure change experienced at a sinking rate of 200 m d⁻¹. Chemical changes over time were evaluated by measuring particulate organic carbon (POC), carbohydrates, transparent exopolymer particles (TEP), amino acids, lipids, and chloropigments, as well as dissolved organic carbon (DOC) and dissolved carbohydrates. Microbial changes were evaluated microscopically, using diamidinophenylindole (DAPI) stain for total cell counts and catalyzed reporter deposition-fluorescence in situ hybridization (CARD-FISH) for phylogenetic distinctions. Concentrations (normalized to POC) of particulate chloropigments, carbohydrates and TEP decreased under both sets of incubation conditions, although less under the increasing pressure regime than under atmospheric conditions. By contrast, dissolved carbohydrates (normalized to DOC) were higher after incubation and significantly higher under atmospheric conditions, suggesting they were produced at the expense of the particulate fraction. POC-normalized particulate wax/steryl esters increased only under pressure, suggesting biochemical responses of prokaryotes to the increasing pressure regime. The prokaryotic community initially consisted of 43% Bacteria, 12% Crenarchaea and 11% Euryarchaea. After incubation, Bacteria dominated (90%) the prokaryote community in all cases, with γ-Proteobacteria comprising the greatest fraction, followed by the Cytophaga–Flavobacter cluster and α-Proteobacteria group. Using the PASS system, we obtained chemical and microbial evidence that degradation by prokaryotes associated with fecal pellets sinking through mesopelagic waters is limited by the increasing pressure they experience.     

Post-rift volcanism and high heat-flow at the ocean-continent transition of the eastern Gulf of Aden

A high heat-flow (∼900 mW m⁻²) has been observed over a volcanic structure at the Ocean-Continent Transition in the Eastern Gulf of Aden (Oman margin). The anomaly is superposed to a progressive increase of heat-flow across the margin and can be interpreted either by (1) heat refraction, (2) fluid discharge or (3) cooling magma. The two first explanations cannot be ruled out definitely by modelling analysis, but require unlikely thermal conductivity or permeability values. The third one implies that the latest activity of the volcano was about 100 000 years old and therefore continued c. 18 Ma after the break-up of Africa and Arabia. This potential mechanism is consistent with other lines of evidence of post-rifting activity in the Gulf of Aden and could invalidate the conventional assumption that rifted-margins become passive after the break-up of continents.     

Release of neutral sodium atoms from the surface of Mercury induced by meteoroid impacts

Meteoroid impact has been shown to be a source of sodium, and most likely of other elements, on the Moon. The same process could be also relevant for Mercury. In this work we calculate the vapor and neutral Na production rates on Mercury due to the impacts of meteoroids in the radius range of 10⁻⁸-10⁻¹ m. We limit our calculations to this size range, because meteoroids with radius larger than 10⁻¹ m have not to be found important for the daily production of the exosphere. This work is based on a new dynamical model of the meteoroid flux at the heliocentric distance of Mercury, regarding objects in the size range 10⁻²-10⁻¹ m. This size range, never investigated before, is not affected by nongravitational forces, such as the Poynting-Robertson effect, which is dominant for particles smaller than 10⁻² m. In order to evaluate the release of neutral sodium atoms also for smaller meteoroids we have used the distribution reported by M.J. Cintala [1992. Impact-induced thermal effects in the lunar and mercurian regoliths. J. Geophys. Res. 97, 947-973] calculated for particle size range 10⁻⁸-10⁻³ m. We have extrapolated this distribution up to 10⁻² m and we have based the impact calculations on a new surface composition assuming 90% plagioclase and 10% pyroxene. The results of our model are that (i) the total mass of vapor produced by the impact of meteoroids in the size range 10⁻⁸-10⁻¹ m is 4.752×¹⁰⁸ g per year, and (ii) the production rate of neutral sodium atoms is 1.5×¹⁰²² s⁻¹.     

Scaling laws and coherent structures in the solar wind

The interplanetary medium is characterized by a very high Reynolds number and is pervaded by fluctuations providing information on a wide range of scales, from fractions of second up to the solar rotation period. In the past decade or so, turbulence in the solar wind has been used as a large wind tunnel to investigate scaling laws of turbulent fluctuations and multifractal models. Moreover, new interesting insights in the theory of turbulence have been derived from the point of view which considers a turbulent flow as a complex system, a sort of benchmark for the theory of dynamical systems. Important finding like the lack of a strict self-similarity of the fluctuations with the consequent nonapplicability of strict scale invariance, the strong anisotropy of velocity and magnetic field fluctuations, the clear lack of equipartition between magnetic and kinetic fluctuations all contributed to suggest the idea that interplanetary fluctuations could possibly be due to a mixture of propagating waves and static structures convected by the wind. In this paper we further discuss this point and bring new evidence about the fact that the presence of a background magnetic field introduces not only a symmetry breaking in interplanetary space but also organizes fluctuations about its large scale orientation.     

lemomaf: Lensed Mock Map Facility

We present the Lensed Mock Map Facility ( lemomaf ), a tool designed to perform mock weak-lensing measurements on numerically simulated chunks of the Universe. Coupling N -body simulations to a semi-analytical model of galaxy formation, lemomaf can create realistic lensed images and mock catalogues of galaxies, at wavelengths ranging from the ultraviolet to the submillimetre. To demonstrate the power of such a tool, we compute predictions of the source–lens clustering (SLC) effect on the convergence statistics, and quantify the impact of weak lensing on galaxy counts in two different filters. We find that the SLC effect skews the probability density function of the convergence towards low values, with an intensity which strongly depends on the redshift distribution of galaxies. On the other hand, the degree of enhancement or depletion in galaxy counts due to weak lensing is independent of the SLC effect. We discuss the impact on the two-point shear statistics to be measured by future missions like SNAP and LSST . The SLC effect would bias the estimation of σ₈ from two-point statistics up to 5 per cent for a narrow redshift distribution of mean   z ∼ 0.5  , and up to 2 per cent in small angular scales for a redshift distribution of mean   z ∼ 1.5  . We conclude that accurate photometric redshifts for individual galaxies are necessary in order to quantify and isolate the SLC effect.     

Equilibration Scales in Silicic to Intermediate Magmas Implications for Experimental Studies

Experimental phase equilibrium studies are increasingly beingused for the determination of intensive variables (P, T, fH₂O,fO₂ ) in silicic to intermediate magmas. In contrast, silicicigneous bodies are now perceived as open, periodically recharged,systems involving only limited chemical equilibration. Thus,the use of laboratory-determined crystal–liquid equilibriumdata needs clarification. Here we review the field, petrologicaland geochemical evidence concerning states and scales of chemicalequilibrium in silicic magma bodies. It is concluded that totalchemical equilibrium is generally not the rule. However, a subsystemin local equilibrium (the reactive magma) can be identified.Equilibration scales in silicic magmas are rate-limited eitherby diffusive flux in crystals (DICL regime) or by diffusiveflux in the melt (MD regime). The recognition that equilibriumin magmas is limited to a reactive subsystem requires phaseequilibrium studies to be chemically scaled. Experiments, eitherof total or partial equilibrium type, should aim at a closereproduction of equilibrium states specific to natural systems.The laboratory reconstruction of the natural equilibrium statesguarantees a precise determination of the pre-eruptive parametersand a reliable application of the experimental data to activevolcanic systems. KEY WORDS: silicic magmas; chemical equilibrium; timescales; experimental studies