The impact of pyrite variability, dispersive transport and precipitation of secondary phases on the sulphate release due to pyrite weathering

The objective of this study was to investigate the impact of flow, transport and geochemical parameters in the unsaturated and saturated zones on the release of SO₄ from overburden lignite spoil piles into the adjacent lake. A vertical one-dimensional model was set up using the reactive transport simulator SULFIDOX in order to account for the unsaturated zone. The SULFIDOX model was calibrated for effective diffusion using measured O₂ in the gas phase and SO₄ concentrations in the liquid phase from the unsaturated zone of the heap. The results show high sensitivity to O₂ supply and initially present gypsum, but the inclusion of secondary mineral precipitation in equilibrium is of minor importance for the results. To account for the transport of released SO₄ from the saturated zone into the surface water, scenarios were performed by using SULFIDOX results as input concentration for a two-dimensional vertical model set up with PROCESSING MODFLOW and MT3D. These scenarios indicate a rising discharge of SO₄ into the adjacent lake due to continued pyrite weathering for 80 a. Results are highly sensitive to dispersivity, whereas the spatial variability of pyrite distribution did not show any influence on the results. The consideration of initially present gypsum shows a major effect on the modelled SO₄ release.     

Gangdese retroarc thrust belt and foreland basin deposits in the Damxung area, southern Tibet

Geologic mapping and U–Pb detrital zircon geochronologic studies of (meta)sedimentary rocks in the Damxung area (90 km north of Lhasa) of the southern Lhasa terrane in Tibet provide new insights into the history of deformation and clastic sedimentation prior to late Cenozoic extension. Cretaceous nonmarine clastic rocks 10 km southeast of Damxung are exposed as structural windows in the footwall of a thrust fault (the Damxung thrust) that carries Paleozoic strata in the hanging wall. To the north of Damxung in the southern part of the northern Nyainqentanglha Range (NNQTL), metaclastic rocks of previously inferred Paleozoic age are shown to range in depositional age from Late Cretaceous to Eocene. The metaclastic rocks regionally dip southward and are interpreted to have been structurally buried in the footwall of the Damxung thrust prior to being tectonized during late Cenozoic transtension. Along the northern flank of the NNQTL, Lower Eocene syncontractional redbeds were deposited in a triangle zone structural setting. All detrital zircon samples of Cretaceous–Eocene strata in the Damxung area include Early Cretaceous grains that were likely sourced from the Gangdese arc to the south. We suggest that the that newly recognized Late Cretaceous to Early Eocene (meta)clastic deposits and thrust faults represent the frontal and youngest part of a northward directed and propagating Gangdese retroarc thrust belt and foreland basin system that led to significant crustal thickening and elevation gain in southern Tibet prior to India-Asian collision.     

Oyster Predation by Black Drum Varies Spatially and Seasonally

Oyster reefs (Crassostrea virginica) supply important ecosystem services to estuarine habitats in the northern Gulf of Mexico, but little is known of the role of fish predators in controlling their structure or areal cover on soft sediments. At two sites and during fall and spring, we employed gill nets and trot lines to remove black drum (Pogonias cromis) from experimental reefs, and assessed oyster survival in comparison to control reefs. Numbers and biomass of black drum removed from reefs varied seasonally, among sites, and among removal methods. In the fall, black drum were rare at one site and abundant at the other, but did not significantly lower oyster survival on control reefs at either site. In the spring, black drum were common at both sites, and significantly lowered oyster survival on control reefs. Oysters and epizoic hooked mussels comprised roughly a third of the fishes’ diet, and oyster mortality was closely related to the percentage of drum feeding on oysters. There was little evidence of mortality from other predators of seed oysters like stone crabs or Southern oyster drills, and a repeated measures analysis of variance indicated black drum biomass was significantly depressed on experimental reefs during the experiments. Black drum thus appear to be potentially important predators on oyster reefs, but more work needs to be done on what factors explain the temporal and spatial variation in their abundance and oyster consumption.     

Stratigraphy of the Koobi Fora Formation (Pliocene and Pleistocene) in the Loiyangalani region of northern Kenya

Tuffaceous marker beds in the Loiyangalani region were previously identified as correlative with similar beds in the Shungura and Koobi Fora Formations of southwestern Ethiopia and northwestern Kenya. Associated sedimentary strata correlate with the Koobi Fora Formation, and include intercalated basalt flows. In the Loiyangalani region the Koobi Fora Formation has a composite thickness of at least 257 m, and records one time interval for which no strata are known in the Koobi Fora region. Four members of the Koobi Fora Formation (Lonyumun, Tulu Bor, Burgi, and KBS) are recognized in the region, and a composite member (Moiti–Lokochot) proposed because the Lokochot Tuff, the formal boundary between the Moiti and Lokochot Members has not been identified. This extends the known geographic area of the Koobi Fora Formation 100 km southward. These strata, together with others, were previously termed ‘Loiyangalani formation (or Formation)’. Deposition in the Loiyangalani region began at about the same time as in the Koobi Fora and Nachukui Formations. Newly named basalts are Kankam (3.2–3.3 Ma), Lenderit (2.02 to 2.18 ± 0.02 Ma), and Balo (1.79 ± 0.02 Ma). We also report K/Ar ages on basalts from Mt. Kulal (2.04 ± 0.02 to 2.40 ± 0.03 Ma) east of the region and from Serima Gorge (0.77 ± 0.01 Ma) south of the study area.     

Comprehensive Evaluation of Fast-Response,Reynolds-Averaged Navier–Stokes,and Large-Eddy Simulation Methods Against High-Spatial-Resolution Wind-Tunnel Data in Step-Down Street Canyons

Three computational fluid dynamics (CFD) methods with different levels of flow-physics modelling are comprehensively evaluated against high-spatial-resolution wind-tunnel velocity data from step-down street canyons (i.e., a short building downwind of a tall building). The first method is a semi-empirical fast-response approach using the Quick Urban Industrial Complex (QUIC-URB) model. The second method solves the Reynolds-averaged Navier–Stokes (RANS) equations, and the third one utilizes a fully-coupled fluid-structure interaction large-eddy simulation (LES) model with a grid-turbulence inflow generator. Unlike typical point-by-point evaluation comparisons, here the entire two-dimensional wind-tunnel dataset is used to evaluate the dynamics of dominant flow topological features in the street canyon. Each CFD method is scrutinized for several geometric configurations by varying the downwind-to-upwind building-height ratio (\(H_\mathrm{d}/H_\mathrm{u}\)) and street canyon-width to building-width aspect ratio (S / W) for inflow winds perpendicular to the upwind building front face. Disparities between the numerical results and experimental data are quantified in terms of their ability to capture flow topological features for different geometric configurations. Overall, all three methods qualitatively predict the primary flow topological features, including a saddle point and a primary vortex. However, the secondary flow topological features, namely an in-canyon separation point and secondary vortices, are only well represented by the LES method despite its failure for taller downwind building cases. Misrepresentation of flow-regime transitions, exaggeration of the coherence of recirculation zones and wake fields, and overestimation of downwards vertical velocity into the canyon are the main defects in QUIC-URB, RANS and LES results, respectively. All three methods underestimate the updrafts and, surprisingly, QUIC-URB outperforms RANS for the streamwise velocity component, while RANS is superior to QUIC-URB for the vertical velocity component in the street canyon.     

A climate trend analysis of Ethiopia: examining subseasonal climate impacts on crops and pasture conditions

Ethiopia experiences significant climate-induced drought and stress on crop and livestock productivity, contributing to widespread food insecurity. Here, we present subseasonal crop water stress analyses that indicate degrading, growing conditions along Ethiopia’s eastern highlands, including productive and populated highland regions. These seasonally shifting areas of increasing water stress stretch from the north to south across eastern Ethiopia, intersecting regions of acute food insecurity and/or high population. Crop model simulations indicate that between 1982 and 2014, parts of eastern Amhara and eastern Oromia experienced increasing water deficits during the critical sowing, flowering, and ripening periods of crop growth. These trends occurred while population in these regions increased by 143% between 2000 and 2015. These areas of enhanced crop water stress in south-central Ethiopia coincide with regions of high population growth and ongoing crop extensification. Conversely, large regions of relatively unpopulated western Ethiopia are becoming wetter. These areas may therefore be good targets for agricultural development.     

Tricarbon monoxide in TMC-1

We report the measurement of three new lines of C3O in TMC-1. The observed peak antenna temperatures, appropriately corrected for atmospheric and telescope losses, are found to be consistent with a large velocity gradient radiative transfer model whose parameters span the range of standard values for this cloud. The derived fractional abundance for C3O is 1.4 x 10(-10), comparable with the results predicted from a model calculation based on a gas-phase ion-molecule reaction scheme. The results of negative searches for C3O in six other sources are not inconsistent with expected conditions in these clouds.     

New interstellar masers in nonmetastable ammonia

We report the astronomical detections of several ammonia inversion transitions involving nonmetastable levels with energies as high s 1090 K above the ground state. The (J, K) = (9, 6) inversion transition shows maser-like emission in the directions of W51, NGC 7538, W49, and DR 21(OH). The NH3 (6, 3) line exhibits similar characteristics in W51 but is seen in absorption in NGC 7538. These are the first definite detections of ammonia masers in space. The intensities and narrow line widths (0.5-1.5 km s-1) for the emission features are in contrast to the previously detected broad, weak, nonmetastable lines attributed to thermal emission in these sources. Temporal variability appears to be evident in the (9, 6) emission in W49 over a 4 month period. The highly excited (J, K) = (9, 6) and (6, 3) ammonia lines are found in regions containing compact H II regions and strong infrared sources with associated H2O and OH masers; i.e., in regions of active star formation.     

Beam-driven return current instability and anomalous plasma heating in solar flares

We consider the problem of ion-acoustic wave generation, and resultant anomalous Joule heating, by a return current driven unstable by a small-area thick-target electron beam in solar flares. With a prescribed beam current evolution, j _b (t) (and, therefore, a prescribed return current j _p (t) = –j _b (t)), and using an approximate local treatment with a two component Maxwellian plasma, and neglecting energy losses, we demonstrate the existence of two quite distinct types of ion-acoustic unstable heating regimes. First, marginally stable heating occurs when the onset of instability occurs at electron-ion temperature ratios T _e /T _i > 4.8. Secondly, there exists a catastrophic heating regime for which marginally stable evolution is impossible, when the onset of instability occurs at T _e /T _i < 4.8.For the marginally stable case, we solve the electron and ion heating equations numerically and find that rapid anomalous Ohmic heating occurs in a substantial plasma volume. This large hot plasma emits thermal bremsstrahlung hard X-rays ( 20 keV) comparable to, or exceeding, the nonthermal bremsstrahlung which would have been emitted by the beam in a conventional thick target, large area, collisional scenario without anomalous effects. This means that, contrary to the usual assumption, onset of return current instability need not turn off hard X-ray production by a beam, though changing its source from direct to indirect. Indeed with small beam areas, this indirect mechanism can result in a higher hard X-ray bremsstrahlung efficiency than in a conventional collisional thick target.The catastrophic heating regime, for which we expect much larger wave levels, is discussed qualitatively, and preliminary results cited of an alternative approach, incorporating an equation directly describing the electrostatic wave energy level. Which of these two regimes will pertain in any particular case depends (discontinuously) on the beam and atmospheric parameters and we suggest that this effect may manifest itself in the distinctive temporal behaviour of X-ray flares.     

Are PSR 0656+14, PSR 0950+08, and PSR 1822-09 gamma-ray pulsars?

The possible discovery of three new -ray pulsars PSR 0656+14, PSR 0950+08, and PSR 1822-09 (Ma, Lu, Yu, and Young, 1993) in data obtained with the COS-B experiment is reinvestigated using a refined technique for pulsar light curve analysis. The results of this study do not confirm the previously claimed -ray pulsar nature of any of these pulsars. Even when using the standard epoch folding technique in conjunction with energy-dependent acceptance cones, we do not detect pulsed -ray emission from these sources. We suspect that insufficient position accuracy is the cause for the discrepancy between our results and those of Maet al. (1993). We do not rule out that any one of the three candidates, or all of them, is in fact a -ray pulsar, but their spin properties must differ from those derived by Maet al. (1993). More work is needed to determine the correct high-energy properties of these three sources.