Soft X-ray spectroscopic studies of the reaction of fractured pyrite surfaces with Cr(VI)-containing aqueous solutions

We have used synchrotron-based soft X-ray core-level photoemission and adsorption spectroscopies to study the reaction of aqueous sodium chromate solutions with freshly fractured pyrite surfaces. Pyrite surfaces were reacted with 50 μM sodium chromate solution at pH 7 for reaction times between 1 min and 37 hr. Additional experiments were performed at pH 2 and pH 4 with 50 μM sodium chromate solutions and at pH 7 with 5 mM solutions. At chromate concentrations of 50 μM, all chromium present on the pyrite surface was in the form of Cr(III), while at 5 mM, both Cr(III) and Cr(VI) were present at the pyrite surface. Minor quantities of oxidized sulfur species (sulfate, sulfite, and zero-valent sulfur) were identified as reaction products on the pyrite surface. The amount of oxidized sulfur species observed on the surface was greater when pyrite was reacted with 5 mM Cr(VI) solutions because the rate of chromium deposition exceeded the rate of dissolution of pyrite oxidation products, effectively trapping Cr(VI) and oxidized sulfur species in an overlayer of iron(III)-containing Cr(III)-hydroxide. This work shows that pyrite, an extremely cheap and readily available waste material, may be suitable for the removal of hexavalent chromium from acidic to circumneutral waste streams. The reduced chromium ultimately forms a coating on the pyrite surface, which passivates the pyrite surface towards further oxidation.     

Evaluation of snow water equivalent datasets over the Saint‐Maurice river basin region of southern Québec

A 10‐km gridded snow water equivalent (SWE) dataset is developed over the Saint‐Maurice River basin region in southern Québec from kriging of observed snow survey data for evaluation of SWE products. The gridded SWE dataset covers 1980–2014 and is based on manual gravimetric snow surveys carried out on February 1, March 1, March 15, April 1, and April 15 of each snow season, which captures the annual maximum SWE (SWEM) with a mean interpolation error of ±19%. The dataset is used to evaluate SWEM from a range of sources including satellite retrievals, reanalyses, Canadian regional climate models, and the Canadian Meteorological Centre operational snow depth analysis. We also evaluate a number of solid precipitation datasets to determine their contribution to systematic errors in estimated SWEM. None of the evaluated datasets is able to provide estimates of SWEM that are within operational requirements of ±15% error, and insufficient solid precipitation is determined to be one of the main reasons. The Climate System Forecast Reanalysis is the only dataset where snowfall is sufficiently large to generate SWEM values comparable to observations. Inconsistencies in precipitation are also found to have a strong impact on year‐to‐year variability in SWEM dataset performance and spread. Version 3.6.1 of the Canadian Land Surface Scheme land surface scheme driven with ERA‐Interim output downscaled by Version 5.0.1 of the Canadian Regional Climate Model was the best physically based model at explaining the observed spatial and temporal variability in SWEM (root‐mean‐square error [RMSE] = 33%) and has potential for lower error with adjusted precipitation. Operational snow products relying on the real‐time snow depth observing network performed poorly due to a lack of real‐time data and the strong local scale variability of point snow depth observations. The results underscore the need for more effort to be invested in improving solid precipitation estimates for use in snow hydrology applications.     

Oscillations of coronal electron traps inferred from hard X-ray data

The work of Brown and Hoyng (1975) on the betatron acceleration of hard X-ray source electrons trapped in a vibrating flux tube is generalised to include Fermi acceleration by the varying transverse field. This development can explain the trajectory of bursts in a plot of equivalent thick-target electron flux versus spectral index as inferred from observations obtained by ESRO TD1A. Specifically the loops observed in this , diagram, unexplained in Brown and Hoyng's anslysis are accounted for by a changing phase relationship between the varying field strength f(t) and magnetic scale length g(t)- Application of the formalism to the detailed TD1A observations of the large events of 1972, August 4 and 7, allows inference of the evolution of f(t), g(t) in these events.Now at: Space Sciences Laboratory, University of California, Berkeley, U.S.A.     

Abnormal quiet days and the effect of the interplanetary magnetic field on the apparent position of the Sq focus

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The effect of the IMF on the position of the Sq focus in summer has been discussed by Matsushita who found an apparent poleward motion of the focus on days when the IMF was directed away from the Sun compared to those when the IMF was directed towards the Sun. However, his analysis took no account of the well known phase variability in Sq(H) . It is shown here that if quiet days are separated into 'normal quiet days', NQDs (defined for a station on the poleward side of the focus as days when the minimum in H occurs between 0830 and 1330 LT) and 'abnormal quiet days', AQDs (minimum in H occurring outside the NQD range), then the apparent poleward motion of the focus only occurs on AQDs and even then only when the IMF is directed away from the Sun. This effect is found to occur in both summer and winter and is probably of magnetospheric origin.     

Use of Noise to Augment Training Data: A Neural Network Method of Mineral–Potential Mapping in Regions of Limited Known Deposit Examples

One of the main factors that affects the performance of MLP neural networks trained using the backpropagation algorithm in mineral-potential mapping isthe paucity of deposit relative to barren training patterns. To overcome this problem, random noise is added to the original training patterns in order to create additional synthetic deposit training data. Experiments on the effect of the number of deposits available for training in the Kalgoorlie Terrane orogenic gold province show that both the classification performance of a trained network and the quality of the resultant prospectivity map increasesignificantly with increased numbers of deposit patterns. Experiments are conducted to determine the optimum amount of noise using both uniform and normally distributed random noise. Through the addition of noise to the original deposit training data, the number of deposit training patterns is increased from approximately 50 to 1000. The percentage of correct classifications significantly improves for the independent test set as well as for deposit patterns in the test set. For example, using ±40% uniform random noise, the test-set classification performance increases from 67.9% and 68.0% to 72.8% and 77.1% (for test-set overall and test-set deposit patterns, respectively). Indices for the quality of the resultant prospectivity map, (i.e. D/A, D × (D/A), where D is the percentage of deposits and A is the percentage of the total area for the highest prospectivity map-class, and area under an ROC curve) also increase from 8.2, 105, 0.79 to 17.9, 226, 0.87, respectively. Increasing the size of the training-stop data set results in a further increase in classification performance to 73.5%, 77.4%, 14.7, 296, 0.87 for test-set overall and test-set deposit patterns, D/A, D × (D/A), and area under the ROC curve, respectively.     

Evaluating the performance of ground-based and remotely sensed near real-time rainfall fields from a hydrological perspective

Abstract

The South African Weather Service (SAWS) issues routine experimental, near real-time rainfall maps from daily raingauge networks, radar networks and satellite images, as well as merged rainfall fields. These products are potentially useful for near real-time forecasting, especially in areas of fast hydrological response, and also to simulate the “now state” of various hydrological state variables such as soil moisture content, streamflow, and reservoir inflows. The purpose of this paper is to evaluate their skill as inputs to hydrological simulations and, in particular, the skill of the merged field in terms of better hydrological results relative to the individual products. Rainfall fields derived from raingauge, radar, satellite, conditioned satellite and the merged (gauge/radar/satellite) were evaluated for two selected days with relatively high amounts of rainfall, as well as for a continuous period of 90 days in the Mgeni catchment, South Africa. Streamflows simulated with the ACRU model indicate that the use of raingauge as well as merged fields of satellite/raingauge and satellite/radars/raingauge provides relatively realistic rainfall results, without much difference in their hydrological outputs, whereas the radar and raw satellite information by themselves cannot be used in operational hydrological application in their current status.

Citation Ghile, Y., Schulze, R. & Brown, C. (2010) Evaluating the performance of ground-based and remotely sensed near real-time rainfall fields from a hydrological perspective. Hydrol. Sci. J. 55(4), 497–511.     

Late Cretaceous reactivation of major crustal shear zones in northern Namibia: constraints from apatite fission track analysis

Namibia's passive continental margin records a long history of tectonic activity since the Proterozoic. The orogenic belt produced during the collision of the Congo and Kalahari Cratons in the Early Proterozoic led to a zone of crustal weakness, which became the preferred location for tectonism during the Phanerozoic. The Pan-African Damara mobile belt forms this intraplate boundary in Namibia and its tectonostratigraphic zones are defined by ductile shear zones, where the most prominent is described as the Omaruru Lineament–Waterberg Thrust (OML–WT). The prominance of the continental margin escarpment is diminished in the area of the Central and Northern Zone of the Damara belt where the shear zones are located. This area has been targeted with a set of 66 outcrop samples over a 550-km-long, 60-km-broad coast-parallel transect from the top of the escarpment in the south across the Damara sector to the Kamanjab Inlier in the north. Apatite fission track age and length data from all samples reveal a regionally consistent cooling event. Thermal histories derived by forward modelling bracket this phase of accelerated cooling in the Late Cretaceous. Maximum palaeotemperatures immediately prior to the onset of cooling range from ca. 120 to ca. 60 °C with the maximum occurring directly south of the Omaruru Lineament. Because different palaeotemperatures indicate different burial depth at a given time, the amount of denudation can be estimated and used to constrain vertical displacements of the continental crust. We interpret this cooling pattern as the geomorphic response to reactivation of basement structures caused by a change in spreading geometry in the South Atlantic and South West Indian Oceans.     

Reassessing the formation of the inner Oort cloud in an embedded star cluster

We re-examine the formation of the inner Oort comet cloud while the Sun was in its birth cluster with the aid of numerical simulations. This work is a continuation of an earlier study (Brasser, R., Duncan, M.J., Levison, H.F. [2006]. Icarus 184, 59–82) with several substantial modifications. First, the system consisting of stars, planets and comets is treated self-consistently in our N-body simulations, rather than approximating the stellar encounters with the outer Solar System as hyperbolic fly-bys. Second, we have included the expulsion of the cluster gas, a feature that was absent previously. Third, we have used several models for the initial conditions and density profile of the cluster – either a Hernquist or Plummer potential – and chose other parameters based on the latest observations of embedded clusters from the literature. These other parameters result in the stars being on radial orbits and the cluster collapses. Similar to previous studies, in our simulations the inner Oort cloud is formed from comets being scattered by Jupiter and Saturn and having their pericentres decoupled from the planets by perturbations from the cluster gas and other stars. We find that all inner Oort clouds formed in these clusters have an inner edge ranging from 100 AU to a few hundred AU, and an outer edge at over 100,000 AU, with little variation in these values for all clusters. All inner Oort clouds formed are consistent with the existence of (90377) Sedna, an inner Oort cloud dwarf planetoid, at the inner edge of the cloud: Sedna tends to be at the innermost 2% for Plummer models, while it is 5% for Hernquist models. We emphasise that the existence of Sedna is a generic outcome. We define a ‘concentration radius’ for the inner Oort cloud and find that its value increases with increasing number of stars in the cluster, ranging from 600 AU to 1500 AU for Hernquist clusters and from 1500 AU to 4000 AU for Plummer clusters. The increasing trend implies that small star clusters form more compact inner Oort clouds than large clusters. We are unable to constrain the number of stars that resided in the cluster since most clusters yield inner Oort clouds that could be compatible with the current structure of the outer Solar System. The typical formation efficiency of the inner Oort cloud is 1.5%, significantly lower than previous estimates. We attribute this to the more violent dynamics that the Sun experiences as it rushes through the centre of the cluster during the latter’s initial phase of violent relaxation.     

变质作用、板块构造及超级大陆旋回

麻粒岩相超高温变质作用（GUHTM）主要发育于新太古代至寒武纪岩石中;推测在深部较年轻的,特别是新生代造山带岩石中也会有GUHTM存在。岩石中最初出现GUHTM记录意味着产生瞬时极高热流处的地球动力学发生了改变。许多GUHTM带可能发育于类似现代大陆弧后的构造背景中。在较热的地球上,超大陆及其裂解形成的循环组合,尤其是经岩石圈减薄的洋盆卷入到其外翻过程中可能产生比现代太平洋边缘更热的大陆弧后。中温榴辉岩 高压麻粒岩相变质作用（EHPGM）也是最先发现于新太古代岩石记录中,并发育于从元古宙至古生代岩石中。EHPGM带是对GUHTM带的补充,并经常认为是记录了从俯冲至碰撞造山作用的过程。在元古宙岩石记录中的蓝片岩明显记录了与现代俯冲作用相关的低热流梯度。以发育柯石英(±硬柱石)或金刚石为特征的硬柱石蓝片岩和榴辉岩（高压变质作用,HPM）及超高压变质岩（UHPM）主要是在显生宙形成。HPMUHPM记录了显生宙俯冲碰撞造山带早期碰撞过程中的低热流梯度及陆壳的深俯冲作用。尽管与直觉不同,在超级大陆聚敛期（Wilson旋回洋盆打开和关闭）的大陆地块增生过程,许多HPMUHPM带看来确实是通过小洋盆关闭而发育起来的,反映双重热体制的双重变质带仅发育于新太古代以来的岩石记录中。双重热体制是现代板块构造的特点,而双重变质作用则是板块构造在岩石记录中的特征性标志。尽管构造样式很可能不同,新太古代以来GUHTM和EHPGM带的发育证明“元古宙板块构造体制”的开始。以冷俯冲和大陆地壳深俯冲至地幔,以及其中的部分又从深达300 km处发生折返为标志,“元古宙板块构造体制”在新元古代进化为“现代板块构造体制”,这个转变可由岩石中的HPMUHPM证明。记录这种极端条件的变质带年龄是不一致的,而变质作用发生时间与各大陆岩石圈聚合到超级克拉通（如Superia/Sclavia）或超级大陆（如Nuna (Columbia), Rodinia, Gondwana, 和Pangea）的时间却是一致的。