Exsolution and shock microstructures of igneous pyroxene clasts in the Northwest Africa 7533 Martian meteorite

Northwest Africa (NWA) 7533 is a Martian regolith breccia. This meteorite (and its pairings) offers a good opportunity to study (near‐) surface processes that occurred on early Mars. Here, we have conducted a transmission electron microscope study of medium‐ and coarse‐grained (a few tens to hundreds of micrometers) Ca‐rich pyroxene clasts in order to define their thermal and shock histories. The pyroxene grains have a high‐temperature (magmatic) origin as revealed by the well‐developed pigeonite–augite exsolution microstructure. Exsolution lamella characteristics (composition, thickness, and spacing) indicate a moderately slow cooling. Some of the pyroxene clasts display evidence for local decomposition into magnetite and silica at the submicron scale. This phase decomposition may have occurred at high temperature and occurred at high oxygen fugacity at least 2–3 log units above the QFM buffer, after the formation of the exsolution lamellae. This corresponds to oxidizing conditions well above typical Martian magmatic conditions. These oxidizing conditions seem to have prevailed early and throughout most of the history of NWA 7533. The shock microstructure consists of (100) mechanical twins which have accommodated plastic deformation. Other pyroxene shock indicators are absent. Compared with SNC meteorites that all suffered significant shock metamorphism, NWA 7533 appears only mildly shocked. The twin microstructure is similar from one clast to another, suggesting that the impact which generated the (100) twins involved the compacted breccia and that the pyroxene clasts were unshocked when they were incorporated into the NWA 7533 breccia.     

A Multi-Wavelength Study of the 3B/X1.2 Flare Observed on 2003 October 26

We report results from a multi-wavelength study of the 3B/X1.2 two-ribbon disk flare (S15E44), which was well observed by both ground-based and space-borne instruments. Two pairs of conjugate kernels - K1 and K4, and K2 and K3 - in the Ha images are identified. These kernels are linked by two different systems of EUV loops. Kl and K4 correspond to the two 17 GHz and 34 GHz microwave sources observed by the Nobeyama Radioheliograph (NoRH), while K2 and K3 have no corresponding microwave sources. Optical spectroscopic observations suggest that all the four kernels are possible precipitating sites of non-thermal electrons. Thus the energy of electron deposited in K2 and K3 should be less than 100 keV. Two-dimensional distributions of the full widths at half maximum (FWHM) of the Ha profiles and the line-of-sight (LOS) velocities derived from the Ca Ⅱ 8542 (?) profiles indicate that the largest FWHM and LOS velocity tends to be located near the outer edges of Ha kernels, which is consistent with the scenario of current two-ribbon flare models and previous results. When non-thermal electron bombardment is present, the observed Ha and Ca Ⅱ 8542 (?) profiles are similar to previous observational and theoretical results, while the He I 10830 A profiles are different from the theoretical ones. This puts some constraints on future theoretical calculation of the He I 10830 (?) line.     

Elimination of Zinc from Roof Runoff through Geotextile and Clinoptilolite Filters

Direct infiltration of roof runoff into the ground may pose a potential risk of soil and groundwater contamination. The performance of two different barrier materials for the retention of zinc from roof runoff of an eleven year old zinc roof was examined in a field study. As barrier materials geotextile and clinoptilolite were applied. Automatic samplers were used to take samples both at the inlet and at the outlet of the retention facility. Samples of twenty rain events were examined. Zinc was detected in the roof runoff in concentrations of up to 25 mg/L, and lead which originates from the tin‐solder was present in concentrations of up to 84 μg/L. Under most circumstances, a first flush could be observed for the analysed substances. No retention of heavy metals was observed, where only geotextile was used as a barrier material. The clinoptilolite filter was able to adsorb up to 97 % of zinc from the roof runoff.     

Historical analysis (2000-2005) of the coastal water quality in San Andrés Island, SeaFlower Biosphere Reserve, Caribbean Colombia

To understand the coastal water quality of San Andrès Island, and provide tools for the management of its marine resources, we present the historical analysis of the island monitoring, which includes ammonia, nitrites, nitrate, phosphates, fecal and total coliforms. The anthropogenic pressure on the coastal system is heavy, with water nutrification, posing at risk seagrass and coral ecosystems. During dry season, biologically available nitrogen is 3-9 times higher than the maximum recommended for coral reefs, while during wet season values are 2-6.4 times the maximum. Biologically available phosphorous is also high, 1-8 times the maximum during dry season, 2-13 times during wet season. In some sites the concentration of pathogenic bacteria is above the limits set by law for primary and secondary contact. It is urgent to improve the management of sewage discharge, the main polluting source of San Andres coastal waters.     

Safeguarding the future marine environment of Europe

The priorities for the protection of the seas have been discussed extensively. Many consider that the problem of marine pollution can only be solved on the basis of joint international actions. This is particularly true for the various countries bordering on the North Sea. To implement such ‘Joint Actions’, a new understanding of safety, namely ‘global maritime safety’ should be discussed with all those involved.     

On the repeatability and consistency of three-component ambient vibration array measurements

Ambient vibration measurements with small, temporary arrays that produce estimates of surface wave dispersion have become increasingly popular as a low-cost, non-invasive tool for site characterisation. An important requirement for these measurements to be meaningful, however, is the temporal consistency and repeatability of the resulting dispersion and spatial autocorrelation curve estimates. Data acquired within several European research projects (NERIES task JRA4, SESAME, and other multinational experiments) offer the chance to investigate the variability of the derived data products. The dataset analysed here consists of repeated array measurements, with several years of time elapsed between them. The measurements were conducted by different groups in different seasons, using different instrumentations and array layouts, at six sites in Greece and Italy. Ambient vibration amplitude spectra and locations of dominant sources vary between the two measurements at each location. Still, analysis indicates that this does not influence the derived dispersion information, which is stable in time and neither influenced by the instrumentation nor the analyst. The frequency range over which the dispersion curves and spatial autocorrelation curves can be reliably estimated depends on the array dimensions (minimum and maximum aperture) used in the specific deployment, though, and may accordingly vary between the repeated experiments. The relative contribution of Rayleigh and Love waves to the wavefield can likewise change between repeated measurements. The observed relative contribution of Rayleigh waves is generally at or below 50%, with especially low values for the rural sites. Besides, the visibility of higher modes depends on the noise wavefield conditions. The similarity of the dispersion and autocorrelation curves measured at each site indicates that the curves are stable, mainly determined by the sub-surface structure, and can thus be used to derive velocity information with depth. Differences between velocity models for the same site derived from independently determined dispersion and autocorrelation curves—as observed in other studies—are consequently not adequately explained by uncertainties in the measurement part.     

High resolution spectra of galaxies

We present inversion techniques which aim at recovering the composite nature and the kinematics of a stellar population from its high resolution absorption line spectrum. The originality of the combined inversion is its potential to recover both the stellar content and the kinematics simultaneously. These techniques use new synthetic high resolution spectra produced by PéGASE and minimization algorithms. We apply them to mock data representing the bulge and disk population of the inner region of spiral galaxies. This revised version was published online in August 2006 with corrections to the Cover Date.     

Spatial interpretation of high-resolution environmental proxy data of the Middle Pleistocene Palaeolithic faunal kill site Schöningen 13 II-4, Germany

To spatially characterize the palaeolakeshore environment at the archaeological kill site Schöningen 13 II-4 of the Middle Pleistocene Reinsdorf sequence, in-depth palynological, geochemical, aquatic microfossil and archaeological analyses were undertaken on sediment sections with an average thickness of about 15 cm, concordantly overlain by faunal remains, dominated by horse, from the unique ‘Spear Horizon’ layers of the 1995 excavation campaign. The data reveal a distinctive lake level drop, documented by the change from a carbonate-rich lake marl to a carbonate-free organic mud with increased carbon content and decreasing C/N, Si/Al, Si/K and Fe/Al ratios, indicating a higher pedogenic supply of organic matter and drier conditions at the site. Compared with older, similar transitional phases of lake level changes occurring within the Reinsdorf sequence, it is important that these youngest sediments are undisturbed, indicating continuous development. Ostracod and diatom analyses indicate a lowering water level with higher salinities and rich aquatic vegetation. Mesorheophilic ostracod species along with tychoplanktic diatom taxa point to flowing waters and turbulence at the lakeshore, presumably related to spring-fed streams originating from nearby highlands. Palynological results reveal a very diverse zonal vegetation pattern around the palaeolakeshore considering an area of investigation of approximately 50 × 75 m and a tessellated type of regional vegetation during the formation of the archaeological horizons. On topographically lower elevated areas, birch groves and taxa favouring wet, marshy conditions such as Cyperaceae, indicative of terrestrialization, were predominating, while other stands of this transitional phase reveal a very dry, grass-dominated steppe woodland favouring a rich wildlife with a striking number of megaherbivores. Our results suggest that the lithological differences of the ‘Spear Horizon’ layers containing the archaeological finds were due to their respective topographical situation and that the layers were deposited almost simultaneously during the beginning of the lake level drop. Human activities seem to have concentrated in sparsely vegetated areas along the palaeolakeshore, rather than in areas of adjacent denser birch swamp forest stands.     

Determination of Reference Values for NIST SRM 610–617 Glasses Following ISO Guidelines

We present new reference values for the NIST SRM 610–617 glasses following ISO guidelines and the International Association of Geoanalysts’ protocol. Uncertainties at the 95% confidence level (CL) have been determined for bulk‐ and micro‐analytical purposes. In contrast to former compilation procedures, this approach delivers data that consider present‐day requirements of data quality. New analytical data and the nearly complete data set of the GeoReM database were used for this study. Data quality was checked by the application of the Horwitz function and by a careful investigation of analytical procedures. We have determined quantitatively possible element inhomogeneities using different test portion masses of 1, 0.1 and 0.02 μg. Although avoiding the rim region of the glass wafers, we found moderate inhomogeneities of several chalcophile/siderophile elements and gross inhomogeneities of Ni, Se, Pd and Pt at small test portion masses. The extent of inhomogeneity was included in the determination of uncertainties. While the new reference values agree with the NIST certified values with the one exception of Mn in SRM 610, they typically differ by as much as 10% from the Pearce et al. (1997) values in current use. In a few cases (P, S, Cl, Ta, Re) the discrepancies are even higher.