Assessing changes in nutrient status in the Richmond River estuary,Australia, using paleolimnological methods

Eutrophication from nutrient over-enrichment is a serious problem for the coastal zone and the estuarine environment globally. Australian estuaries are generally oligotrophic, but assessing whether they are becoming more eutrophic over time is inhibited by a lack of long-term monitoring data. The Richmond River, Australia, provided an ideal example of an estuary under anthropogenic pressure where the use of paleoecological techniques may potentially be used to reconstruct changes in nutrient status over time. Five cores were extracted from depositional areas in the Richmond River, and subjected to paleo-magnetic profiling and loss-on-ignition testing to ensure the core of greatest integrity was selected for further analytical work. Results from diatom and stable isotope analyses combined with ²¹⁰Pb and AMS ¹⁴C dating show a strong indication that the total phosphorus levels in the Richmond River have fluctuated since 1940. Evidence also suggests that these fluctuations are most likely a function of climate. This study has successfully applied paleolimnological techniques to the estuarine environment to produce information that can be used by environmental managers to aid decision making in relation to nutrient control for the Richmond River. Further work using paleolimnological techniques should be aimed at the extraction of a core containing diatoms that pre-date European settlement and include analyses of specific lipids and fatty acid biomarkers.     

Ancient graphite in the Eoarchean quartz-pyroxene rocks from Akilia in southern West Greenland I: Petrographic and spectroscopic characterization

Because all known Eoarchean (>3.65 Ga) volcano-sedimentary terranes are locked in granitoid gneiss complexes that have experienced high degrees of metamorphism and deformation, the origin and mode of preservation of carbonaceous material in the oldest metasedimentary rocks remain a subject of vigorous debate. To determine the biogenicity of carbon in graphite in such rocks, carbonaceous material must be demonstrably indigenous and its composition should be consistent with thermally altered biogenic carbon as well as inconsistent with abiogenic carbon. Here we report the petrological and spectroscopic characteristics of carbonaceous material, typically associated with individual apatite grains, but also with various other minerals including calcite, in a >3.83 Ga granulite-facies ferruginous quartz-pyroxene unit (Qp rock) from the island of Akilia in southern West Greenland. In thin sections of the fine-grained parts of Akilia Qp rock sample G91-26, mapped apatites were found to be associated with graphite in about 20% of the occurrences. Raman spectra of this carbonaceous material had strong G-band and small D-band absorptions indicative of crystalline graphite. Three apatite-associated graphites were found to contain curled graphite structures, identified by an anomalously intense second-order D-band (or 2D-band) Raman mode. These structures are similar to graphite whiskers or cones documented to form at high temperatures. Raman spectra of apatite-associated graphite were consistent with formation at temperatures calculated to be between 635 and 830 °C, which are consistent with granulite-facies metamorphic conditions. Three graphite targets extracted by focused ion beam (FIB) methods contained thin graphite coatings on apatite grains rather than inclusions sensu stricto as inferred from transmitted light microscopy and Raman spectroscopy. TEM analyses of graphite in these FIB sections showed a (0 0 0 2) interplanar spacing between 3.41 and 3.64 Å for apatite-associated graphite, which is larger than the spacing of pure graphite (3.35 Å) and may be caused by the presence of non-carbon heteroatoms in interlayer sites. Samples analyzed by synchrotron-based scanning transmission X-ray microscopy (STXM) also confirmed the presence of crystalline graphite, but abundances of N and O heteroatoms were below detection limit for this method. Graphite in the Akilia Qp rock was also found to occur in complex polyphase mineral assemblages of hornblende ± calcite ± sulfides ± magnetite that point to high-temperature precipitation from carbon-bearing fluids. These complex mineral assemblages may represent another generation of graphitization that could have occurred during the amphibolite-facies metamorphic event at 2.7 Ga. Several observations point to graphitization from high-temperature fluid-deposition for some of the Akilia graphite and our results do not exclude a biogenic source of carbon in graphite associated with apatite, but ambiguities remain for the origin of this carbon.     

The OSL chronology of eolian sand deposition in a perched dune field along the northwestern shore of Lower Michigan

Extensive coastal dunes occur in the Great Lakes region of North America, including northwestern Michigan where some are perched on high (~ 100 m) bluffs. This study focuses on such a system at Arcadia Dunes and is the first to systematically generate optical ages from stratigraphic sections containing buried soils. Dune growth began ca. 4.5 ka during the Nipissing high lake stand and continued episodically thereafter, with periods of increased sand supply at ca. 3.5 ka and ca. 1.7 ka. The most volumetrically dominant phase of dune growth began ca. 1.0 ka and continued intermittently for about 500 years. It may have begun due to the combined effects of a high lake phase, potential changes in lake hydrodynamics with final isostatic separation of Lake Superior from Lakes Michigan and Huron, and increased drought and hydrologic variability associated with the Medieval Warm Period. Thus, this latest eolian phase likely reflects multiple processes associated with Great Lakes water level and climate variability that may also explain older eolian depositional events. Comparison of Arcadia ages and calendar corrected ¹⁴C ages from previous studies indicate broad chronological agreement between events at all sites, although it appears that dune growth began later at Arcadia.     

Isotopic and Elemental Composition of Marine Macrophytes as Biotracers of Nutrient Recycling Within a Coastal Lagoon in Baja California,Mexico

Nutrient sources of San Quintin Bay, a coastal lagoon affected by coastal upwelling off Baja California (Mexico), were traced using generalized additive (mixed) models (GAMM) to the stable nitrogen isotopic composition, C:N and N content of two co-occurring macrophytes (the macroalgae Ulva spp. and the seagrass Zostera marina). The geochemical tracers followed a spatial trend that partly responded to the long-term nutrient gradient from the ocean towards the interior of the bay. N content in Z. marina and Ulva spp. decreased linearly (while C:N increased) towards the middle section of the bay to concentration levels that indicate potential N limitation for growth. Concurrently midway into the bay (6–9 km), the δ¹⁵N of both macrophytes showed a gradual enrichment in ¹⁵N reflecting progressive denitrification. The spatial pattern of δ¹⁵N and the decrease in C:N of the macrophytes towards the innermost section of the bay indicated an additional nonoceanic source of dissolved nitrogen in this zone. The similarity of the δ¹⁵N pattern of Z. marina and Ulva spp. implies that their δ¹⁵N composition is mainly controlled by the availability of N, in spite of the physiological differences between taxa. A better fit of GAMM to N content and C:N was obtained for Z. marina than for Ulva spp. indicating that the former delineate more steadily and smoothly the influence of upwelling along the spatial gradient. Nonetheless, Ulva spp. may be analyzed in combination with Z. marina to characterize the environmental conditions at the time of sampling.     

Turbulence Reynolds number and the turbulent kinetic energy balance in the atmospheric surface layer

The relation between the turbulence Reynolds numberR and a Reynolds numberz* based on the friction velocity and height from the ground is established using direct measurements of the r.m.s. longitudinal velocity and turbulent energy dissipation in the atmospheric surface layer. Measurements of the relative magnitude of components of the turbulent kinetic energy budget in the stability range 0 >z/L 0.4 indicate that local balance between production and dissipation is maintained. Approximate expressions, in terms of readily measured micrometeorological quantities, are proposed for the Taylor microscale and the Kolmogorov length scale .     

Wind variations in Jupiter's equatorial atmosphere: A QQO counterpart?

Jupiter's equatorial atmosphere, much like the Earth's, is known to show quasi-periodic variations in temperature, particularly in the stratosphere, but variations in other jovian atmospheric tracers have not been studied for any correlations to these oscillations. Data taken at NASA's Infrared Telescope Facility (IRTF) from 1979 to 2000 were used to obtain temperatures at two levels in the atmosphere, corresponding to the upper troposphere (250 mbar) and to the stratosphere (20 mbar). We find that the data show periodic signals at latitudes corresponding to the troposphere zonal wind jets, with periods ranging from 4.4 (stratosphere, 95% confidence at 4° S planetographic latitude) to 7.7 years (troposphere, 97% confidence at 6° N). We also discuss evidence that at some latitudes the troposphere temperature variations are out of phase from the stratosphere variations, even where no periodicity is evident. Hubble Space Telescope images were used, in conjunction with Voyager and Cassini data, to track small changes in the troposphere zonal winds from 20° N to 20° S latitude over the 1994-2000 time period. Oscillations with a period of 4.5 years are found near 7°-8° S, with 80-85% significance. Further, the strongest evidence for a QQO-induced tropospheric wind change tied to stratospheric temperature change occurs near these latitudes, though tropospheric temperatures show little periodicity here. Comparison of thermal winds and measured zonal winds for three dates indicate that cloud features at other latitudes are likely tracked at pressures that can vary by up to a few hundred millibar, but the cloud altitude change required is too large to explain the wind changes measured at 7° S.     

Flowpath Independent Monitoring of Reductive Dechlorination Potential in a Fractured Rock Aquifer

The flowpath dependent approaches that are typically employed to assess biodegradation of chloroethene contaminants in unconsolidated aquifers are problematic in fractured rock settings, due to difficulties defining discrete groundwater flowpaths in such systems. In this study, the variation in the potential for chloroethene biodegradation with depth was evaluated in a fractured rock aquifer using two flowpath independent lines of field evidence: (1) the presence of the three biochemical prerequisites [electron donor(s), chloroethene electron acceptor(s), and chlororespiring microorganism(s)] for efficient chloroethene chlororespiration and (2) the in situ accumulation of chloroethene reductive dechlorination daughter products. The validity of this approach was assessed by comparing field results with the results of [1, 2-¹⁴C] cis -DCE microcosm experiments. Microcosms were prepared with depth-specific core material, which was crushed and emplaced in discrete packer intervals for 1 year to allow colonization by the indigenous microbial community. Packer intervals characterized by significant electron donor concentrations, elevated numbers of chlororespiring microorganisms, and high reductive dechlorination product to parent contaminant ratios correlated well with the production of ¹⁴C-labeled reductive dechlorination products in the microcosm experiments. These results indicate that, in the absence of information on discrete groundwater flowpaths, a modified approach emphasizing flowpath independent lines of evidence can provide insight into the temporal and spatial variability of contaminant biodegradation in fractured rock systems.     

Error estimation of closed‐form solution for annual rate of structural collapse

With the increasing emphasis of performance‐based earthquake engineering in the engineering community, several investigations have been presented outlining simplified approaches suitable for performance‐based seismic design (PBSD). Central to most of these PBSD approaches is the use of closed‐form analytical solutions to the probabilistic integral equations representing the rate of exceedance of key performance measures. Situations where such closed‐form solutions are not appropriate primarily relate to the problem of extrapolation outside of the region in which parameters of the closed‐form solution are fit. This study presents a critical review of the closed‐form solution for the annual rate of structural collapse. The closed‐form solution requires the assumptions of lognormality of the collapse fragility and power model form of the ground motion hazard, of which the latter is more significant regarding the error of the closed‐form solution. Via a parametric study, the key variables contributing to the error between the closed‐form solution and solution via numerical integration are illustrated. As these key variables cannot be easily measured, it casts doubt on the use of such closed‐form solutions in future PBSD, especially considering the simple and efficient nature of using direct numerical integration to obtain the solution. Copyright © 2008 John Wiley & Sons, Ltd.