Persistent organic pollutants and stable isotopes in biopsy samples (2004/2006) from Southern Resident killer whales

“Southern Resident” killer whales include three “pods” (J, K and L) that reside primarily in Puget Sound/Georgia Basin during the spring, summer and fall. This population was listed as “endangered” in the US and Canada following a 20% decline between 1996 and 2001. The current study, using blubber/epidermis biopsy samples, contributes contemporary information about potential factors (i.e., levels of pollutants or changes in diet) that could adversely affect Southern Residents. Carbon and nitrogen stable isotopes indicated J- and L-pod consumed prey from similar trophic levels in 2004/2006 and also showed no evidence for a large shift in the trophic level of prey consumed by L-pod between 1996 and 2004/2006. ∑PCBs decreased for Southern Residents biopsied in 2004/2006 compared to 1993–1995. Surprisingly, however, a three-year-old male whale (J39) had the highest concentrations of ∑PBDEs, ∑HCHs and HCB. POP ratio differences between J- and L-pod suggested that they occupy different ranges in winter.     

Hydrologic significance of carbon monoxide concentrations in ground water

Dissolved carbon monoxide (CO) is present in ground water produced from a variety of aquifer systems at concentrations ranging from 0.2 to 20 nanomoles per liter (0.0056 to 0.56 microg/L). In two shallow aquifers, one an unconsolidated coastal plain aquifer in Kings Bay, Georgia, and the other a fractured-bedrock aquifer in West Trenton, New Jersey, long-term monitoring showed that CO concentrations varied over time by as much as a factor of 10. Field and laboratory evidence suggests that the delivery of dissolved oxygen to the soil zone and underlying aquifers by periodic recharge events stimulates oxic metabolism and produces transiently high CO concentrations. In between recharge events, the aquifers become anoxic and more substrate limited, CO is consumed as a carbon source, and CO concentrations decrease. According to this model, CO concentrations provide a transient record of oxic metabolism affecting ground water systems after dissolved oxygen has been fully consumed. Because the delivery of oxygen affects the fate and transport of natural and anthropogenic contaminants in ground water, CO concentration changes may be useful for identifying predominantly anoxic ground water systems subject to periodic oxic or microaerophilic conditions.     

A simple pore water hydrogen diffusion syringe sampler

Molecular hydrogen (H(2)) is an important intermediate product and electron donor in microbial metabolism. Concentrations of dissolved H(2) are often diagnostic of the predominant terminal electron-accepting processes in ground water systems or aquatic sediments. H(2) concentrations are routinely measured in ground water monitoring wells but are rarely measured in saturated aquatic sediments due to a lack of simple and practical sampling methods. This report describes the design and development (including laboratory and field testing) of a simple, syringe-based H(2) sampler in (1) saturated, riparian sediments, (2) surface water bed sediments, and (3) packed intervals of a fractured bedrock borehole that are inaccessible by standard pumped methods.     

Recommendations for a system to photograph core segments and create stitched images of complete cores

High-resolution digital imagery of sediment cores increases researchers’ ability to examine, review, and disseminate complex and meaningful core data. The high cost of commercial core scanning systems currently limits the number of cores that are imaged. Here, we present a simple, inexpensive system that can be built in almost any laboratory environment and used to create complete core images. This system uses a stationary light source and a moving core tray (sledge) which provides for consistent lighting across multiple images. Polarized lens filters and diffuse light are used to minimize glare on the core surface. Our system also repurposes professionally engineered exercise equipment which, provides for precise core and camera movement. Once images are taken, stitching software is used to create the final core image. While there are many stitching programs on the market, none are explicitly aimed at stitching together many images in a single, straight line. We evaluated seven of the most common stitching programs and identified Hugin as the most useful for creating completed core images.     

Relative sea‐level observations in western Scotland since the Last Glacial Maximum for testing models of glacial isostatic land movements and ice‐sheet reconstructions

Observations of relative sea‐level change and local deglaciation in western Scotland provide critical constraints for modelling glacio‐isostatic rebound in northern Britain over the last 18 000 years. The longest records come from Skye, Arisaig and Knapdale with a shorter, Holocene, record from Kintail. Biostratigraphic (diatom, pollen, dinoflagellate, foraminifera and thecamoebian), lithological and radiocarbon analyses provide age and elevation parameters for each sea‐level index point. All four sites reveal relative sea‐level change that is highly non‐monotonic in time as the local vertical component of glacio‐isostatic rebound and eustasy (or global meltwater influx) dominate at different periods. Copyright © 2006 John Wiley & Sons, Ltd.     

Relative sea‐level changes,glacial isostatic modelling and ice‐sheet reconstructions from the British Isles since the Last Glacial Maximum

While contributing <1 m equivalent eustatic sea‐level rise the British Isles ice sheet produced glacio‐isostatic rebound in northern Britain of similar magnitude to eustatic sea‐level change, or global meltwater influx, over the last 18 000 years. The resulting spatially variable relative sea‐level changes combine with observations from far‐field locations to produce a rigorous test for quantitative models of glacial isostatic adjustment, local ice‐sheet history and global meltwater influx. After a review of the attributes of relative sea‐level observations significant for constraining large‐scale models of the isostatic adjustment process we summarise long records of relative sea‐level change from the British Isles and far‐field locations. We give an overview of different global theoretical models of the isostatic adjustment process before presenting intercomparisons of observed and predicted relative sea levels at sites in the British Isles and far‐field for a range of Earth and ice model parameters in order to demonstrate model sensitivity and the resolving power available from using evidence from the British Isles. For the first time we show a good degree of fit between relative sea‐level observations and predictions that are based upon global Earth and ice model parameters, independently derived from analysis of far‐field data, with a terrain‐corrected model of the British Isles ice sheet that includes extensive glaciation of the North Sea and western continental shelf, that does not assume isostatic equilibrium at the Last Glacial Maximum and keeps to trimline constraints of ice surface elevation. We do not attempt to identify a unique solution for the model lithosphere thickness parameter or the local‐scale detail of the ice model in order to provide a fit for all sites, but argue that the next stage should be to incorporate an ice‐sheet model that is based on quantitative, glaciological model simulations. We hope that this paper will stimulate this debate and help to integrate research in glacial geomorphology, glaciology, sea‐level change, Earth rheology and quantitative modelling. Copyright © 2006 John Wiley & Sons, Ltd.     

Simultaneous spaced direction-finding measurements of medium-latitude VLF/ELF emissions

Simultaneous spaced measurements of medium-latitude VLF/ELF emissions were carried out during the three northern winters from 1976 to 1979. The experiment was making use of two different kinds of direction-finding systems (a field-analysis method and a goniometer network) at two stations in Europe, namely Brorfelde in Denmark (L = 2.9) and Chambron-la-Foret in France (L = 1.9); this enabled us to locate the ionospheric exit regions of emissions over a wide range of L-values up to and beyond 4.0, the average plasmapause location. In order to study the time delay in the temporal evolution of VLF emissions or the longitudinal drift of the emissions, observations from the Moshiri Observatory in Japan, widely separated in longitude, are also used. The overall system of the VLF equipment installed at the three stations is described. Then we present the VLF/ELF data of good quality obtained during the final year's campaign (Nov. 1978–Feb. 1979). By making use of the direction-finding data, we were able to classify the observed emissions into several categories, and some early results for some of the emissions are presented.     

15,000-yr pollen record of vegetation change in the high altitude tropical Andes at Laguna Verde Alta, Venezuela

Pollen analysis of sediments from a high-altitude (4215 m), Neotropical (9°N) Andean lake was conducted in order to reconstruct local and regional vegetation dynamics since deglaciation. Although deglaciation commenced 15,500 cal yr B.P., the area around the Laguna Verde Alta (LVA) remained a periglacial desert, practically unvegetated, until about 11,000 cal yr B.P. At this time, a lycopod assemblage bearing no modern analog colonized the superpáramo. Although this community persisted until 6000 cal yr B.P., it began to decline somewhat earlier, in synchrony with cooling following the Holocene thermal maximum of the Northern Hemisphere. At this time, the pioneer assemblage was replaced by a low-diversity superpáramo community that became established 9000 cal yr B.P. This replacement coincides with regional declines in temperature and/or available moisture. Modern, more diverse superpáramo assemblages were not established until 4600 cal yr B.P., and were accompanied by a dramatic decline in Alnus, probably the result of factors associated with climate, humans, or both. Pollen influx from upper Andean forests is remarkably higher than expected during the Late Glacial and early to middle Holocene, especially between 14,000 and 12,600 cal yr B.P., when unparalleled high values are recorded. We propose that intensification of upslope orographic winds transported lower elevation forest pollen to the superpáramo, causing the apparent increase in tree pollen at high altitude. The association between increased forest pollen and summer insolation at this time suggests a causal link; however, further work is needed to clarify this relationship.