RECOVERY AND CLASSIFICATION OF THIRTY NEW METEORITES FROM ROOSEVELT COUNTY,NEW MEXICO

We report the discovery and classification of 30 new meteorites found in or close to Roosevelt County, New Mexico, including two H3 chondrites and a ureilite; the others are equilibrated ordinary chondrites. Over 160 meteorites representing at least 100 different falls have been recovered from this region, mostly from wind blowout areas. As in Antarctica, small specimens predominate and irons, achondrites and C and E chondrites are rare. Paired specimens are also very difficult to identify.     

Regional landslide risk to the Cairns community

A GIS-based regional reconnaissance-level assessment of landslide risk to the Cairns community has been carried out to provide information to the Cairns City Council for planning and emergency management purposes. Magnitude recurrence relations were tentatively established for the two main slope processes: landslides on the hill slopes; and large debris flows extending out from the gully systems on to the plains. From the recurrence relations, landslide hazard (H) was estimated as the annual probability of a point being impacted by a landslide. The nature, number (E) and geographic distribution of the elements at risk were obtained by interrogating the GIS, and their vulnerabilities (V) to destruction by the two main landslide slope processes were assessed. From this information, specific risk (= H × V) and total risk (= H × V× E) maps were produced.Although total landslide risk is relatively low at present, it will increase as development extends further into the hill slopes, unless adequate mitigation measures are taken. Large debris flows, while considerably less frequent than landslides on cut slopes, could impact on subdivisions at the base of the slopes. Blockage by landslides of roads and railways providing access to Cairns can cause isolation of the community. Flash flooding in Freshwater Creek, or debris flows, have the potential to disrupt the Cairns water supply by blocking the intake or destroying sections of the pipeline.     

An estuarine benthic index of biotic integrity for the Mid-Atlantic region of the United States. I. Classification of assemblages and habitat definition

An objective of the Mid-Atlantic Integrated Assessment Program (MAIA) of the U.S. Environmental Protection Agency is to develop an index for assessing benthic community condition in estuaries of the mid-Atlantic region of the United States (Delaware Bay through Pamlico Sound). To develop such an index, natural unimpaired communities must first be identified and variability related to natural factors accounted for. This study focused on these two objectives; Lnansó et al. (2002) describe the index. Using existing data sets from multiple years, classification analyses of species abundance and discriminant analysis were employed to identify major habitat types in the MAIA region and evaluate the physical characteristics that structure benthic infaunal assemblages. Sampling was restricted to soft bottoms and to the index development period, July through early October. The analyses revealed salinity and sediment composition as major factors structuring infaunal assemblages in mid-Atlantic estuaries. Geographical location was a secondary factor. Nine habitat classes were distinguished as a combination of 6 salinity classes, 2 sediment types, and the separation of North Carolina and Delaware-Chesapeake Bay polyhaline sites. The effect of sediment types on faunal assemblages was restricted to polyhaline sites, which were separated into two sediment groups above and below 90% sand content. Assemblages corresponding to each of these 9 habitats were identified in the context of widely recognized patterns of dominant taxa. Differences between North Carolina and Delaware-Chesapeake Bay polyhaline assemblages were attributed to the relative contributions of species and not to differences in species composition. No zoogeographic discontinuities could be identified. Our results reinforce the findings of recent studies which suggest that, with respect to estuarine benthic assemblages, the boundary between the Virginian and the Carolinian Provinces be moved to a new location south of Pamlico Sound.     

Detection of fluorescent compounds in the environment using granular activated charcoal detectors

Granular activated charcoal (GAC) acts as a general adsorptive medium for organic molecules, and is widely used to capture fluorescent tracer dyes. To investigate the capability of GAC in contaminant screening and tracer adsorption, a number of detectors were deployed for 2-6 days in a range of urban surface waters, and the adsorbed compounds eluted in an alkaline alcohol solution. Simultaneous water samples showed a diverse range of fluorescence environments, ranging from relatively clean, steady groundwater discharge, to highly concentrated and variable treated municipal sewage. A wide variety of organic compounds and dyes were found in the waters, as chronic and acute contaminants. The relationship between charcoal and water spectra depended on exposure time and loading. Short exposure times emphasized short wavelengths, longer exposure times emphasized longer wavelengths at the expense of shorter wavelengths. The magnitude of the effect depended on loading, being greater in enriched waters. In general, charcoal eluent shows a significant gain in fluorescence intensity over water. However, there may be an apparent loss at shorter wavelengths for samples with long exposure times and high loading. A similar bias was also discovered with the elution time of activated charcoal. Short wavelength fluorescence intensity peaked after a few minutes of elution; longer wavelength fluorescence increased over many days. These results show that charcoal is a reasonably effective material for adsorption of longer wavelength compounds. However, the ubiquity of many fluorescent dyes in the environment, and the complex relationship between the waters and the eluent spectrum, suggest that considerable care is required in the interpretation of eluent spectra.     

A Raman spectroscopic study of arsenite and thioarsenite species in aqueous solution at 25°C

The Raman spectra of thioarsenite and arsenite species in aqueous solution were obtained at room temperature. Solutions at constant ΣAs + ΣS of 0.1 and 0.5 mol kg^-1 were prepared with various ΣS/ΣAs ratios (0.1–9.0) and pH values (~7–13.2). Our data suggest that the speciation of As under the conditions investigated is more complicated than previously thought. The Raman measurements offer evidence for at least six separate S-bearing As species whose principal bands are centered near 365, 385, 390, 400, 415 and 420 cm^-1. The data suggest that at least two different species may give rise to bands at 385 cm^-1, bringing the probable minimum number of species to seven. Several additional species are possible but could not be resolved definitively. In general, the relative proportions of these species are dependent on total As concentration, ΣS/ΣAs ratio and pH. At very low ΣS/ΣAs ratios we also observe Raman bands attributable to the dissociation products of H₃AsO₃(aq). Although we were unable to assign precise stoichiometries for the various thioarsenite species, we were able to map out general pH and ΣS/ΣAs conditions under which the various thioarsenite and arsenite species are predominant. This study provides a basis for more detailed Raman spectroscopic and other types of investigations of the nature of thioarsenite species.     

Major active faults determine the location of the Tongonan geothermal field: Evidence provided by rock alteration and stable isotope geochemistry

Abstract The influence of major active faults on rock alteration and stable isotope geochemistry is described for the Tongonan geothermal field, Leyte, the Philippines. In the Pliocene, acid alteration with characteristic iron enrichment (3 g/100 g) and calcium depletion (2 g/100 g) occurred along a Riedel shear fault in the Malitbog sector, and initial minor acid alteration also occurred along a similar shear in the Mahiao sector. Later, sodium metasomatism (5 g/100 g) coincided with the highest aquifer chloride (10 000 mg/kg) as a result of dissociation of saline magmatic fluids discharging through the reservoir rocks in the Upper Mahiao. The incursion of magmatic fluids (possibly δD 35‰, δ¹⁸O +7‰) set up a vigorous convection cell of meteoric water, which focused around low‐angle (L) shears centered in the Sambaloran sector. Meteoric water (δD ?35 to ?40‰, δ¹⁸O ?6 ± 1‰) depleted the reservoir in silica (6 g/100 g) and potassium (1–2 g/100 g). It also completely exchanged oxygen isotopes rapidly (within months) at high temperatures (300–400°C), and now does so continuously with fractured isotopically fresh or incompletely altered rock at small scales (centimeters or less) exposed by a 2 cm/year creep around the L shears to form a new component called geothermal water. Geothermal water mixes with meteoric water at lower temperatures (<300°C) to create the characteristic shift in δ¹⁸O of 6‰ at near constant δD (?35 ± 5‰). The 10‰ variation in δD is due to groundwater recharge derived from rain falling on steep terrain (5‰) and to enrichment of deuterium in boiling saline solutions (5‰); it is not due to two‐component mixing of meteoric with magmatic water. The low (～1) isotopic water/rock (W/R) ratios calculated from oxygen isotopes in previously published reports are meaningless, because the water contains four components (predominantly geothermal and meteoric water; <10% magmatic and rock water). W/R ratios of up to 1500 calculated from spring and rock chemistry are more realistic and, with a flow rate of approximately 50 L/s through a 30 km³ reservoir, can account for the estimated 3 My age of the system.     

Local Initiation of Deep Convection on the Canadian Prairie Provinces

Our study found that local mesoscale circulations associated with highlandareas, and transient evapotranspiration discontinuities, are likely to influencethe timing and location of the initiation of deep convection across the Canadianprairie provinces when synoptic-scale forcing is weak (e.g., weak low level windsand no frontal boundaries). The cumulus congestus and cumulonimbus clouds thatformed over the highland areas were initiated by anabatic wind induced mesoscalecirculations. These deep convective clouds generally formed relatively early in theday (about 1030 Central Standard Time (CST)). In the relatively flat cropped grasslandregion, transient evapotranspiration gradients influenced the location of deep convectioninitiation, and the average soil moisture in the root zone had a direct impact on theirtiming. As root zone soil moisture declined from greater than 70% to less than 30%,convection initiation was delayed from about 0930 to 1630 CST. Cumulus congestusand cumulonimbus clouds that formed over the ephemeral evapotranspiration gradientswere initiated by land-land circulations. The study has improved the understanding ofthe influence of local surface forcing on the development of deep convective cloud onthe Canadian prairie provinces. The identification of areas where deep convection islikely to be initiated with weak synoptic forcing will also aid in the forecasting ofthunderstorms in this region.     

The northern Walker Lane refraction experiment: Pn arrivals and the northern Sierra Nevada root

In May 2002, we collected a new crustal refraction profile from Battle Mountain, Nevada across western Nevada, the Reno area, Lake Tahoe, and the northern Sierra Nevada Mountains to Auburn, CA. Mine blasts and earthquakes were recorded by 199 Texan instruments extending across this more than 450-km-long transect. The use of large mine blasts and the ultra-portable Texan recorders kept the field costs of this profile to less than US$10,000. The seismic sources at the eastern end were mining blasts at Barrick's GoldStrike mine. The GoldStrike mine produced several ripple-fired blasts using 8000–44,000 kg of ANFO each, a daily occurrence. First arrivals from the larger GoldStrike blasts are obvious to distances of 300 km in the raw records. First arrivals from a quarry blast west of the survey near Watsonville, CA, located by the Northern California Seismic Network with a magnitude of 2.2, can be picked across the recording array to distances of 600 km. The Watsonville blast provides a western source, nearly reversing the GoldStrike blasts. A small earthquake near Bridgeport, CA. also produced pickable P-wave arrivals across the transect, providing fan-shot data. Arrivals from M5 events in the Mariana and Kuril Islands also appear in the records. This refraction survey observes an unexpectedly deep crustal root under the northern Sierra Nevada range, over 50 km in thickness and possibly centered west of the topographic crest. Pn delays of 4–6 s support this interpretation. At Battle Mountain, Nevada, we observe anomalously thin crust over a limited region perhaps only 150 km wide, with a Moho depth of 19–23 km. Pn crossover distances of less than 80 km support this anomaly, which is surrounded by observations of more normal, 30-km-thick crust. A 10-km-thick and high-velocity lower-crustal “pillow” is an alternative hypothesis, but unlikely due to the lack of volcanics west of Battle Mountain. Large mine and quarry blasts prove very effective crustal refraction sources when recorded with a dense receiver array, even over distances exceeding 600 km. New elastic synthetic seismogram modeling suggests that Pn can be strong as a first arrival, easing the modeling and interpretation of crustal refraction data. Fast eikonal computations of first-arrival time can match pickable Pn arrival times.