Chemistry of Halogen Oxides in the Troposphere: Comparison of Model Calculations with Recent Field Data

Reactive halogen species (RHS = X, XO, HOX, OXO; X = Cl, Br, I) are known to have an important influence on the chemistry in the polar boundary layer (BL), where they are responsible for ozone depletion events in spring. Recent field campaigns at Mace Head, Ireland, and the Dead Sea, Israel, identified for the first time iodine oxide (IO) at mixing ratios of up to 6.6 ppt and 90 ppt bromine oxide (BrO), respectively, by DOAS also at lower latitudes. These results intensified the discussion about the role of the RHS in the mid-latitude BL.Photochemical box model calculations show that the observed IO mixing ratios can destroy ~0.45 ppb ozone per hour. This is comparable to the rates of the known O₃-loss processes in the boundary layer. The model studies also reveal that IO, at these levels, has a strong influence on the BL photochemistry, increasing the OH/HO₂- and the NO₂/NO - ratios. In combination these changes lead to a reduction of the photochemical ozone formation, which - in addition - reduces ozone mixing ratios by up to 0.15 ppb/h.The studies for the Dead Sea case give no information on the heterogeneous process responsible for the bromine release, but they show that a total of 2 – 4 ppb of total bromine have to be released to explain the observed complete depletion of 60 ppb ozone in 2 – 3 hours.     

Modelling sensible and latent heat fluxes over sea during unstable,very close to neutral conditions

During slightly unstable but still very close to neutral conditions new results from two previous investigations have shown a significant increase of sensible and latent heat fluxes over the sea. The vertical heat transport during these conditions is dominated by detached eddies originating at the top of the boundary layer, bringing relatively cold and dry air to the surface. This effect can be described in numerical models by either enhanced heat transfer coefficients for sensible and latent heat (Stanton and Dalton numbers respectively) or with an additional roughness length, added to the original roughness lengths for heat and humidity. Such new expressions are developed using turbulence measurements from the Baltic Sea valid for wind speeds up to 14 m s⁻¹. The effect of including the increased heat fluxes is investigated using two different numerical models: a regional three-dimensional climate model covering northern Europe, and a process-oriented ocean model for the Baltic Sea. During periods of several days, the latent heat flux can be increased by as much as 100 W m⁻². The increase in sensible heat flux is significantly smaller since the process is only of importance in the very near-neutral regime where the sensible heat flux is very small. The long-term average effect over the Baltic Sea is of the order of several W m⁻².     

Large-Eddy Simulations of Surface Heterogeneity Effects on the Convective Boundary Layer During the LITFASS-2003 Experiment

We investigate the impact of observed surface heterogeneities during the LITFASS-2003 experiment on the convective boundary layer (CBL). Large-eddy simulations (LES), driven by observed near-surface sensible and latent heat fluxes, were performed for the diurnal cycle and compare well with observations. As in former studies of idealized one- and two-dimensional heterogeneities, secondary circulations developed that are superimposed on the turbulent field and that partly take over the vertical transport of heat and moisture. The secondary circulation patterns vary between local and roll-like structures, depending on the background wind conditions. For higher background wind speeds, the flow feels an effective surface heat-flux pattern that derives from the original pattern by streamwise averaging. This effective pattern generates a roll-like secondary circulation with roll axes along the mean boundary-layer wind direction. Mainly the upstream surface conditions control the secondary circulation pattern, where the fetch increases with increasing background wind speed. Unlike the entrainment flux that appears to be slightly decreased compared to the homogeneously-heated CBL, the vertical flux of sensible heat appears not to be modified in the mixed layer, while the vertical flux of latent heat shows different responses to secondary circulations. The study illustrates that sufficient time averaging and ensemble averaging is required to separate the heterogeneity-induced signals from the raw LES turbulence data. This might be an important reason why experiments over heterogeneous terrain in the past did not give any clear evidence of heterogeneity-induced effects.     

Controls on the deep thermal field: implications from 3-D numerical simulations for the geothermal research site Groß Schönebeck

The deep thermal field in sedimentary basins can be affected by convection, conduction or both resulting from the structural inventory, physical properties of geological layers and physical processes taking place therein. For geothermal energy extraction, the controlling factors of the deep thermal field need to be understood to delineate favorable drill sites and exploitation compartments. We use geologically based 3-D finite element simulations to figure out the geologic controls on the thermal field of the geothermal research site Groß Schönebeck located in the E part of the North German Basin. Its target reservoir consists of Permian Rotliegend clastics that compose the lower part of a succession of Late Carboniferous to Cenozoic sediments, subdivided into several aquifers and aquicludes. The sedimentary succession includes a layer of mobilized Upper Permian Zechstein salt which plays a special role for the thermal field due to its high thermal conductivity. Furthermore, the salt is impermeable and due to its rheology decouples the fault systems in the suprasalt units from subsalt layers. Conductive and coupled fluid and heat transport simulations are carried out to assess the relative impact of different heat transfer mechanisms on the temperature distribution. The measured temperatures in 7 wells are used for model validation and show a better fit with models considering fluid and heat transport than with a purely conductive model. Our results suggest that advective and convective heat transport are important heat transfer processes in the suprasalt sediments. In contrast, thermal conduction mainly controls the subsalt layers. With a third simulation, we investigate the influence of a major permeable and of three impermeable faults dissecting the subsalt target reservoir and compare the results to the coupled model where no faults are integrated. The permeable fault may have a local, strong impact on the thermal, pressure and velocity fields whereas the impermeable faults only cause deviations of the pressure field.     

Sedimentological parameters and erosion behaviour of submarine coastal sediments in the south-western Baltic Sea

The aim of this study was to evaluate the erodibility of submarine coastal sediments for the purpose of modelling sediment dynamics in Mecklenburg Bay, south-western Baltic Sea. Erosion thresholds derived from experiments with a device microcosm on cores of fine sand (n=5, mean grain size=132 µm) and mud (n=5, medium silt size, mean=21 µm), collected at different times of the year, were compared to theoretical critical shear stress velocities based on grain-size measurements. For this purpose, a sedimentological map of natural surface sediments was constructed for the study area. Calculated values for critical shear stress velocities (u* _{cr-Hjulström} ) are 1.2 cm s^?1 for fine sand, and 3.75 cm s^?1 for cohesive mud. At the mud station, erosion experiments showed an initial transport of the fluffy surface layer (u* _cr-initial ) at a mean critical shear stress velocity of 0.39 cm s^?1. Initial rolling transport at the fine sand station for single sand grains was recorded at values of 0.5 cm s^?1. At higher shear stress velocities, the two sediment types showed diverging erosion behaviour. Measurable erosion (ε>5.0×10^?6 kg m^?2 s^?1) of fine sand starts at a mean critical shear stress velocity (u* _cr-erosion ) of 1.15 cm s^?1 whereas fluffy surface material on mud cores was eroded at mean u* _cr-erosion of 0.62 cm s^?1. This indicates that measured erosion thresholds at the fine sand site fit well to calculated critical shear stress velocities whereas calculated erosion thresholds for cohesive mud are roughly 6 times higher than measured values. As erosion behaviour at the mud station was dominated by fluffy surface material, the comparability of measured and calculated threshold values may be reduced. The underlying silt-sized sediment itself was stable due to cohesive effects. This behaviour has to be taken into consideration by using sediment types instead of mean grain sizes for mapping and modelling sediment dynamics. A comparison of the near-bottom hydrodynamic conditions in the study area and experimentally derived critical shear stress velocities suggests that particle transport is controlled by storm events whereas under calm conditions shear stress velocities do not exceed the critical values.     

Book Review: Martin L.J. Turner: Expedition Mars,Springer/Praxis,London, 2004, 321 pages. ISBN: 1-85233-735-4

Earth, Moon, and Planets -     

Correlation of late precambrian and early Palaeozoic sequences by eustatic sea-level changes and the selection of the Precambrian-Cambrian boundary

The author argues for a pragmatic approach to the problem of defining the Precambrian-Cambrian boundary. A boundary at first occurrence of shelly fauna as recommended by the Precambrian-Cambrian working group will create severe difficulties in worldwide correlation. By placing the boundary stratigraphically somewhat higher (i.e. the Fallotaspis zone) with a more abundant fauna, there is a much better basis for biostratigraphic correlation.Eustatic sea-level changes may be another important tool for late Precambrian-early Palaeozoic correlation, and more detailed facies interpretation of such sequences should be carried out in order to recognise these eustatic sea-level changes.     

Degradation of digested sewage sludge residue under anaerobic conditions for mine tailings remediation

Previous studies showed that 85 % of total organic matter (TOM) in digested sewage sludge (biosolids) used as a sealing layer material over sulfide tailings at the Kristineberg Mine, northern Sweden, had been degraded 8 years after application, resulting in a TOM reduction from 78 to 14 %. To achieve a better understanding of the field observations, laboratory studies were performed to evaluate biodegradation rates of the TOM under anaerobic conditions. Results reveal that the original biosolid consisted of ca. 60 % TOM (48.0 % lignin and 11.8 % carbohydrates) that had not been fully degraded. The incubation experiments proved that 27.8 % TOM in the biosolid was further degraded anaerobically at 20–22 °C during the 230 days’ incubation period, and that a plateau to the biodegradation rate was approached. Based on model results, the degradation constant was found to be 0.0125 (day^?1). The calculated theoretical gas formation potential was ca. 50 % higher than the modeled results based on the average degradation rate. Cumulated H₂S equated to 0.65 μmoL g^?1 of biosolid at 230 days. However, the large sulfurous compounds reservoir (1.76 g SO₄ ^2? kg^?1 biosolid) together with anaerobic conditions can generate high concentrations of this gas over a long-term perspective. Due to the rate of biodegradability identified via anaerobic processes, the function of the biosolid to serve as an effective barrier to inhibit oxygen migration to underlying tailings, may decrease over time. However, a lack of readily degradable organic fractions in the biosolid and a large fraction of organic matter that was recalcitrant to degradation suggest a longer degradation duration, which would prolong the biosolid material’s function and integrity.     

Possible Concepts for Waterproofing of Norwegian TBM Railway Tunnels

The aim of this paper is to evaluate and compare the durability, life expectancy and maintenance needs of traditional Norwegian waterproofing concepts to the generally more rigid waterproofing concepts seen in other European countries. The focus will be on solutions for future Norwegian tunnel boring machine railway tunnels. Experiences from operation of newer and older tunnels with different waterproofing concepts have been gathered and analyzed. In the light of functional requirements for Norwegian rail tunnels, some preliminary conclusions about suitable concepts are drawn. Norwegian concepts such as polyethylene panels and lightweight concrete segments with membrane are ruled out. European concepts involving double shell draining systems (inner shell of cast concrete with membrane) and single shell undrained systems (waterproof concrete segments) are generally evaluated as favorable. Sprayable membranes and waterproof/insulating shotcrete are welcomed innovations, but more research is needed to verify their reliability and cost effectiveness compared to the typical European concepts. Increasing traffic and reliance on public transport systems in Norway result in high demand for durable and cost effective solutions.     

3D coupled fluid and heat transport simulations of the Northeast German Basin and their sensitivity to the spatial discretization: different sensitivities for different mechanisms of heat transport

Based on a numerical model of the Northeast German Basin (NEGB), we investigate the sensitivity of the calculated thermal field as resulting from heat conduction, forced and free convection in response to consecutive horizontal and vertical mesh refinements. Our results suggest that computational findings are more sensitive to consecutive horizontal mesh refinements than to changes in the vertical resolution. In addition, the degree of mesh sensitivity depends strongly on the type of the process being investigated, whether heat conduction, forced convection or free thermal convection represents the active heat driver. In this regard, heat conduction exhibits to be relative robust to imposed changes in the spatial discretization. A systematic mesh sensitivity is observed in areas where forced convection promotes an effective role in shorten the background conductive thermal field. In contrast, free thermal convection is to be regarded as the most sensitive heat transport process as demonstrated by non-systematic changes in the temperature field with respect to imposed changes in the model resolution.