Effects of salinity on NH4 + adsorption capacity, nitrification, and denitrification in Danish estuarine sediments

The regulatory effect of salinity on nitrogen dynamics in estuarine sediments was investigated in the Randers Fjord estuary, Denmark, using sediment slurries and intact sediment cores and applying ¹⁵N-isotope techniques. Sediment was sampled at three representative stations varying in salinity, and all experiments were run at 0‰, 10‰, 20‰, and 30‰. The sediment NH₄ ⁺ adsorption capacity decreased markedly at all stations when salinity was increased from 0‰ to 10‰; further increase showed little effect. In situ nitrification and denitrification also decreased with increasing salinities, with the most pronounced reduction of approximately 50% being observed when the salinity was raised from 0‰ to 10‰. The salinity-induced reduction in NH₄ ⁺ adsorption capacity and stimulation of NH₄ ⁺ efflux has previously been argued to cause a reduction in nitrification activity since the nitrifying bacteria become limited by NH₄ ⁺ availability at higher salinities. However, using a potential nitrification assay where NH₄ ⁺ was added in excess, it was demonstrated that potential nitrification activity also decreased with increasing salinity, indicating that the inhibitory salinity effect may also be a physiological effect on the microorganisms. This hypothesis was supported by the finding that denitrification based on NO₃ ⁻ from the overlying water (D_w), which is independent of the nitrification process, and hence NH₄ ⁺ availability, also decreased with increasing salinity. We conclude that changes in salinity have a significant effect on nitrogen dynamics in estuarine sediments, which must be considered when nitrogen transformations are measured and evaluated.     

Altimetry-derived tide model for improved tide and water level forecasting along the European continental shelf

Ocean Dynamics - With the continued rise in global mean sea level, operational predictions of tidal height and total water levels have become crucial for accurate estimations and understanding of...     

On the impact of wind on the development of wave field during storm Britta

The observation of extreme waves at FINO 1 during storm Britta on the 1st November 2006 has initiated a series of research studies regarding the mechanisms behind. The roles of stability and the presence of the open cell structures have been previously investigated but not conclusive. To improve our understanding of these processes, which are essential for a good forecast of similarly important events offshore, this study revisits the development of storm Britta using an atmospheric and wave coupled modeling system, wind and wave measurements from ten stations across the North Sea, cloud images and Synthetic Aperture Radar (SAR) data. It is found here that a standard state-of-the-art model is capable of capturing the important characteristics of a major storm like Britta, including the storm path, storm peak wind speed, the open cells, and peak significant wave height (H _s ) for open sea. It was also demonstrated that the impact of the open cells has negligible contribution to the development of extreme H _s observed at FINO 1. At the same time, stability alone is not sufficient in explaining the development of extreme H _s . The controlling conditions for the development of Britta extreme H _s observed at FINO 1 are the persistent strong winds and a long and undisturbed fetch over a long period.     

Investigation of the thermal regime and subsurface properties of a tidally affected,variably saturated streambed

Temperature and moisture content in the variably saturated subsurface are two of the most important physical parameters that govern a wide variety of geochemical and ecological processes. An understanding of thermal and hydraulic processes and properties of transient vadose zones is therefore fundamental in the evaluation of such processes. Here, an investigation of the thermal regime and subsurface properties of a tidally affected, variably saturated streambed is presented. Field and laboratory measurements, as well as a forward numerical model, are jointly employed in the investigation. Temperature, soil moisture, surface level, and water level data were recorded in a transect perpendicular to a tidally driven stream. Frequency‐domain analysis of the subsurface temperature measurements revealed the rapid decay of the tidal temperature driver within the top ～30 cm of sediment. Several techniques were used to evaluate subsurface thermal and hydraulic properties, including thermal conductivity and the soil water retention curve. These properties were used to constrain a forward numerical model that included coupled treatment of relevant variable saturation thermal and hydraulic physics. Even though the investigated vadose zone is intermittent and relatively shallow ( 20 cm), the results illustrate how error can be introduced into heat‐transport calculations if unsaturated conditions are not taken into account.     

How does water near clay mineral surfaces influence the rock physics of shales?

Clays and clay‐bearing rocks like shale are extremely water sensitive. This is partly due to the interaction between water and mineral surfaces, strengthened by the presence of nanometer‐size pores and related large specific surface areas. Molecular‐scale numerical simulations, using a discrete‐element model, show that shear rigidity can be associated with structurally ordered (bound or adsorbed) water near charged surfaces. Building on these and other molecular dynamics simulations plus nanoscale experiments from the literature, the water monolayer adjacent to hydrophilic solid surfaces appears to be characterised by shear stiffness and/or enhanced viscosity. In both cases, elastic wave propagation will be affected by the bound or adsorbed water. Using a simple rock physics model, bound water properties were adjusted to match laboratory measured P‐ and S‐wave velocities on pure water‐saturated kaolinite and smectite. To fit the measured stress sensitivity, particularly for kaolinite, the contribution from solid‐grain contact stiffness needs to be added. The model predicts, particularly for S‐waves, that viscoelastic bound water could be a source of dispersion in clay and clay‐rich rocks. The bound‐water‐based rock physics model is found to represent a lower bound to laboratory‐measured velocities obtained with shales of different mineralogy and porosity levels.     

Strömgren CCD photometry of Globular Clusters

We present results from Strömgren uvby photometry forthe globular clusters M3 and M13, obtained from the Nordic Optical Telescope and the Danish 1.54 m telescope on La Silla obtained as part ofa larger program to investigate cluster ages.     

Comparison of abstraction scenarios simulated by SWAT and SWAT-MODFLOW

In hydrological modelling of catchments, wherein streams are groundwater-fed, an accurate representation of groundwater processes and their interaction with surface water is crucial. With this purpose, a coupled model was recently developed linking SWAT (Soil and Water Assessment Tool) with the fully-distributed groundwater model MODFLOW (Modular Groundwater Flow). In this study, SWAT and SWAT-MODFLOW were applied to a Danish groundwater-dominant catchment, simulating groundwater abstraction scenarios and assessing the benefits and drawbacks of SWAT-MODFLOW. Both models demonstrated good performance. However, SWAT-MODFLOW provided more realistic outputs when simulating abstraction: the decrease in streamflow was similar to the volume of water abstracted, while in SWAT the impact was negligible. SWAT also showed impacts on streamflow only when abstractions were taken from the shallow aquifer, not from the deep aquifer. Overall, SWAT-MODFLOW demonstrated wider possibilities for groundwater analysis, providing more insights than SWAT in supporting decision making in relation to environmental assessment.