Membrane Interface Probe Protocol for Contaminants in Low‐Permeability Zones

Accurate characterization of contaminant mass in zones of low hydraulic conductivity (low k) is essential for site management because this difficult‐to‐treat mass can be a long‐term secondary source. This study developed a protocol for the membrane interface probe (MIP) as a low‐cost, rapid data‐acquisition tool for qualitatively evaluating the location and relative distribution of mass in low‐k zones. MIP operating parameters were varied systematically at high and low concentration locations at a contaminated site to evaluate the impact of the parameters on data quality relative to a detailed adjacent profile of soil concentrations. Evaluation of the relative location of maximum concentrations and the shape of the MIP vs. soil profiles led to a standard operating procedure (SOP) for the MIP to delineate contamination in low‐k zones. This includes recommendations for: (1) preferred detector (ECD for low concentration zones, PID or ECD for higher concentration zones); (2) combining downlogged and uplogged data to reduce carryover; and (3) higher carrier gas flow rate in high concentration zones. Linear regression indicated scatter in all MIP‐to‐soil comparisons, including R² values using the SOP of 0.32 in the low concentration boring and 0.49 in the high concentration boring. In contrast, a control dataset with soil‐to‐soil correlations from borings 1‐m apart exhibited an R² of ≥0.88, highlighting the uncertainty in predicting soil concentrations using MIP data. This study demonstrates that the MIP provides lower‐precision contaminant distribution and heterogeneity data compared to more intensive high‐resolution characterization methods. This is consistent with its use as a complementary screening tool.     

Observations of X/M asteroids across multiple wavelengths

We have conducted a radar-driven observational campaign of main-belt asteroids (MBAs) focused on X/M class asteroids using the Arecibo radar and NASA Infrared Telescope Facilities (IRTF). M-type asteroids have been identified as metallic, enstatite chondrites and/or heavily altered carbonaceous chondrites [Bell, J.F., Davis, D., Hartmann, W.K., Gaffey, M.J., 1989. In: Binzel, R.P., Gehrels, T., Matthews, M.S. (Eds.), Asteroids II. Univ. of Arizona Press, Tucson, pp. 921-948; Gaffey, M.J., McCord, T.B., 1979. In: Gehrels, T., Matthews, M.S. (Eds.), Asteroids. Univ. of Arizona Press, Tucson, pp. 688-723; Vilas, F., 1994. Icarus 111, 456-467]. Radar wavelength observations can determine whether an asteroid is metallic and provide information about the porosity and regolith depth. Near-infrared observations can help determine the grain size, porosity and composition of an object. Concurrent observations with these tools can give us a wealth of information about an object. Our objectives for this observation program were to (a) determine if there are any consistent relationships between spectra in the near-infrared wavelengths and radar signatures and (b) look for rotationally resolved relationships between asteroid radar properties and near-infrared spectral properties. This paper describes preliminary results of an ongoing survey of near-infrared observations of M-type asteroids and is a companion paper to radar observations reported by Shepard [Shepard, M.K., and 19 colleagues, 2008a. Icarus 195, 184-205]. In the analysis of 16 asteroid near-infrared spectra and nine radar measurements, we find a trend indicating a correlation between continuum slope from 1.7 to 2.45 μm and radar albedo—an asteroid with a steep continuum slope also has a bright radar albedo, which suggests a significant metal content. This may provide a means to use near-IR observations to predict the most likely metallic candidates for radar studies.     

Nutrient availability in support of Karenia brevis blooms on the central West Florida Shelf: What keeps Karenia blooming?

Identifying nutrient sources, primarily nitrogen (N) and phosphorus (P), sufficient to support high biomass blooms of the red tide dinoflagellate, Karenia brevis, has remained problematic. The West Florida Shelf is oligotrophic, yet populations >10⁶ cells L⁻¹ frequently occur and blooms can persist for months. Here we examine the magnitude and variety of sources for N and P that are available to support blooms. Annual average in situ or background concentrations of inorganic N in the region where blooms occur range 0.02–0.2 μM while inorganic P ranges 0.025–0.24 μM. Such concentrations would be sufficient to support the growth of populations up to ∼3×10⁴ cells L⁻¹ with at least a 1 d turnover rate. Organic N concentrations average 1–2 orders of magnitude greater than inorganic N, 8–14 μM while organic P concentrations average 0.2–0.5 μM. Concentrations of organic N are sufficient to support blooms >10⁵ cells L⁻¹ but the extent to which this complex mixture of N species is utilizable is unknown. Other sources of nutrients included in our analysis are aerial deposition, estuarine flux, benthic flux, zooplankton excretion, N₂-fixation, and subsequent release of organic and inorganic N by Trichodesmium spp., and release of N and P from dead and decaying fish killed by the blooms. Inputs based on atmospheric deposition, benthic flux, and N₂-fixation, were minor contributors to the flux required to support growth of populations >2.6×10⁴ cells L⁻¹. N and P from decaying fish could theoretically maintain populations at moderate concentrations but insufficient data on the flux and subsequent mixing rates does not allow us to calculate average values. Zooplankton excretion rates, based on measured zooplankton population estimates and excretion rates could also supply all of the N and P required to support populations of 10⁵ and 10⁶ cells L⁻¹, respectively, but excretion is considered as “regenerated” nutrient input and can only maintain biomass rather than contribute to “new” biomass. The combined estuarine flux from Tampa Bay, Charlotte Harbor, and the Caloosahatchee River can supply a varying, but at times significant level of N and P to meet growth and photosynthesis requirements for populations of approximately 10⁵ cells L⁻¹ or below. Estimates of remineralization of dead fish could supply a significant proportion of bloom maintenance requirements but the rate of supply must still be determined. Overall, a combination of sources is required to maintain populations >10⁶ cells L⁻¹.     

It takes a garden: Cultivating citizen-subjects in organized garden projects

Since the 1980’s organized garden projects have proliferated in a institutional settings associated with the “roll-out” neoliberal state and the sad consequences of neoliberalism more generally: jails, schools, hospitals and other clinical settings for “at-risk” populations. This article advances the concept “organized garden project” over the richly connotative, but inchoate term “community garden,” and links the long episodic history of garden projects with changing discourses about the supposedly transformative power of gardening practice for individual and social transformation. The article highlights two organized garden projects within the San Francisco Bay area, a chief locus in the movement to using organized garden projects to produce new individual and collective subjectivities. The case studies assess, from the typically unambiguous standpoint of the garden organizers, the nature of the subjectivity that gardening practice is supposed to produce, the need for such alternative subjectivity and the “difference” such alternatives are believed to make for the individual and in the wider social, political and economic milieu.     

Eutrophication erodes inter-basin variation in macrophytes and co-occurring invertebrates in a shallow lake: combining ecology and palaeoecology

Aquatic biodiversity is commonly linked with environmental variation in lake networks, but less is known about how local factors may influence within-lake biological heterogeneity. Using a combined ecological and multi-proxy palaeoecological approach we investigated long-term changes in the pathways and processes that underlie eutrophication and water depth effects on lake macrophyte and invertebrate communities across three basins in a shallow lake—Castle Lough, Northern Ireland, UK. Contemporary data allow us to assess how macrophyte assemblages vary in composition and heterogeneity according to basin-specific factors (e.g. variation in water depth), while palaeoecological data (macrophytes and co-occurring invertebrates) enable us to infer basin-specific impacts and susceptibilities to nutrient-enrichment. Results indicate that variability in water depth promotes assemblage variation amongst the lake basins, stimulating within-lake macrophyte assemblage heterogeneity and hence higher lake biodiversity. The palaeo-data indicate that eutrophication has acted as a strong homogenising agent of macrophyte and invertebrate diversities and abundances over time at the whole-lake scale. This novel finding strongly suggests that, as eutrophication advances, the influence of water depth on community heterogeneity is gradually eroded and that ultimately a limited set of eutrophication-tolerant species will become homogeneously distributed across the entire lake.     

Fingerprinting TCE in a bedrock aquifer using compound-specific isotope analysis

A dual isotope approach based on compound-specific isotope analysis (CSIA) of carbon (C) and chlorine (Cl) was used to identify sources of persistent trichloroethylene (TCE) that caused the shut-down in 1994 of a municipal well in an extensive fractured dolostone aquifer beneath Guelph, Ontario. Several nearby industrial properties have known subsurface TCE contamination; however, only one has created a comprehensive monitoring network in the bedrock. The impacted municipal well and many monitoring wells were sampled for volatile organic compounds (VOCs), inorganic parameters, and CSIA. A wide range in isotope values was observed at the study site. The TCE varies between -35.6‰ and -21.8‰ and from 1.6‰ to 3.2‰ for δ(13) C and δ(37) Cl, respectively. In case of cis-1,2-dichloroethene, the isotope values range between -36.3‰ and -18.9‰ and from 2.4‰ to 4.7‰ for δ(13) C and δ(37) Cl, respectively. The dual isotope approach represented by a plot of δ(13) C vs. δ(37) Cl shows the municipal well samples grouped in a domain clearly separate from all other samples from the property with the comprehensive well network. The CSIA results collected under non-pumping and short-term pumping conditions thus indicate that this particular property, which has been studied intensively for several years, is not a substantial contributor of the TCE presently in the municipal well under non-pumping conditions. This case study demonstrates that CSIA signatures would have been useful much earlier in the quest to examine sources of the TCE in the municipal well if bedrock monitoring wells had been located at several depths beneath each of the potential TCE-contributing properties. Moreover, the CSIA results show that microbial reductive dechlorination of TCE occurs in some parts of the bedrock aquifer. At this site, the use of CSIA for C and Cl in combination with analyses of VOC and redox parameters proved to be important due to the complexity introduced by biodegradation in the complex fractured rock aquifer. It is highly recommended to revisit the study when the municipal well is back into full operation.     

A radar survey of M- and X-class asteroids II. Summary and synthesis

Using the S-band radar at Arecibo Observatory, we observed six new M-class main-belt asteroids (MBAs), and re-observed one, bringing the total number of Tholen M-class asteroids observed with radar to 19. The mean radar albedo for all our targets is , significantly higher than the mean radar albedo of every other class (Magri, C., Nolan, M.C., Ostro, S.J., Giorgini, J.D. [2007]. Icarus 186, 126-151). Seven of these objects (Asteroids 16 Psyche, 129 Antigone, 216 Kleopatra, 347 Pariana, 758 Mancunia, 779 Nina, 785 Zwetana) have radar albedos indicative of a very high metal content , and consistent with a remnant iron/nickel core interpretation (irons) or exotic high metal meteorite types such as CB. We propose designating these high radar albedo objects as Mm. Two asteroids, 110 Lydia and 678 Fredegundis, have more moderate radar albedos , but exhibit high values at some rotation phases suggesting a significant metal content. The remaining 10 objects have moderate radar albedos at all rotation phases. Most of our targets have visible/near-infrared spectra (Hardersen, P.S., Gaffey, M.J., Abell, P.A. [2005]. Icarus 175, 141-158; Fornasier, S., Clark, B.E., Dotto, E., Migliorini, A., Ockert-Bell, M., Barucci, M.A. [2009]. Icarus, submitted for publication) that indicate the presence of at least some silicate phases. All of the non-Mm asteroids show a positive correlation between visual and radar albedo but the reasons for this are not clear. All of the higher radar albedo targets (the 7 Mm asteroids, Lydia, and Fredegundis) show moderate to large variations in radar albedo with rotation phase. We suggest that their high radar reflectivity exaggerates irregularities in the asteroid shape to cause this behavior. One-third of our targets show evidence for asteroid-scale concavities or bifurcation. Based on all the evidence available, we suggest that most Tholen M-class asteroids are not remnant iron cores or enstatite chondrites, but rather collisional composites of silicates and irons with compositions more analogous to stony-iron meteorites and high-iron carbonaceous chondrites.     

A late Pleistocene steppe bison (Bison priscus) partial carcass from Tsiigehtchic, Northwest Territories, Canada

A partial steppe bison (Bison priscus) carcass was recovered at Tsiigehtchic, near the confluence of the Arctic Red and Mackenzie Rivers, Northwest Territories, Canada in September of 2007. The carcass includes a complete cranium with horn cores and sheaths, several complete post-cranial elements (many of which have some mummified soft tissue), intestines and a large piece of hide. A piece of metacarpal bone was subsampled and yielded an AMS radiocarbon age of 11,830 ± 45 ¹⁴C yr BP (OxA-18549). Mitochondrial DNA sequenced from a hair sample confirms that Tsiigehtchic steppe bison (Bison priscus) did not belong to the lineage that eventually gave rise to modern bison (Bison bison). This is the first radiocarbon dated Bison priscus in the Mackenzie River valley, and to our knowledge, the first reported Pleistocene mammal soft tissue remains from the glaciated regions of northern Canada. Investigation of the recovery site indicates that the steppe bison was released from the permafrost during a landslide within unconsolidated glacial outwash gravel. These data indicate that the lower Mackenzie River valley was ice free and inhabited by steppe bison by 11,800 ¹⁴C years ago. This date is important for the deglacial chronology of the Laurentide Ice Sheet and the opening of the northern portal to the Ice Free Corridor. The presence of steppe bison raises further potential for the discovery of more late Pleistocene fauna, and possibly archaeological evidence, in the region.