The Infrared Transmission Spectrum of the Salzwedel Meteorite

Abstract— The paper presents the infrared transmission spectrum of the Salzwedel meteorite. Further, the spectrum is used to characterize the meteorite's mineralogical composition.     

Particle dynamics in reconnection field configurations

Trajectories of test particles are studied numerically in two types of reconnection magnetic field configurations, a single X-line magnetic field configuration and a tearing magnetic field configuration. Both adiabatic and nonadiabatic motions are examined, with special emphasis on net energy gain and time spent in the neutral line regions. They spend typically one characteristic gyroperiod in the X-line region and are ejected predominantly along field lines in the vicinity of the separatrix. Both adiabatic and nonadiabatic test particles in the tearing-type field configuration are channelled into and accelerated along the O-line region. It may be inferred from these test particle results that particle energizations are significant along the O-line region, but not along the X-line region. These results are in qualitative agreement with those obtained by a self-consistent particle simulation.     

The accuracy of geopotential models

Extensive tests of two recent geopotential models (GEM 7 and 8) have been made with observations not used in the solutions. Several other recent models are also evaluated. These tests show the accuracy of the satellite derived model (GEM 7, with 400 coefficients) to be about 4.3 m (r.m.s.) with respect to the global geoid surface. The corresponding accuracy of the combined satellite and surface gravimetry model (GEM 8, with 706 coefficients) is found to be 3.9m (r.m.s.). These results include a calibration for the commission errors of the coefficients in the models and an estimate of the errors from omitted coefficients. For GEM 7, the formal precision (commission errors) of the solution gives 0.7 m for the geoid error which after calibration increases to 2.4 m.

Independent observations used in this assessment include: 159 lumped coefficients from 35 resonant orbits of 1 and 9 through 15 revolutions per day, two sets of (8, 8) fields derived from optical-only and laser-only data, sets of zonal and resonant coefficients derived from largely independent sources and geoid undulations measured by satellite altimetry. In addition, the accuracy of GEM 7 has been judged by the gravimetry in GEM 8. The ratio of estimated commission to formal error in GEM 7 and 8 ranges from 2 to 5 in these tests.     

Orbital-scale record of the late Cenomanian–Turonian oceanic anoxic event (OAE-2) in the Tarfaya Basin (Morocco)

High sedimentation rates (up to 12 cm/kyear) of laminated organic carbon-rich biogenic limestones in the Tarfaya Basin provide an unusually high (millennial) resolution record of the late Cenomanian oceanic anoxic event (OAE-2). The global positive carbon-isotope excursion across the Cenomanian–Turonian corresponds to 11 light/dark sedimentary cycles. We interpret these cycles as a response to orbital obliquity variation and estimate the duration of the complete excursion as 440 kyear or one long eccentricity cycle. On this timescale, the main increase in ¹³C values occurred over a short time interval of less than 20 kyear in the late Cenomanian and reached a first maximum approximately 15 kyear prior to the bulk (mainly coccoliths) ¹⁸O-derived sea surface maximum temperature that occurs coeval to the extinction of Rotalipora cushmani. Organic carbon-accumulation rates follow obliquity cycles, reaching a maximum approximately 10 kyear after the last occurrence of R. cushmani, then slowly decreasing during the early Turonian. Thus, the maximum temperature and the maximum organic carbon accumulation in the Tarfaya Basin lagged by at least 15 kyear behind the global carbon-isotope shift and a proposed reduction of atmospheric CO₂ content. The climate change across the Cenomanian/Turonian boundary probably occurred independent of CO₂ levels and may have been controlled by different greenhouse gases (water vapour and methane) and changes in ocean circulation (i.e., opening of the Equatorial Atlantic gateway)     

Evaluation of the accuracy of the EIGEN-1S and -2 CHAMP-derived gravity field models by satellite crossover altimetry

Since the advent of CHAMP, the first in a series of low-altitude satellites being almost continuously and precisely tracked by GPS, a new generation of long-wavelength gravitational geopotential models can be derived. The accuracy evaluation of these models depends to a large extent on the comparison with external data of comparable quality. Here, two CHAMP-derived models, EIGEN-1S and EIGEN-2, are tested with independent long-term-averaged single satellite crossover (SSC) sea heights from three altimetric satellites (ERS-1, ERS-2 and Geosat). The analyses show that long-term averages of crossover residuals still are powerful data to test CHAMP gravity field models. The new models are tested in the spatial domain with the aid of ERS-1/-2 and Geosat SSCs, and in the spectral domain with latitude-lumped coefficient (LLC) corrections derived from the SSCs. The LLC corrections allow a representation of the satellite-orbit-specific error spectra per order of the models spherical harmonic coefficients. These observed LLC corrections are compared to the LLC projections from the models variance–covariance matrix. The excessively large LLC errors at order 2 found in the case of EIGEN-2 with the ERS data are discussed. The degree-dependent scaling factors for the variance-covariance matrices of EIGEN-1S and –2, applied to obtain more realistic error estimates of the solved-for coefficients, are compatible with the results found here.     

Error analyses of resonant orbits for geodesy

An error analysis of resonant orbits for geodesy indicates that attempts to use resonance to recover high order geopotential coefficients may be seriously hampered by errors in the geopotential. This effect, plus the very high correlations (up to .99) of the resonant coefficients with each other and the orbital period in single satellite solutions, makesindividual resonant orbits of limited value for geodesy. Multiple-satellite, single-plane solutions are only a slight improvement over the single satellite case. Accurate determination of high order coefficients from low altitude resonant satellites requires multiple orbit planes and small drift-periods to reduce correlations and effects of errors of non-resonant geopotential terms. Also, the effects of gravity model errors on low-altitude resonant satellites make the use of tracking arcs exceeding two to three weeks of doubtful validity. Because high-altitude resonant orbits are less affected by non-resonant terms in the geopotential, much longer tracking arcs can be used for them.     

Carbonatite diversity in the Central Andes: the Ayopaya alkaline province,Bolivia

The Ayopaya province in the eastern Andes of Bolivia, 100 km NW of Cochabamba, hosts a Cretaceous alkaline rock series within a Palaeozoic sedimentary sequence. The alkaline rock association comprises nepheline-syenitic/foyaitic to ijolitic intrusions, carbonatite, kimberlite, melilititic, nephelinitic to basanitic dykes and diatremes, and a variety of alkaline dykes. The carbonatites display a wide petrographic and geochemical spectrum. The Cerro Sapo area hosts a small calciocarbonatite intrusion and a multitude of ferrocarbonatitic dykes and lenses in association with a nepheline-syenitic stock. The stock is crosscut by a spectacular REE-Sr-Th-rich sodalite-ankerite-baryte dyke system. The nearby Chiaracke complex represents a magnesiocarbonatite intrusion with no evidence for a relationship to igneous silicate rocks. The magnesiocarbonatite ( REE up to 1.3 wt%) shows strong HREE depletion, i.e. unusually high La/Yb ratios (520–1,500). Calciocarbonatites ( REE up to 0.5 wt%) have a flatter REE distribution pattern (La/Yb 95–160) and higher Nb and Zr contents. The sodalite-ankerite-baryte dyke system shows geochemical enrichment features, particularly in Na, Ba, Cl, Sr, REE, which are similar to the unusual natrocarbonatitic lavas of the recent volcano of Oldoinyo Lengai, Tanzania. The Cerro Sapo complex may be regarded as an intrusive equivalent of natrocarbonatitic volcanism, and provides an example for carbonatite genesis by late-stage crystal fractionation and liquid immiscibility. The magnesiocarbonatite intrusion of Chiaracke, on the other hand, appears to result from a primary carbonatitic mantle melt. Deep seated mantle magmatism/metasomatism is also expressed by the occurrence of a kimberlite dyke. Neodymium and strontium isotope data (_Nd 1.4–5.4, ⁸⁷Sr/⁸⁶ Sr<Bulk Earth) indicate a depleted mantle source for the alkaline magmatism. The magmatism of the Ayopaya region is attributed to failed rifting of western South America during the Mesozoic and represents the only occurrence of carbonatite and kimberlite rocks in the Andes.     

A review of the thermal regime of the Eastern Alps with respect to the effects of paleoclimate and exhumation

Transient thermal signals such as Pleistocene surface temperature variations or exhumation of great rock volumes are important for the current thermal regime of the Eastern Alpine crust. In this study transient 1-D forward simulations and an analytical approach were used to estimate the order of magnitude of these effects. A comparison with numerical forward simulations and inverse analyses of steady-state heat conduction yields the following main conclusions with respect to the thermal regime of the Eastern Alps along the TRANSALP profile: (1) The change of surface temperatures in the past affects mainly the uppermost part of the Eastern Alpine crust. It results in a maximum thermal signature of more than − 6 K at a depth of 2 km. The deviations from a steady-state temperature gradient and heat flow in the region of the Tauern Window range from 0.3–4 K km^− 1 and 0–6 mW m^− 2, respectively, with maximum values at the surface. (2) Exhumation of the Eastern Alpine lithosphere may result in a thermal signature of up to 4 K at a depth of 1 km. The thermal signature increases further with depth to a maximum of approximately 80 K at a depth of 50 km. As the temperature gradient of the exhumation signal is almost zero at the base of the crust, Moho heat flow appears to be not critically perturbed. (3) The combined effect of exhumation and changing surface temperatures at the Tauern Window amounts to less than 15% of the steady-state temperatures at a depth of  8 km and to less than 10% at the base of Eastern Alpine root. The corresponding perturbation in heat flow is less than 20% at a depth of 4 km, approaching zero below 40 km.