The carbonatite-marble dykes of Abyan Province, Yemen Republic: the mixing of mantle and crustal carbonate materials revealed by isotope and trace element analysis

Summary Dykes of carbonate rocks, that cut gneisses in the Lowder-Mudiah area of southern Yemen, consist of dolomite and/or calcite with or without apatite, barite and monazite. Petrographic observations, mineralogical, XRF and ICP-MS analyses reveal that some of the carbonate rocks are derived from sedimentary protoliths, whereas others are magmatic calcio- and magnesio-carbonatites some of which are mineralized with barite-monazite. The interbanded occurrence and apparent contemporary emplacement of these different rock types within individual dykes, backed by Sr–Nd isotope evidence, are interpreted to show that intrusion of mantle-derived carbonatite magma was accompanied by mobilization of crustal marbles. That took place some 840Ma ago but the REE-mineralization is dated at ca. 400Ma.Supplementary material to this paper is available in electronic form at http://dx.doi.org/10.1007/s00710-004-0056-2     

Groundwater chemistry and mass transfers in the Independence aquifer,central Mexico,by using multivariate statistics and mass-balance models

In the light of progressive depletion of groundwater reservoir and water quality deterioration of the Independence aquifer, an investigation on chemical data of dissolved major and minor constituents in 246 recent groundwater samples was performed. The main objective was the detection of processes responsible for the geochemical evolution and mineralization throughout the area. Multivariate techniques revealed different sources of solutes (a) dissolution of calcium and magnesium carbonate minerals, (b) weathering of acid volcanic minerals, (c) alteration of manganese containing alkaline silicates, (d) leaching of halite deposits of meteoric origin, (e) contamination from agricultural and urban wastewaters, and (f) evaporative effects due to intensive irrigation. Although nitrate contamination is associated with pollution from intensive cultivated areas, natural contamination plays an important role in the study area. The investigation reveals that weathering of acid volcanic rocks (rhyolite) and oxidation of arsenic bearing sulfide minerals are the responsible processes for high fluorine (up to 16 mg/l) and arsenic (up to 0.12 mg/l) contents, respectively, exceeding the Mexican maximum admissible concentration for drinking water. Except for kaolinite, all recharge processes are dissolution oriented (CO₂, calcite, dolomite, K-feldspar, plagioclase). Silicate precipitation (amorphous silica and chalcedony) is of growing importance in discharge zones. Cation exchange is not an important issue in the whole study area.     

Surface gravitational field and topography changes induced by the Earth’s fluid core motions

Using a Love number formalism, the elastic deformations of the mantle and the mass redistribution gravitational potential within the Earth induced by the fluid pressure acting at the core–mantle boundary (CMB) are computed. This pressure field changes at a decadal time scale and may be estimated from observations of the surface magnetic field and its secular variation. First, using a spherical harmonic expansion, the poloidal and toroidal part of the fluid velocity field at the CMB for the last 40 years is computed, under the hypothesis of tangential geostrophy. Then the associated geostrophic pressure, whose order of magnitude is about 1000 Pa, is computed. The surface topography induced by this pressure field is computed using Love numbers, and is a few millimetres. The mass redistribution gravitational potential induced by these deformations and, in particular, the zonal components of the related surface gravitational potential perturbation (J₂, J₃ and J₄ coefficients), are calculated. Overall perturbations for the J₂ coefficient of about 10^–10, for J₃ of about 10^–11 and for J₄ are found of about 0.3×10^–11. Finally, these theoretical results are compared with recent observations of the decadal variation of J₂ from satellite laser ranging. Results concerning J₂ can be described as follows: first, they are one order of magnitude too small to explain the observed decadal variation of J₂ and, second, they show a significant linear trend over the last 40 years, whose rate of decrease amounts to 7% of the observed value.     

Détermination indirecte des limites d'Atterberg par gravimétrie dynamique

This study presents a new method for Atterberg limits measurements using dynamic drying. Indeed, for some polluted clays, or clay mixtures, classical methods cannot be used. The principle of liquid $(W_{\mathrm{L}})$ and plasticity $(W_{\mathrm{P}})$ limits determination by this method is presented. Experimental values for classical clays are close to those obtained with Casagrande's methods, allowing for larger physical mud characterisation. To cite this article: C. Proust et al., C. R. Geoscience 336 (2004).     

The synergistic powers of AEM and GIS geodatabase models in water resources studies

Comprehensive studies of water resources systems require integration of modeling tools and data associated with individual processes. An object-oriented approach is presented here that associates ground water models based upon the analytic element method (AEM) with geographic information system (GIS) geodatabase features using an AEM Model Interface. Each aquifer object contains a prescribed geometry, a mathematical representation in the AEM, and GIS hydrogeologic data. The synergistic understanding inherent in such an approach is illustrated by a study linking local AEM model predictions of water elevation with ground water geodatabase objects. This AEM Model Interface provides a key component in establishing a common object-oriented geodatabase modeling approach linking ground water to a variety of natural and social processes.     

Mental maps and travel behaviour: meanings and models

In this paper, the “mental map” concept is positioned with regard to individual travel behaviour to start with. Based on Ogden and Richards’ triangle of meaning (The meaning of meaning: a study of the influence of language upon thought and of the science of symbolism. International library of psychology, philosophy and scientific method. Routledge and Kegan Paul, London, 1966) distinct thoughts, referents and symbols originating from different scientific disciplines are identified and explained in order to clear up the notion’s fuzziness. Next, the use of this concept in two major areas of research relevant to travel demand modelling is indicated and discussed in detail: spatial cognition and decision-making. The relevance of these constructs to understand and model individual travel behaviour is explained and current research efforts to implement these concepts in travel demand models are addressed. Furthermore, these mental map notions are specified in two types of computational models, i.e. a Bayesian Inference Network (BIN) and a Fuzzy Cognitive Map (FCM). Both models are explained, and a numerical and a real-life example are provided. Both approaches yield a detailed quantitative representation of the mental map of decision-making problems in travel behaviour.     

A new design of the LAPS land surface scheme for use over and through heterogeneous and non-heterogeneous surfaces: Numerical simulations and tests

Numerical simulations and tests with the recently redesigned land–air parameterization scheme (LAPS) are presented. In all experiments, supported either by one-point micrometeorological, 1D or 3D simulations, the attention has been directed to: (1) comparison of simulation outputs, expressing the energy transfer over and through heterogeneous and non-heterogeneous surfaces, versus observations and (2) analysis of uncertainties occurring in the solution of the energy balance equation at the land–air interface. To check the proposed method for aggregation of albedo, “propagating hole” sensitivity tests with LAPS over a sandstone rock grid cell have been performed with the forcing meteorological data for July 17, 1999 in Baxter site, Philadelphia (USA). Micrometeorological and biophysical measurements from the surface experiments conducted over crops and apple orchard in Serbia, Poland, Austria and France were used to test the operation of LAPS in calculating surface fluxes and canopy environment temperatures within and above plant covers of different densities. In addition, sensitivity tests with single canopy covers over the Central Europe region and comparison against the observations taken from SYNOP data using 3D simulations were made. Validation of LAPS performances over a solid surface has been done by comparison of 2 m air temperature observations against 5-day simulations over the Sahara Desert rocky ground using 3D model. To examine how realistically the LAPS simulates surface processes over a heterogeneous surface, we compared the air temperature measured at 2 m and that predicted by the 1D model with the LAPS as the surface scheme. Finally, the scheme behaviour over urban surface was tested by runs over different parts of a hypothetical urban area. The corresponding 1D simulations were carried out with an imposed meteorological dataset collected during HAPEX-MOBILHY experiment at Caumont (France). The quantities predicted by the LAPS compare well with the observations and the various subcomponents of the scheme appear to operate realistically.     

Impacts of warm and cold situations in the Mediterranean basins on the West African monsoon: observed connection patterns (1979–2006) and climate simulations

Using both empirical and numerical ensemble approaches this study focuses on the Mediterranean/West African relationship in northern summer. Statistical analyses utilize skin temperature, sea surface temperature, in situ and satellite rainfall, outgoing longwave radiation (OLR) observations and reanalyzed data winds and specific humidity on isobaric surfaces. Numerical investigations are based on a large set of sensitivity experiments performed on four atmospheric general circulation models (AGCM): ARPEGE-Climat3, ECHAM4, LMDZ4 and UCLA7.3. Model outputs are compared to observations, discussed model by model and with an ensemble (multi-model) approach. As in previous studies the anomalous Mediterranean warm events are associated with specific impacts over the African monsoon region, i.e., a more intense monsoon, enhanced flux convergence and ascendances around the ITCZ, a strengthening of low level moisture advection and a more northward location of ascending motion in West Africa. The results show also new features (1) thermal variability observed in the two Mediterranean basins has unalike impacts, i.e. the western Mediterranean covaries with convection in Gulf of Guinea, while the eastern Mediterranean can be interpreted as Sahelian thermal-forcing; (2) although observations show symmetry between warming and cooling, modelling evidences only support the eastern warming influence; (3) anomalous East warm situations are associated with a more northward migration of the monsoon system accompanied by enhanced southwertely flow and weakened northeasterly climatological wind; (4) the multi-model response shows that anomalous East warm surface temperatures generate an enhancement of the overturning circulation in low and high levels, an increase in TEJ (Tropical Eeasterly Jet) and a decrease in AEJ (African Eeasterly Jet).     

Titan's surface at 2.2-cm wavelength imaged by the Cassini RADAR radiometer: Calibration and first results

The first comprehensive calibration and mapping of the thermal microwave emission from Titan's surface is reported based on radiometric data obtained at 2.2-cm wavelength by the passive radiometer included in the Cassini Radar instrument. The data reported were accumulated from 69 separate observational segments in Titan passes from Ta (October 2004) through T30 (May 2007) and include emission from 94% of Titan's surface. They are diverse in the key observing parameters of emission angle, polarization, and spatial resolution, and their reduction into calibrated global mosaic maps involved several steps. Analysis of the polarimetry obtained at low to moderate resolution (50+ km) enabled integration of the radiometry into a single mosaic of the equivalent brightness temperature at normal incidence with a relative precision of about 1 K. The Huygens probe measurement of Titan's surface temperature and radiometry obtained on Titan's dune fields allowed us to infer an absolute calibration estimated to be accurate to a level approaching 1 K. The results provide evidence for a surface that is complex and varied on large scales. The radiometry primarily constrains physical properties of the surface, where we see strong evidence for subsurface (volume) scattering as a dominant mechanism that determines the emissivity, with the possibility of a fluffy or graded-density surface layer in many regions. The results are consistent with, but not necessarily definitive of a surface composition resulting from the slow deposition and processing of organic compounds from the atmosphere.