Fast diffusion along mobile grain boundaries in calcite

Experimental measurements of grain boundary diffusion are usually conducted on static boundaries, despite the fact that grain boundaries deep in the Earth are frequently mobile. In order to explore the possible effect of boundary mobility on grain boundary diffusion rates we have measured the uptake of ⁴⁴Ca from a layer of ⁴⁴Ca-enriched calcite powder during the static recrystallization of a single crystal of calcite at 900°C. A region about 500 μm wide adjacent to the powder layer is heterogeneously enriched in ⁴⁴Ca, and complex zoning patterns, including sharp steps in composition and continuous increases and decreases in ⁴⁴Ca content, are developed. In metamorphic rocks, these would normally be interpreted in terms of changes in pressure or temperature, Rayleigh fractionation, or episodic fluid infiltration. These explanations cannot apply to our experiments, and instead the zoning patterns are interpreted as being due to variations in grain boundary migration rate. We have applied an analytical model which allows the product of grain boundary diffusion coefficient and grain boundary width (D _GB δ) to be calculated from the grain boundary migration rate and the compositional gradient away from the powder layer. The value of D _GB δ in the mobile grain boundaries is at least five orders of magnitude greater than the published value for static boundaries under the same conditions. In order to allow the scale of chemical equilibrium (and hence textural evolution) to be predicted under both experimental and geological conditions, we present quantitative diffusion-regime maps for static and mobile boundaries in calcite, using both published values and our new values for grain boundary diffusion in mobile boundaries. Enhanced diffusion in mobile boundaries has wide implications for the high temperature rheology of Earth materials, for geochronology, and for interpretations of the length- and time-scales of chemical mass-transport. Moreover, zones of anomalously high electrical conductivity in the crust and mantle could be regions undergoing recrystallization such as active shear zones, rather than regions of anomalous mineralogy, water- or melt-content as is generally suggested.     

带压开采煤层底板的承压能力研究

通过实测资料揭示了煤层底板保护层在一定条件下存在导水和贮水的性能,并剖析了这种性能的水理性质和规律,阐明了起始水力梯度、消压强度、抗水压强度、临界突水系数在概念上的统一性;在此基础上,分析了煤矿突水的机理与模式;并指明了探测研究保护层这一特性在确定开采煤层底板抗水压能力和带压开采安全性等方面的重要意义。     

Inverse modeling for seawater intrusion in coastal aquifers: Insights about parameter sensitivities,variances, correlations and estimation procedures derived from the Henry problem

Inverse modeling studies employing data collected from the classic Henry seawater intrusion problem give insight into several important aspects of inverse modeling of seawater intrusion problems and effective measurement strategies for estimation of parameters for seawater intrusion. Despite the simplicity of the Henry problem, it embodies the behavior of a typical seawater intrusion situation in a single aquifer. Data collected from the numerical problem solution are employed without added noise in order to focus on the aspects of inverse modeling strategies dictated by the physics of variable-density flow and solute transport during seawater intrusion. Covariances of model parameters that can be estimated are strongly dependent on the physics. The insights gained from this type of analysis may be directly applied to field problems in the presence of data errors, using standard inverse modeling approaches to deal with uncertainty in data.     

Towards quantifying uncertainty in transient climate change

Ensembles of coupled atmosphere–ocean global circulation model simulations are required to make probabilistic predictions of future climate change. “Perturbed physics” ensembles provide a new approach in which modelling uncertainties are sampled systematically by perturbing uncertain parameters. The aim is to provide a basis for probabilistic predictions in which the impact of prior assumptions and observational constraints can be clearly distinguished. Here we report on the first perturbed physics coupled atmosphere–ocean model ensemble in which poorly constrained atmosphere, land and sea-ice component parameters are varied in the third version of the Hadley Centre model (the variation of ocean parameters will be the subject of future study). Flux adjustments are employed, both to reduce regional sea surface temperature (SST) and salinity biases and also to admit the use of combinations of model parameter values which give non-zero values for the global radiation balance. This improves the extent to which the ensemble provides a credible basis for the quantification of uncertainties in climate change, especially at a regional level. However, this particular implementation of flux-adjustments leads to a weakening of the Atlantic overturning circulation, resulting in the development of biases in SST and sea ice in the North Atlantic and Arctic Oceans. Nevertheless, model versions are produced which are of similar quality to the unperturbed and un-flux-adjusted version. The ensemble is used to simulate pre-industrial conditions and a simple scenario of a 1% per year compounded increase in CO₂. The range of transient climate response (the 20 year averaged global warming at the time of CO₂ doubling) is 1.5–2.6°C, similar to that found in multi-model studies. Measures of global and large scale climate change from the coupled models show simple relationships with associated measures computed from atmosphere-mixed-layer-ocean climate change experiments, suggesting that recent advances in computing the probability density function of climate change under equilibrium conditions using the perturbed physics approach may be extended to the transient case.     

Long-term rates of chemical weathering and physical erosion from cosmogenic nuclides and geochemical mass balance

Quantifying long-term rates of chemical weathering and physical erosion is important for understanding the long-term evolution of soils, landscapes, and Earth's climate. Here we describe how long-term chemical weathering rates can be measured for actively eroding landscapes using cosmogenic nuclides together with a geochemical mass balance of weathered soil and parent rock. We tested this approach in the Rio Icacos watershed, Puerto Rico, where independent studies have estimated weathering rates over both short and long timescales. Results from the cosmogenic/mass balance method are consistent with three independent sets of weathering rate estimates, thus confirming that this approach yields realistic measurements of long-term weathering rates. This approach can separately quantify weathering rates from saprolite and from overlying soil as components of the total. At Rio Icacos, nearly 50% of Si weathering occurs as rock is converted to saprolite; in contrast, nearly 100% of Al weathering occurs in the soil. Physical erosion rates are measured as part of our mass balance approach, making it particularly useful for studying interrelationships between chemical weathering and physical erosion. Our data show that chemical weathering rates are tightly coupled with physical erosion rates, such that the relationship between climate and chemical weathering rates may be obscured by site-to-site differences in the rate that minerals are supplied to soil by physical erosion of rock. One can normalize for variations in physical erosion rates using the “chemical depletion fraction,” which measures the fraction of total denudation that is accounted for by chemical weathering. This measure of chemical weathering intensity increases with increasing average temperature and precipitation in data from climatically diverse granitic sites, including tropical Rio Icacos and six temperate sites in the Sierra Nevada, California. Hence, across a wide range of climate regimes, analysis of chemical depletion fractions appears to effectively account for site-to-site differences in physical erosion rates, which would otherwise obscure climatic effects on chemical weathering rates. Our results show that by quantifying rates of physical erosion and chemical weathering together, our mass balance approach can be used to determine the relative importance of climatic and nonclimatic factors in regulating long-term chemical weathering rates.     

An analysis of short-term albedo variations at Haut Glacier d'Arolla, Switzerland

Abstract An analysis of ten‐minute albedo variations, recorded on Haut Glacier d'Arolla, Switzerland, over an 11 day period in the 1999 ablation season is presented. Most of the short‐term (<1 day) albedo variability is caused by variations in cloud cover, while solar zenith angle variations in the range 25° to 75° are of minor importance, probably due to the predominantly cloudy conditions during the measurement period. A new method to calculate albedo variation as a function of cloud cover is developed. Short‐term albedo variations are expressed by the ratio of the measured albedo to the daily albedo ‘minimum’, defined as the albedo under cloud‐free conditions when the solar zenith angle is <50°. Variations in cloud cover are quantified by the ratio of the measured incoming shortwave radiation flux to the theoretical direct‐beam shortwave radiation flux. The resulting relationships are successful, explaining 83% and 87–90% of short‐term albedo variation on snow and ice respectively, and may be incorporated into albedo parameterizations already used in numerical energy balance melt models, without the need for additional data. Simulations with a glacier energy balance model suggest that melt rates are overestimated by between 1 and 3 mm water equivalent per day if a correction is not made for the increase in albedo under cloudy conditions. Other causes of albedo variation are identified and evidence is found for the removal of fine debris from the glacier surface by intense rainfall, leading to an albedo increase. The implications for energy balance models and satellite‐derived albedo measurements are discussed.     

Rock Strength and Development of Glacial Valley Morphology in the Scottish Highlands and Northwest Iceland

Using data from the Scottish Highlands and northwest Iceland, the present study indicates that bedrock strength properties are an important control on the morphology of glacial valleys. Results indicate that on closely jointed metasedimentary bedrock of low rock mass strength, broad U‐shaped valleys are developed, whilst steeper sided, narrower cross‐profiles have been developed on igneous bedrock of high rock mass strength. Findings suggest it is the interplay of the mass strength of the subglacial bedrock and the dynamic properties of the eroding glacier that control valley morphological development. The implication is that realistic models of topographic development beneath ice sheets need to consider the rock mass strength properties of the eroded bedrock as well as the glaciological variables.