Betekhtinite and bi-sulfosalts from the copper mine of „La Leona“ (Argentina)

The copper deposit La Leona consists of ore veins in a granite batholite which intruded into Permian sediments. In these veins the following minerals are observed: pyrite, sphalerite, chalcopyrite, galena, betekhtinite, two Bisulfosalts, electrum, bornite, chalcocite, enargite, tennantite, Zn-Fahlerz, cuprite, delafossite, molybdenite, hematite and iron hydroxides, and copper carbonates with quartz and iron carbonates as gangue. The betekhtinite, (CuFe)₁₀Pb S₆, found for the first time in Argentina, the Zn-Fahlerz and the sulfosalts (Cu_3.2Bi_1.2Pb_1.2S_8.5) and (Cu_9.3Bi_1.1S_6.8) were studied in detail under the microscope, by X-rays and by microprobe. Specifically, the paragenesis of these three minerals with galena, chalcocite and bornite is discussed.

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Résumé Le gisement de cuivre de la mine «La Leona» est formé de filons de minerais recoupant un batholite granitique qui a fait intrusion dans des sédiments permiens. Les minéraus suivants ont été observés: pyrite, blende, chalcopyrite, galène, bétekhtinite, deux sulfosels de Bi, électrum, bornite, chalcosine, énargite, tennantite, «Zn-Fahlerz», cuprite, delafossite, molybdénite, hématite et hydroxydes de fer, des carbonates de cuivre, dans une gangue de quartz et de carbonates de fer. La bétekhtinite (Cu Fe)₁₀Pb S₆, trouvée pour la première fois en Argentine, le «Zn-Fahlerz» et les sulfosels (Cu_3.2Bi_1.2Pb_1.2S_8.5) et (Cu_9.3Bi_1.1S_6.8) ont été spécialement étudiés à l'aide de la microscopie, de la diffraction des rayons-X et de la microsonde. La paragénèse formée par ces trois mineraux associés à la galène, la chalcosine et la bornite est discutée.

     

Oxidative stress in the mussel Mytella guyanensis from polluted mangroves on Santa Catarina Island,Brazil

Digestive glands of the mangrove mussel Mytella guyanensis, collected at one non-polluted site (site 1) and two polluted sites (sites 2 and 3), were analysed for different antioxidant defenses, lipid peroxidation and DNA damage. Thiobarbituric acid-reactive substance (TBARS) and 8-oxo-7,8-dihydro-2'-deoxyguanosine levels were enhanced at the polluted sites. With the exception of superoxide dismutase, the activities of catalase and glutathione peroxidase were also higher at the polluted sites. Greater increases were observed in glutathione reductase, glutathione S-transferase and etoxyresorufine-O-deethylase activities at the polluted sites. Conversely, reduced glutathione content was higher at the control site. Trace metal contents in mussels collected at polluted sites were increased compared to the control site, and there were strong positive correlations between TBARS and Cu and Pb contents. M. guyanensis is routinely exposed to an oxidative stress condition at both polluted sites, and considering xenobiotic bioaccumulation in bivalve molluscs, the mangrove mussel represents an excellent bioindicator for environmental monitoring studies.     

Late Pleistocene and Holocene Paleoenvironments of Chalco Lake, Central Mexico

In order to establish paleoenvironmental conditions during the late Quaternary, four cores from the Basin of Mexico (central Mexico) were drilled in Chalco Lake, located in the southeastern part of the basin. The upper 8 m of two parallel cores were studied, using paleomagnetic, loss-on-ignition, pollen, and diatom analyses. Based on 11 ¹⁴C ages, the analyzed record spans the last 19,000 ¹⁴C yr B.P. Volcanic activity has affected microfossil abundances, both directly and indirectly, resulting in absence or reduction of pollen and diatom assemblages. Important volcanic activity took place between 19,000 and 15,000 yr B.P. when the lake was a shallow alkaline marsh and an increase of grassland pollen suggests a dry, cold climate. During this interval, abrupt environmental changes with increasing moisture occurred. From 15,000 until 12,500 yr B.P. the lake level increased and the pollen indicates wetter conditions. The highest lake level is registered from 12,500 to ca. 9000 yr B.P. The end of the Pleistocene is characterized by an increase in humidity. From 9000 until ca. 3000 yr B.P. Chalco Lake was a saline marsh and the pollen record indicates warmer conditions. After 3000 yr B.P. the lake level increased and human disturbance dominates the lacustrine record.     

Phytoplankton absorption spectra along the water column in deep North Patagonian Andean lakes (Argentina)

During a summer period we studied the vertical variation of in vivo and chlorophyll a specific phytoplankton absorption spectra in relation to the underwater light climate of ten deep North Patagonian Andean lakes of Argentina. The lakes were thermally stratified, and the underwater light climate was characterized by extended euphotic zones which included highly illuminated epilimnetic layers (both UVR and PAR) and metalimnia exposed to dim blue-green light. Most of the lakes presented the development of Deep Chlorophyll Maxima (DCM) at the metalimnetic layers, near 1% of surface PAR irradiance. Analyzing the fourth-derivative plots of in vivo phytoplankton absorption spectra [d^IVa_ph(λ)], we were able to identify several maxima absorption values attributed to different pigments. Considering lakes with DCM, a significant positive linear relationship was found between d^IVa_ph (495–500 nm) normalized by chlorophyll a and downward irradiance. Indeed, a negative significant relationship was found between d^IVa_ph (495–500 nm) normalized by chlorophyll a and diffuse PAR attenuation coefficients. These results point out an increase in the relative concentration of different carotenoids at surface layers indicating the role of photoprotection of these pigments. On the other hand, significant negative linear relationships were found between fourth-derivative spectra normalized by chlorophyll a at 650, 590–595, 560–565 and 520–525 nm and downward irradiance. These results indicated an increase in the relative concentration of photosynthetic accessory pigments at deep layers of the euphotic zone. Furthermore, we found a decrease in depth of specific absorption spectra at 440, 670 nm and in the ratio a_ph* (440 nm) to a_ph* (670 nm). This pattern was associated with the package effect concept. The increase in relative photosynthetic accessory pigment concentrations and the decrease in values of specific absorption spectra at the bottom of the euphotic zone were attributed to changes in phytoplankton communities between surface and deep layers. These outcomes pointed out that the underwater light climate and temperature water structure are, like in marine systems, very important factors governing the distribution of phytoplanktonic organisms. In addition, the possession of specific photosynthetic accessory pigments suggests that dominant species in the DCM are well adapted to these dim blue-green light scenarios.     

Tebuthiuron leaching in three Brazilian soils as affected by soil pH

Underground contamination water by herbicides depends on the interactions between their molecules with physical and chemical soil characteristics and climatic conditions. Studies with columns can estimate the leaching potential of herbicides in soils. This study aimed to determine the effect of soil pH on tebuthiuron leaching, and capacity of bioindicators to detect tebuthiuron residues in three Brazilian soils. Cucumber plants (Cucumis sativus) were more negatively affected when grown in soils with lower amounts of organic matter and clay, and in these soils, the tebuthiuron levels reached greater depths in the column. There was a positive correlation between tebuthiuron concentration and cucumber intoxication, and a negative correlation between tebuthiuron concentration and dry matter cucumber in all soils. The tebuthiuron leached up to 50 cm depth even in soils with higher organic matter and clay content. The increasing of soil pH can affect the leaching of nonionic herbicides, and liming practice may elevate the environmental contamination risk by tebuthiuron. The bioindicator method using Cucumis sativus is viable and can be recommended to detect tebuthiuron concentrations above 0.2 mg kg^?1.     

Projections of temperature changes over South America during the twenty-first century using CMIP6 models

A 22-member ensemble from CMIP6 is used to analyze the projected changes and seasonal behavior in surface air temperature over South America during the twenty-first century. In the future projections, CMIP6 models shown a high dependency to the socioeconomic pathway over each country of South America. The multimodel ensemble projects a continuous increase in the annual mean temperature over South America during the twenty-first century under the three future scenarios (SSP1-2.6, SSP2-4.5 and SSP5-8.5). Besides, it was possible to identify consistent positive trends across all the models, with values between 0.45 ± 0.05 and 2.05 ± 0.31 °C cy⁻¹ under the historical experiment, however largest trends occurs for the projection periods (near, mid and far future), with values between − 0.87 ± 0.84 to 2.88 ± 0.60 °C cy⁻¹ (SSP1-2.6), 1.41 ± 0.88 to 5.32 ± 0.81 °C cy⁻¹ (SSP2-4.5) and 4.75 ± 0.58 to 8.76 ± 0.74 °C cy⁻¹ (SSP5-8.5) with maximum values at Bolivia, Brasil, Paraguay and Venezuela whilst minimum values for Argentina and Uruguay, regardless of the SSP scenario used. From the seasonal behavior analysis was possible to identify maximum values between January and March whilst minimum between June and July, except in Brasil, Venezuela and Guyana–Surinam–French Guayana, with annual range decreasing as the latidude decreases. By the end of the twenty-first century the annual mean temperature over South america is projected to increase between 0.92–2.11 °C, 0.97–3.37 °C and 1.27–6.14 °C under SSP1-2.6, SSP2-4.5 and SSP5-8.5 projection scenarios respectively. This projected increase of temperature across the continent will produce negative repercussions in the social, economic and political spheres. The results obtained in this study provide insights about the CMIP6 performance over this region, which can be used to develop adaptation strategies and might be useful for the adaptation to the climate change.

     

Magnetic properties of lake sediments from Lake Chalco,central Mexico,and their palaeoenvironmental implications

Lake Chalco (99.0°W, 19.5°N) in the Basin of Mexico, was formed during the Pleistocene after the emplacement of the Chichinautzin volcanic field that closed the former drainage system. The lake sediment record has been influenced by a number of factors, including glacial–interglacial cycles, local volcanism, erosion of soils and anthropogenic disturbances. The magnetic properties of the lake sediments and the associated tephra layers of the last 16500 yr have been studied. It is found that the magnetic properties of the Lake Chalco sediments are very distinctive. Magnetic concentration varies by a factor of 1000 and magnetic stability also varies over an extremely wide range. The predominant magnetic mineral is titanomagnetite in addition to an imperfect antiferromagnetic phase, possibly goethite. An unusually large range of coercivities is found in certain of the tephras. Down‐core variations in magnetic properties closely follow climatic/environmental changes previously established by other proxy methods. The late Pleistocene and late Holocene lake sediments display a higher concentration of magnetic minerals than the early–middle Holocene sediments. In the non‐volcanic sediments, fluctuations in the magnetic concentration reflect changes in both the intensity of erosion, as represented by ferrimagnetic and paramagnetic minerals, and by the maturing of soils, as represented by geothite. Copyright © 2000 John Wiley & Sons, Ltd.     

Comparison of C and N stable isotope ratios between surface particulate organic matter and microphytoplankton in the Gulf of Lions (NW Mediterranean)

Carbon and nitrogen stable isotope ratios of particulate organic matter (POM) in surface water and 63–200 μm-sized microphytoplankton collected at the fluorescence maximum were studied in four sites in the Gulf of Lions (NW Mediterranean), a marine area influenced by the Rhone River inputs, in May and November 2004. Some environmental (temperature, salinity) and biological (POM, Chlorophyll a and phaeopigments contents, phytoplankton biomass and composition) parameters were also analysed. Significantly different C and N isotopic signatures between surface water POM and microphytoplankton were recorded in all sites and seasons. Surface water POM presented systematically lower δ¹³C (∼4.2‰) and higher δ¹⁵N (∼2.8‰) values than those of microphytoplankton, due to a higher content of continental and detrital material. Seasonal variations were observed for all environmental and biological parameters, except salinity. Water temperature was lower in May than in November, the fluorescence maximum was located deeper and the Chlorophyll a content and the phytoplankton biomass were higher, along with low PON/Chl a ratio, corresponding to spring bloom conditions. At all sites and seasons, diatoms dominated the phytoplankton community in abundance, whereas dinoflagellate importance increased in autumn particularly in coastal sites. C and N isotopic signatures of phytoplankton did not vary with season. However, the δ¹⁵N of surface water POM was significantly higher in November than in May in all sites likely in relation to an increase in ¹⁵N/¹⁴N ratio of the Rhone River POM which influenced surface water in the Gulf of Lions. As it is important to determine true baseline values of primary producers for analysing marine food webs, this study demonstrated that C and N isotopic values of surface water POM cannot be used as phytoplankton proxy in coastal areas submitted to high river inputs.     

Forced oscillation measurements of seismic attenuation in fluid saturated sandstone

Adopting the method of forced oscillation, attenuation was studied in Fontainebleau sandstone (porosity 10%, permeability 10 mD) at seismic frequencies (1–100 Hz). Confining pressures of 5, 10, and 15 MPa were chosen to simulate reservoir conditions. First, the strain effect on attenuation was investigated in the dry sample for 11 different strains across the range 1 × 10^?6–8 × 10^?6, at the confining pressure of 5 MPa. The comparison showed that a strain of at least 5 × 10^?6 is necessary to obtain a good signal to noise ratio. These results also indicate that nonlinear effects are absent for strains up to 8 × 10^?6. For all the confining pressures, attenuation in the dry rock was low, while partial (90%) and full (100%) saturation with water yielded a higher magnitude and frequency dependence of attenuation. The observed high and frequency dependent attenuation was interpreted as being caused by squirt flow.