Laboratory Evaluation of Zero Valent Iron and Sulfur‐Modified Iron for Agricultural Drainage Water Treatment

Agricultural subsurface drainage waters containing nutrients (nitrate/phosphate) and pesticides are discharged into neighboring streams and lakes, frequently producing adverse environmental impacts on local, regional, and national scales. On‐site drainage water filter treatment systems can potentially prevent the release of agricultural contaminants into adjacent waterways. Zero valent iron (ZVI) and sulfur‐modified iron (SMI) are two types of promising filter materials that could be used within these treatment systems. Therefore, water treatment capabilities of three ZVI and three SMI filter materials were evaluated in the laboratory. Laboratory evaluation included saturated falling‐head hydraulic conductivity tests, contaminant removal batch tests, and saturated solute transport column experiments. The three ZVI and the three SMI filter materials, on average, all had a sufficient hydraulic conductivity greater than 1 × 10^–3 cm/s. Batch test results showed a phosphate decrease of at least 94% for all tests conducted with the ZVI and SMI. Furthermore, the three SMI filter materials removed at least 86% of the batch test nitrate originally present, while batch tests for one of the ZVI filter materials exhibited an 88% decrease in the pesticide, atrazine. Saturated solute transport column experiments were carried on the best ZVI filter material, or the best SMI filter material, or both together, in order to better evaluate drainage water treatment effectiveness and efficiency. Results from these column tests additionally document the drainage water treatment ability of both ZVI and SMI to remove the phosphate, the ability of SMI to remove nitrate, and the ability of a select ZVI material to remove atrazine. Consequently, these findings support further investigation of ZVI and SMI subsurface drainage water treatment capabilities, particularly in regard to small‐ and large‐scale field tests.     

Northern fulmars as biological monitors of trends of plastic pollution in the eastern North Pacific

Marine plastic debris is a global issue, which highlights the need for internationally standardized methods of monitoring plastic pollution. The stomach contents of beached northern fulmar (Fulmarus glacialis) have proven a cost-effective biomonitor in Europe. However, recent information on northern fulmar plastic ingestion is lacking in the North Pacific. We quantified the stomach contents of 67 fulmars from beaches in the eastern North Pacific in 2009-2010 and found that 92.5% of fulmars had ingested an average of 36.8 pieces, or 0.385g of plastic. Plastic ingestion in these fulmars is among the highest recorded globally. Compared to earlier studies in the North Pacific, our findings indicate an increase in plastic ingestion over the past 40years. This study substantiates the use of northern fulmar as biomonitors of plastic pollution in the North Pacific and suggests that the high levels of plastic pollution in this region warrant further monitoring.     

Recognition of down-valley translation in tidally influenced meandering fluvial deposits,Athabasca Oil Sands (Cretaceous), Alberta,Canada

The vast Athabasca Oil Sands of Alberta, Canada has an estimated resource of more than 1.7 trillion barrels of bitumen in-place, the majority of which is hosted in the Lower Cretaceous McMurray Formation. Despite its economical significance the depositional environment of the formation, and particularly the middle part that is the primary reservoir in most areas, is still a matter of considerable debate. These strata of interest are widely known to comprise fluvial and estuarine point bar deposits that were subject to varying degrees of marine influence. The orientation of point bar strata from the formation is tabulated and the majority is observed to dip paleo-basinward, to the north. This observation has proven difficult to explain by geologists attempting to build predictive models for the formation over the last two decades. However, the basinward-dipping point bar strata can be attributed to widespread down-valley translation of point bars in confined north-south oriented valleys, which have previously been delineated in the region. Differentiating the deposits of lateral point bar migration and down-valley translation in the rock record is not possible at the facies scale, and thus translated point bars have not been previously recognized or interpreted in the rock record, despite their prevalence in numerous modern fluvial valley systems. Their identification in the McMurray Formation has important implications for the delineation and development of Canada’s economically significant oil sands resources.     

Numerical simulation of two-phase flow for sediment transport in the inner-surf and swash zones

A two-dimensional two-phase flow framework for fluid–sediment flow simulation in the surf and swash zones was described. Propagation, breaking, uprush and backwash of waves on sloping beaches were studied numerically with an emphasis on fluid hydrodynamics and sediment transport characteristics. The model includes interactive fluid–solid forces and intergranular stresses in the moving sediment layer. In the Euler–Euler approach adopted, two phases were defined using the Navier–Stokes equations with interphase coupling for momentum conservation. The k–ε$k''–''\epsilon$ closure model and volume of fluid approach were used to describe the turbulence and tracking of the free surface, respectively. Numerical simulations explored incident wave conditions, specifically spilling and plunging breakers, on both dissipative and intermediate beaches. It was found that the spatial variation of sediment concentration in the swash zone is asymmetric, while the temporal behavior is characterized by maximum sediment concentrations at the start and end of the swash cycle. The numerical results also indicated that the maximum turbulent kinetic energy and sediment flux occurs near the wave-breaking point. These predictions are in general agreement with previous observations, while the model describes the fluid and sediment phase characteristics in much more detail than existing measurements. With direct quantifications of velocity, turbulent kinetic energy, sediment concentration and flux, the model provides a useful approach to improve mechanistic understanding of hydrodynamic and sediment transport in the nearshore zone.     

Transport of nonsorbing solutes in a streambed with periodic bedforms

Previous studies of hyporheic zone focused largely on the net mass transfer of solutes between stream and streambed. Solute transport within the bed has attracted less attention. In this study, we combined flume experiments and numerical simulations to examine solute transport processes in a streambed with periodic bedforms. Solute originating from the stream was subjected to advective transport driven by pore water circulation due to current–bedform interactions as well as hydrodynamic dispersion in the porous bed. The experimental and numerical results showed that advection played a dominant role at the early stage of solute transport, which took place in the hyporheic zone. Downward solute transfer to the deep ambient flow zone was controlled by transverse dispersion at the later stage when the elapsed time exceeded the advective transport characteristic time t_c (= L/u_c with L being the bedform length and u_c the characteristic pore water velocity). The advection-based pumping exchange model was found to predict reasonably well solute transfer between the overlying water and streambed at the early stage but its performance deteriorated at the later stage. With dispersion neglected, the pumping exchange model underestimated the long-term rate and total mass of solute transfer from the overlying water to the bed. Therefore both advective and dispersive transport components are essential for quantification of hyporheic exchange processes.     

Evaluation of a peat filtration system for treating highway runoff in a karst setting

The deleterious character of highway runoff, especially following long periods without precipitation, has been well documented in the literature. It transports hydrocarbons, heavy metals, and other contaminants from highways, contributing to the pollution of surface water and groundwater. Groundwater is particularly vulnerable in karst areas where highway runoff is transferred quickly into subsurface conduit networks through open sinkholes and/or sinking streams. The difficulties in remediating contaminated karst aquifers make it crucial for karst aquifers to receive only uncontaminated water. A peat filtration system was constructed at the I-40/I-640 interchange in eastern Knoxville, Tennessee, USA, to remove highway runoff contaminants prior to being transported into karst aquifers. Recent field tests indicate that the system can significantly decrease the concentrations of analyzed constituents including PAHs (polyaromatic hydrocarbons), copper, and zinc. However, the removal efficiency depends on the concentration of the contaminants in the runoff. Long-term monitoring is required to determine the true effectiveness of the designed filtration system and its reliability.     

Mass and energy flow near sunspots

Sunspots block the flow of energy to the solar surface. The blocked energy heats the volume beneath the spot, producing a pressure excess which drives an outflow of mass. Linear numerical models of the mass and energy flow around spots were constructed to estimate the predictions of this physical picture against the observed properties of sunspot bright rings and moat flows. The width of the bright ring and moat are predicted to be proportional to the depth of the spot penumbra, in conflict with the observed proportionally of the moat width to the spot diameter. Postulating that spot depths are proportional to spot diameters would bury the moat flow too deeply to be observed, because the radial velocity at the surface is found to be inversely proportional to the depth of the spot penumbra. The radial velocity at the surface is of order a few hundred meters per second after 1 day, in agreement with the observed excess of moat velocities over supergranule velocities.     

An early Holocene oxygen isotope record from the Olson buried forest bed, Southern Lake Michigan

Analysis of a 3.5 m vibracore from the Olson buried forest bed in the southern Lake Michigan basin provides new paleolimnological data for the early Holocene. The core records a rise in lake level from the Chippewa low water phase toward the Nipissing high water phase. Deepening of the water level at the core site is suggested by a trend toward decreasing organic carbon content up core that is interpreted as a response to increasing distance between terrestrial debris sources and the core site.Published data from deep water cores from the southern Lake Michigan basin suggest there had been an inflow of isotopically light water from glacial Lake Agassiz into the southern basin between 10.5-11 ka (A1 event). The data also indicate a second flood of isotopically light water between 8-9 ka (A2 event).Three new ¹⁴C dates from the Olson site core suggest that most of the sediment was deposited between 8.45 ka and 8.2 ka, an interval roughly coeval with the second pulse of ¹⁸O-depleted water (A2) from Lake Agassiz into the southern basin. Oxygen isotope ratio analysis of shell aragonite from the gastropods Probythinella lacustris and Marstonia deceptashows increasingly negative values up core. This trend in¹⁸O values suggests that ¹⁸O - depleted water entered the southern basin about 8.4 ka. The Olson site core thus provides a chronology of events in the southern Lake Michigan basin associated with the draining of glacial Lake Agassiz.