An aerosol climatology of Samoa

An atmospheric monitoring station is operated at Cape Matatula, American Samoa, by the Geophysical Monitoring for Climatic Change program under the National Oceanic and Atmospheric Administration. A nearly continuous record of condensation nucleus (CN) concentration and multiwavelength aerosol scattering extinction coefficient (_sp) is available from mid-1977 to the present. This report presents the 1977–1983 data. The long-term mean of CN concentration is 274 cm^-3 the long-term mean of _sp (550 nm) is 1.54×10^-5, and no significant long-term, annual, or diurnal trend is apparent in either data record.     

X-Ray Fluorescence Determination of Trace Elements in 6 B.C.S. and 5 P.R.E. Reference Materials

The concentrations of 20 trace elements in 6 British Chemical Standards (BCS) reference materials and 5 European Federation of Refractories Producers (PRE) reference materials have been determined by X-ray fluorescence spectrometry.     

The contribution of humic substances to the acidity of colored natural waters

An operationally defined carboxyl content of humic substances extracted from rivers, streams, lakes, wetlands, and groundwaters throughout the United States and Canada is reported. Despite the diversity of the samples, only small variations were observed in this humic carboxyl content. The dissociation behavior of two combined fulvic/humic acid extracts was studied and it was found that the dissociation of the humics varied in a predictable manner with pH. Using a carboxyl content of 10 μeq/ mg humic organic carbon, and mass action quotient calculated from sample pH, the ionic balances of three highly colored Nova Scotia rivers were estimated.     

A derived probability distribution approach to stormwater quality modeling

The closed-form analytical stormwater quality models are developed for simulating urban catchment pollutant buildup and washoff processes. By integrating the rainfall–runoff transformation with pollutant buildup and washoff functions, stormwater quality measures, such as the cumulative distribution functions (CDFs) of pollutant loads, the expected value of pollutant event mean concentrations (EMCs) and the average annual pollutant load can be derived. This paper presents methodologies and major procedures for the development of urban stormwater quality models based on derived probability distribution theory. In order to investigate the spatial variation in model parameters and its impact on stormwater pollutant buildup and washoff processes as well as pollutant loads to receiving waters, an extended form of the original rainfall–runoff transformation which is based on lumped runoff coefficient approach is proposed to differentiate runoff generation mechanisms between the impervious and pervious areas of the catchment. In addition, as a contrast to the aggregated pollutant buildup models formulated with a single lumped buildup parameter, the disaggregated form of the pollutant buildup model is proposed by introducing a number of physically-based parameters associated with pollutant buildup and washoff processes into the pollutant load models. The results from the case study indicate that analytical urban stormwater management model are capable of providing results in good agreement with the field measurements, and can be employed as alternatives to continuous simulation models in the evaluation of long-term stormwater quality measures.     

Secondary dispersion from gold deposits in west Turkey

Orientation studies over the Sarpda? prospect in the Biga peninsula and the Arapdagi deposit near Izmir have provided elear evidence for elemental dispersion around west Turkish gold prospects. Although these deposits are of different types, silicification associated with the deposits results in the main part of both deposits forming topographic highs.At Sarpda? gold mineralisation is relatively weak compared with nearby prospects and associated with a silicified cap on the main hill. Comparison of coarse and fine fractions, based on a 190 μm size split of 8 kg of -2 mm material, suggests that gold disperses clastically on the steep slopes, probably within silica, but coarse grains break down giving Au concentrations in the finer fractions at the base of the main slope. Discrete gold grains, that can be panned, only occur 1–2 km downstream within the streams and heavy mineral concentrations are very limited. This interpretation of Au dispersion is consistent with the data from 1 kg samples collected at the higher primary grade, but more contaminated, Arapda?i prospect.Antimony is the most consistent pathfinder both for the silicified cap at Sarpda? and for gold-rich veins at Arpada?i. It gives high contrast anomalies. Arsenic is useful being more mobile than Sb, although contrast may be low. High resolution Ag data can be useful but base metal enrichments are also often associated with Ag anomalies. Most prospects have some base metal enrichments although they can be displaced from the main gold-rich parts of the deposit and anomalies may be weak. Lead and Cu are the more consistently useful elements.The use of large (> 8 kg of -2 mm material) samples produces consistent stream sediment data that can be used to reliably interpret single samples and quantify Au anomalies. A survey around the Halíköy Hg and Emirli Sb mines, using these large samples, confirmed the extension of the known gold-bearing Emirli structure. In contrast the major Hg-bearing Halíköy Fault is gold poor although a structure parallel to it is auriferous.     

A note on peak-to-mean concentration ratios

The peak-to-mean concentration ratio obtained from observations near a point source of pollution is a particular example of the ratio of any short-period concentration to the long-term mean. The value of this ratio may be obtained from the probability distribution function: $$F(C) = F(0) exp [ - F(0) C/M]$$ whereF(C) is the probability or frequency that the ratio of a short-period average concentration (C) to the long-term mean (M) exceeds the valueC/M, andF(0) is a parameter dependent on the length of the short period and the position of the sampler relative to the centre-line of the plume. From (1) the peak-to-mean concentration ratio is shown to be related to the two averaging times by the expression $$P/M = 1/F(0) [lnF(0) - lnt_M /t_P ]$$ wheret _M andt _P are, respectively, the averaging times of the long-term meanM and the short-term peakP. Using recently published experimental data, Equation (1) and hence also (2) are shown to be valid for averaging timest _P from 5 s to 24 h and oft _M from 6 min to 5 yr providedt _P ?t _M .