Preterrestrial aqueous alteration of the Lafayette (SNC) meteorite

Abstract— The Lafayette meteorite, a nakhlite of the SNC (Martian?) group, contains hydrous alteration materials as intergranular films and as veinlets and patches replacing olivine, pyroxenes, and high-Si glass. The alteration materials (“iddingsite”) consist of ferroan smectite clays, magnetite (or maghemite), and ferrihydrite, as shown by SEM and TEM. Three varieties of veinlets are present and formed in the order: coarse phyllosilicate; fine-grained (phyllosilicate-oxide), and porous oxide. Veinlets of fine-grained material cross-cut coarse phyllosilicate veinlets. The alteration materials are preterrestrial, as they are older than Lafayette's fusion crust, which is glassy and not affected by any alterations. Approaching the crust, the veinlets are progressively modified to the point of melting, and progressively depleted in adsorbed volatile constituents (S, Cl, and P). Bulk compositions of the alteration veinlets (SEM and TEM EDX) are consistent with the observed mineralogy, and suggest: that the smectite contains significant adsorbed S and Cl; that the ferrihydrite contains significant adsorbed S, but not Cl; that rare grains of sulfate (Ca?) and chloride (Na or K?) are present; and that the compositions of the alteration materials are approximated by Lafayette's olivine + high-Si glass + water. We estimate that Lafayette's alteration materials formed at less than 100 °C. The oxidation potential of the water was near or slightly below that of the magnetite-hematite buffer. The presence of sulfate and chloride in discrete phases and as adsorbates on ferrihydrite and smectite suggests that the altering solutions were saline. However, relatively little mass was transferred into or out of Lafayette because the bulk composition of the alteration materials is nearly isochemical with a mixture of magmatic silicate phases and water. Chemical transport within Lafayette was also limited, as alteration materials preserve some chemical signature of their host minerals. Presence of alteration materials along only some grain boundaries and some cracks suggests that Lafayette was not soaked in fluid. These last two inferences suggest that the alteration of Lafayette took place during episodic infiltrations of small volumes of saline water.     

Compositional variations of olivines and pyroxenes in chondritic interplanetary dust particles

Abstract We report here analyses of olivines and pyroxenes, and petrofabrics of 27 chondritic interplanetary dust particles (IDPs), comparing those from anhydrous and hydrous types. Approximately 40% of the hydrous particles contain diopside, a probable indicator of parent body thermal metamorphism, while this mineral is rarely present in the anhydrous particles. Based on this evidence, we find that hydrous and anhydrous IDPs are, in general, not directly related, and we conclude that olivine and pyroxene major-element compositions can be used to help discriminate between IDPs that are (1) predominantly nebular condensates, and lately resided in anhydrous or icy (no liquids) primitive parent bodies, and (2) those originating from more geochemically active parent bodies (probably hydrous and anhydrous asteroids).     

OBS development at Bedford Institute of Oceanography

The Ocean Bottom Seismometer (BOBS) designed and built at BIO is described. The instrument is small, easy to handle and has performed reliably. Signals from two geophones and one hydrophone are recorded continuously for up to 10 days. A microcomputer is used as the clock and control.An account of past use, and future plans is given.     

Assimilation of snow covered area information into hydrologic and land-surface models

This paper describes a data assimilation method that uses observations of snow covered area (SCA) to update hydrologic model states in a mountainous catchment in Colorado. The assimilation method uses SCA information as part of an ensemble Kalman filter to alter the sub-basin distribution of snow as well as the basin water balance. This method permits an optimal combination of model simulations and observations, as well as propagation of information across model states. Sensitivity experiments are conducted with a fairly simple snowpack/water-balance model to evaluate effects of the data assimilation scheme on simulations of streamflow. The assimilation of SCA information results in minor improvements in the accuracy of streamflow simulations near the end of the snowmelt season. The small effect from SCA assimilation is initially surprising. It can be explained both because a substantial portion of snowmelts before any bare ground is exposed, and because the transition from 100% to 0% snow coverage occurs fairly quickly. Both of these factors are basin-dependent. Satellite SCA information is expected to be most useful in basins where snow cover is ephemeral. The data assimilation strategy presented in this study improved the accuracy of the streamflow simulation, indicating that SCA is a useful source of independent information that can be used as part of an integrated data assimilation strategy.     

Thirteen plus one: a comparison of global climate policy architectures

We critically review the Kyoto Protocol and thirteen alternative policy architectures for addressing the threat of global climate change. We employ six criteria to evaluate the policy proposals: environmental outcome, dynamic efficiency, cost-effectiveness, equity, flexibility in the presence of new information, and incentives for participation and compliance. The Kyoto Protocol does not fare well on a number of criteria, but none of the alternative proposals fare well along all six dimensions. We identify several major themes among the alternative proposals: Kyoto is “too little, too fast”; developing countries (DCs) should play a more substantial role and receive incentives to participate; implementation should focus on market-based approaches, especially those with price mechanisms; and participation and compliance incentives are inadequately addressed by most proposals. Our investigation reveals tensions among several of the evaluative criteria, such as between environmental outcome and efficiency, and between cost-effectiveness and incentives for participation and compliance.     

A ROSAT observation of the dipping, flaring and eclipsing polar MN Hya (RX J0929.1–2404)

We present the results of a 22.5 ks pointed ROSAT PSPC observation of the 3.4-h period eclipsing polar MN Hya (RX J0929.1−2404). The X-ray light curve exhibits a 'double-humped' shape, with a secondary minimum occuring at φ∼ 0.45, a morphology consistent with two-pole accretion. Strong aperiodic flaring activity, with flux enhancements of ∼ 6 × the quiescent level, is also observed. A pre-eclipse 'dip' occurs in the phase interval φ= 0.87–0.95 with the X-rays becoming harder, indicative of photoelectric absorption by the pre-shock flow. There is also evidence of a secondary spectrally hard 'dip' near φ = 0.45–0.55, which might be associated with a second accretion stream flowing to the other magnetic pole.   The X-ray spectrum is best represented by a combination of a ∼50 eV blackbody and a thermal bremsstrahlung component of kT 1.6 keV, with a total absorption column of N _H  = 2.9 × 10²⁰ cm⁻².   The primary maximum (φ∼ 0.65) has a slightly larger column and normalization compared to the secondary maximum. Although there are few photons, the dip spectrum is very flat in comparison to other phases, and is best represented by a single bremsstrahlung component. This is indicative of the spectral hardening seen in the light curves attributed to photoabsorption. The ratio of unabsorbed bremsstrahlung and blackbody luminosities is ∼ 0.1 for the best-fitting average spectral models. This implies a magnetic field strength  30 MG on the basis of the empirical L _hard/ L _soft −  B relationships, although consideration of the cyclotron flux and aspect effects could allow for an even higher field (55 MG).     

Shock compression of deuterium to 900 Kbar

An experimental program to compress liquid deuterium with a two-stage gun is described. A xenon standard was used to check the adequacy of the EOS of the Dural container in the 7000 (1.7 Mbar) to 3000° K (0.0 Mbar) range. The agreement is reasonable. Further work on this standard is in progress to improve the accuracy. The target design parameters were checked with some sound speed measurements which confirm the liquid-like behavior of Dural at the temperatures, pressures, and strain rates of these experiments. The uncertainties of the results are analyzed and tabulated with the data. Comparison between the molecular and the metallic equations of state indicates a small volume change on metallization due to the high compressibility of the molecular phase vis-a-vis the metallic phase.     

Geology and volcanic stratigraphy of the Canatuan and Malusok volcanogenic massive sulfide deposits,southwestern Mindanao,Philippines

The Canatuan and Malusok massive sulfide deposits are located near Siocon, Zamboanga del Norte, in southwestern Mindanao, Philippines. The Canatuan–Malusok area is underlain by the Jurassic–Cretaceous Tungauan schists, which form much of the Zamboanga Peninsula. The volcanic strata at Canatuan and Malusok can be traced for >7 km along strike and is host to at least three discrete massive sulfide bodies: Canatuan, Malusok and SE Malusok. Basal basaltic andesite volcanic rocks are generally chemically uniform and show only moderate alteration. The massive sulfide deposits occur in overlying rhyolitic to rhyodacitic volcanic rocks that are altered to a schistose assemblage of quartz, sericite, chlorite and pyrite. The alteration is texturally destructive but graded clastic beds are locally observed. Despite tropical saprolitic weathering, four lithogeochemical subunits of the felsic package are identified. Stratigraphic interleaving, however, has made correlation of these units over any significant distance difficult. The sulfide lenses are overlain by a few metres of felsic schists which locally contain manganese-bearing silicates and oxides that serve as a stratigraphic marker. Hangingwall andesitic volcaniclastic rocks are discontinuously preserved, although where present, they consist of regularly bedded mafic volcanic sandstones. The lateral continuity of a manganese-bearing marker and flanking felsic volcaniclastic intervals indicate that locally the volcanic strata form a homoclinal sequence. The Canatuan Au–Ag–Cu–Zn deposit consists of a gossan overlying a massive sulfide lens. The sulfides and gossan are flat lying and hosted within felsic volcanic rocks. The gossan is gold–silver-rich, and was formed by a combination of oxidation and volume collapse of the original sulfide lens. The sulfide minerals present below the current water table, are auriferous massive pyrite with base metal sulfides, with some supergene chalcocite. The transition from gossan to sulfides is very sharp, occurring at the water table. Massive sulfide deposits at Malusok are hosted in the same felsic sequence as Canatuan and they have similar base and precious metal contents. Only limited gossan has been found at Malusok. The bimodal nature of the volcanic rocks at Canatuan, together with their low HFSE contents, near-flat REE patterns and tholeiitic affinities, suggest that they formed in an intra-oceanic arc setting above a depleted mantle source. Mafic and felsic volcanic rocks of similar composition have been recovered from the Tonga-Kermadec and Izu-Bonin-Marianas island-arc systems in the western Pacific. Mafic rocks at Canatuan show no evidence for LILE enrichment that characterizes melts derived from metasomatized mantle under more mature arcs, suggesting that they are the product of a nascent, rather than a mature arc. There is no evidence from the REE, or other incompatible trace elements, that continental crust or evolved arc crust was involved in the generation of the Canatuan-Malusok volcanic rocks. Although it has been proposed that the Zamboanga metamorphic complex comprises microcontinental fragments of Eurasian affinity, our data do not support an evolved crustal setting for the Canatuan-Malusok volcanic rocks, which we suggest were derived from an intra-oceanic arc and subsequently accreted to the eastern Mindanao terrane.Electronic Supplementary Material Supplementary material is available in the online version of this article at http://dx.doi.org/10.1007/s00126-003-0350-7Editorial handling: R.R. Large     

The Palaeoproterozoic Kristineberg VMS deposit, Skellefte district, northern Sweden, part I: geology

The Kristineberg volcanic-hosted massive sulphide (VMS) deposit, located in the westernmost part of the Palaeoproterozoic Skellefte district, northern Sweden, has yielded 22.4 Mt of ore, grading 1.0% Cu, 3.64% Zn, 0.24% Pb, 1.24 g/t Au, 36 g/t Ag and 25.9% S, since the mine opened in 1941, and is the largest past and present VMS mine in the district. The deposit is hosted in a thick pile of felsic to intermediate and minor mafic metavolcanic rocks of the Skellefte Group, which forms the lowest stratigraphic unit in the district and hosts more than 85 known massive sulphide deposits. The Kristineberg deposit is situated lower in the Skellefte Group than most other deposits. It comprises three main ore zones: (1) massive sulphide lenses of the A-ore (historically the main ore), having a strike length of about 1,400 m, and extending from surface to about 1,200 m depth, (2) massive sulphide lenses of the B-ore, situated 100–150 m structurally above the A-ore, and extending from surface to about 1,000 m depth, (3) the recently discovered Einarsson zone, which occurs in the vicinity of the B-ore at about 1,000 m depth, and consists mainly of Au–Cu-rich veins and heavily disseminated sulphides, together with massive sulphide lenses. On a regional scale the Kristineberg deposit is flanked by two major felsic rock units: massive rhyolite A to the south and the mine porphyry to the north. The three main ore zones lie within a schistose, deformed and metamorphosed package of hydrothermally altered, dominantly felsic volcanic rocks, which contain varying proportions of quartz, muscovite, chlorite, phlogopite, pyrite, cordierite and andalusite. The strongest alteration occurs within 5–10 m of the ore lenses. Stratigraphic younging within the mine area is uncertain as primary bedding and volcanic textures are absent due to strong alteration, and tectonic folding and shearing. In the vicinity of the ore lenses, hydrothermal alteration has produced both Mg-rich assemblages (Mg-chlorite, cordierite, phlogopite and locally talc) and quartz–muscovite–andalusite assemblages. Both types of assemblages commonly contain disseminated pyrite. The sequence of volcanic and ore-forming events at Kristineberg is poorly constrained, as the ages of the massive rhyolite and mine porphyry are unknown, and younging indicators are absent apart from local metal zoning in the A-ores. Regional structural trends, however, suggest that the sequence youngs to the south. The A- and B-ores are interpreted to have formed as synvolcanic sulphide sheets that were originally separated by some 100–150 m of volcanic rocks. The Einarsson zone, which is developed close to the 1,000 m level, is interpreted to have resulted in part from folding and dislocation of the B-ore sulphide sheet, and in part from remobilisation of sulphides into small Zn-rich massive sulphide lenses and late Au–Cu-rich veins. However, the abundance of strongly altered, andalusite-bearing rocks in the Einarsson zone, coupled with the occurrence of Au–Cu-rich disseminated sulphides in these rocks, suggests that some of the mineralisation was synvolcanic and formed from strongly acidic hydrothermal fluids. Editorial handling: P. Weihed