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661.
The influence of carbon source on abiotic organic synthesis and carbon isotope fractionation under hydrothermal conditions 总被引:2,自引:0,他引:2
Thomas M. McCollom Barbara Sherwood Lollar Jeffrey S. Seewald 《Geochimica et cosmochimica acta》2010,74(9):2717-155
A series of laboratory experiments were performed to investigate the relative contributions of CO and other single-carbon compounds to abiotic synthesis of organic compounds in hydrothermal environments. Experiments were conducted by heating aqueous solutions of CO, CO2, HCOOH, or CH4 at 250 °C under reducing conditions, and observing production of CH4 and other hydrocarbons. Native Fe was included in the experiments as a source of H2 through reaction with water and as a potential catalyst. Experiments with CO or HCOOH as the carbon source resulted in rapid generation of CH4 and other hydrocarbons that closely resembled typical products of Fischer-Tropsch organic synthesis. In contrast, experiments using CO2 or CH4 as the carbon source yielded no detectable hydrocarbon products. Carbon isotope measurements of reaction products from the CO experiments indicate that the CH4 and other hydrocarbons were substantially depleted in 13C, with CH4 δ13C values 30 to 34‰ lighter than the initial CO. Most of the fractionation apparently occurs during attachment of CO to the catalyst surface and subsequent reduction to surface-bound methylene. The initial step in polymerization of these methylene units to form hydrocarbons involves a small, positive fractionation, so that ethane and ethene are slightly enriched in 13C relative to CH4. However, subsequent addition of carbon molecules to the growing hydrocarbon chain proceeds with no net observable fractionation, so that the isotopic compositions of the C3+ light hydrocarbons are controlled by isotopic mass balance. This result is consistent with a previously proposed model for carbon isotopic patterns of light hydrocarbons in natural samples. The abundance and isotopic composition of light hydrocarbons produced with HCOOH as the carbon source were similar to those generated with CO, but the isotopic compositions of non-volatile hydrocarbons diverged, suggesting that the higher hydrocarbons were formed by different mechanisms in the CO and HCOOH experiments. The experiments indicate that CO, and possibly HCOOH, may be critical intermediates in the abiotic formation of organic compounds in geologic environments, and suggest that the low levels of these compounds present in most hydrothermal systems could represent a bottleneck restricting the extent of abiotic organic synthesis in some circumstances. 相似文献
662.
Tewodros Rango Riccardo Petrini Barbara Stenni Gianluca Bianchini Francesca Slejko Luigi Beccaluva Tenalem Ayenew 《Applied Geochemistry》2010,25(12):1860-1871
Water samples from cold and geothermal boreholes, hot springs, lakes and rivers were analyzed for δD, δ18O and 87Sr/86Sr compositions in order to investigate lake water–groundwater mixing processes, water–rock interactions, and to evaluate groundwater flow paths in the central Main Ethiopian Rift (MER) of the Ziway–Shala basin. Different ranges of isotopic values were recorded for different water types: hot springs show δ18O −3.36 to +3.69 and δD −15.85 to +24.23, deep Aluto-Langano geothermal wells show δ18O −4.65 to −1.24 and δD −12.39 to −9.31, groundwater wells show δ18O −3.99 to +5.14 and δD −19.69 to +32.27, whereas the lakes show δ18O and δD in the range +3.98 to +7.92 and +26.19 to +45.71, respectively. The intersection of the Local Meteoric Water Line (LMWL: δD = 7 δ18O + 11.2, R2 = 0.94, n = 42) and the Local Evaporation Line (LEL: δD = 5.63δ18O + 8, n = 14, R2 = 0.82) was used to estimate the average isotopic composition of recharge water into the basin (δD = −5.15 and δ18O = −2.34). These values are depleted if compared with the modern-day average precipitation, presumably indicating paleo-groundwater components recharged during previous humid climatic phases. The measured stable isotope values indicate that the geothermal wells, some of the hot springs and groundwater wells mainly consist of meteoric water. The Sr isotopic signatures in all waters are within the range of the Sr isotopic composition of the rift basalts and rhyolites. The variability of Sr isotopic data also pinpoints complex water–rock interaction and mixing processes in groundwater and surface water. The 87Sr/86Sr ratio ranges from 0.70445 to 0.70756 in the hot springs, from 0.70426 to 0.70537 in two deep geothermal wells, and from 0.70673 to 0.70721 in the rift lakes Ziway, Langano, Shala and Awasa. The radiogenic composition recorded by the lakes indicates that the input water was predominantly affected by progressive interaction with rhyolitic volcanics and lacustrine sediments. 相似文献
663.
664.
P. G. Brown P. J. A. McCausland A. R. Hildebrand L. T. J. Hanton L. M. Eckart H. Busemann D. Krietsch C. Maden K. Welten M. W. Caffee M. Laubenstein D. Vida F. Ciceri E. Silber C. D. K. Herd P. Hill H. Devillepoix Eleanor K. Sansom Martin Cupák Seamus Anderson R. L. Flemming A. J. Nelson M. Mazur D. E. Moser W. J. Cooke D. Hladiuk Barbara Malečić Maja Telišman Prtenjak R. Nowell The Golden Meteorite Consortium 《Meteoritics & planetary science》2023,58(12):1773-1807
665.
Surface water on the mainly dry, upland interfluves of the Upper Coastal Plain of South Carolina occurs currently as a sporadic distribution of shallow ponds held within Carolina bays and other small, isolated basins. At seven bays on the U.S. Department of Energy's Savannah River Site on the Upper Coastal Plain of South Carolina, we investigated Holocene changes in bay morphology, ecology, and prehistoric human activity. At Flamingo Bay, we employed archaeological survey and testing, shovel and auger testing, sediment analysis, and ground-penetrating radar to document stratigraphy and chronology of the sand rim on the eastern side of the bay. Artifact assemblage indicate changes in intensity of human use of the bay. Radiocarbon dates from a sediment core establish time scales for depositional processes at the center of the basin. Ground-penetrating radar data from the other bays indicate that the stratigraphy of all seven bays is broadly similar. We conclude that: (1) Significant modification of the bays, including rim development and basin infilling, occurred during the Holocene; (2) ponds on the early Holocene landscape were larger and more permanent than at present; (3) early Holocene climate, as indicated by both depositional processes and human activity, was not characterized by prolonged periods of extremely dry conditions; and (4) fluvial-centric models of terminal Pleistocene—early Holocene human adaptations require revision to include intensive use of isolated upland ponds. © 1996 John Wiley & Sons, Inc. 相似文献