New evidences of hydrothermal fluids circulation at the Devonian Kess Kess mounds,Hamar Laghdad (eastern Anti‐Atlas,Morocco)

New evidences based on a combination of field and laboratory investigations reinforce the hypotheses that the circulation of warm fluids has remarkably contributed to the origin and development of the Devonian Kess Kess mounds of the Hamar Laghdad Ridge (eastern Anti‐Atlas, Morocco). The limestones of the Hamar Laghdad Ridge were deposited above a structural high generated by calc‐alkaline volcanic activity that has probably fuelled the circulation of warm fluids throughout the overlying carbonate units. The geological and palaeontological attributes described throughout the succession of the Hamar Laghdad Ridge (from the Lochkovian to Frasnian intervals) are interpreted as the result of hydrothermal processes related to a volcanic system. In particular, these attributes seem consistent with a chemo‐physical environment fuelled by the circulation of warm and late magmatic fluids. These attributes include a very low oxygen stable isotope signature (δ¹⁸O ~ −10‰) for carbonates. Evidences for a late magmatic fluid circulation consist of volcanic glass and pyroclasts replacement with hydrothermal minerals such as quartz, anatase and clinochlore. Fluids circulating through veins and pores into sediments, and venting to the seafloor, probably induced the formation of cavities where monospecific trilobite communities were detected. The partially silicified trilobite remains are associated with traces of goethite. This iron‐bearing oxide mineral is also present in the upper part of the Hamar Laghdad Ridge. All these attributes are here interpreted as possible evidences for a low‐temperature hydrothermal venting system active during the Lochkovian–Frasnian time span. This study combines an updated revision with new petrographic, geological and geochemical results aimed at providing an overall framework on the origin and early diagenesis of the Devonian succession of Hamar Laghdad. Copyright © 2014 John Wiley & Sons, Ltd.     

Uncertainty in Carbon Capture and Storage (CCS) deployment projections: a cross-model comparison exercise

Carbon Capture and Storage (CCS) can be a valuable CO₂ mitigation option, but what role CCS will play in the future is uncertain. In this paper we analyze the results of different integrated assessment models (IAMs) taking part in the 27th round of the Energy Modeling Forum (EMF) with respect to the role of CCS in long term mitigation scenarios. Specifically we look into the use of CCS as a function of time, mitigation targets, availability of renewables and its use with different fuels. Furthermore, we explore the possibility to relate model results to general and CCS specific model assumptions. The results show a wide range of cumulative capture in the 2010–2100 period (600–3050 GtCO₂), but the fact that no model projects less than 600 GtCO₂ indicates that CCS is considered to be important by all these models. Interestingly, CCS storage rates are often projected to be still increasing in the second half of this century. Depending on the scenario, at least six out of eight, up to all models show higher storage rates in 2100 than in 2050. CCS shares in cumulative primary energy use are in most models increasing with the stringency of the target or under conservative availability of renewables. The strong variations of CCS deployment projection rates could not be related to the reported differences in the assumptions of the models by means of a cross-model comparison in this sample.     

The role of negative CO2 emissions for reaching 2 °C—insights from integrated assessment modelling

Limiting climate change to 2 °C with a high probability requires reducing cumulative emissions to about 1600 GtCO₂ over the 2000–2100 period. This requires unprecedented rates of decarbonization even in the short-run. The availability of the option of net negative emissions, such as bio-energy with carbon capture and storage (BECCS) or reforestation/afforestation, allows to delay some of these emission reductions. In the paper, we assess the demand and potential for negative emissions in particular from BECCS. Both stylized calculations and model runs show that without the possibility of negative emissions, pathways meeting the 2 °C target with high probability need almost immediate emission reductions or simply become infeasible. The potential for negative emissions is uncertain. We show that negative emissions from BECCS are probably limited to around 0 to 10 GtCO₂/year in 2050 and 0 to 20 GtCO₂/year in 2100. Estimates on the potential of afforestation options are in the order of 0–4 GtCO₂/year. Given the importance and the uncertainty concerning BECCS, we stress the importance of near-term assessments of its availability as today’s decisions has important consequences for climate change mitigation in the long run.     

Rapid bottom-water circulation changes during the last glacial cycle in the coastal low-latitude NE Atlantic

Previous paleoceanographic studies along the NW African margin focused on the dynamics of surface and intermediate waters, whereas little attention has been devoted to deep-water masses. Currently, these deep waters consist mainly of North Atlantic Deep Waters as part of the Atlantic Meridional Overturning Circulation (AMOC). However, this configuration was altered during periods of AMOC collapse. We present a high-resolution reconstruction of bottom-water ventilation and current evolution off Mauritania from the last glacial maximum into the early Holocene. Applying redox proxies (Mo, U and Mn) measured on sediments from off Mauritania, we describe changes in deep-water oxygenation and we infer the evolution of deep-water conditions during millennial-scale climate/oceanographic events in the area. The second half of Heinrich Event 1 and the Younger Dryas were recognized as periods of reduced ventilation, coinciding with events of AMOC reduction. We propose that these weakening circulation events induced deficient deep-water oxygenation in the Mauritanian upwelling region, which together with increased productivity promoted reducing conditions and enhanced organic-matter preservation. This is the first time the effect of AMOC collapse in the area is described at high resolution, broadening the knowledge on basin-wide oceanographic changes associated with rapid climate variability during the last deglaciation.     

Carolina Bay geoarchaeology and Holocene landscape evolution on the Upper Coastal Plain of South Carolina

Surface water on the mainly dry, upland interfluves of the Upper Coastal Plain of South Carolina occurs currently as a sporadic distribution of shallow ponds held within Carolina bays and other small, isolated basins. At seven bays on the U.S. Department of Energy's Savannah River Site on the Upper Coastal Plain of South Carolina, we investigated Holocene changes in bay morphology, ecology, and prehistoric human activity. At Flamingo Bay, we employed archaeological survey and testing, shovel and auger testing, sediment analysis, and ground-penetrating radar to document stratigraphy and chronology of the sand rim on the eastern side of the bay. Artifact assemblage indicate changes in intensity of human use of the bay. Radiocarbon dates from a sediment core establish time scales for depositional processes at the center of the basin. Ground-penetrating radar data from the other bays indicate that the stratigraphy of all seven bays is broadly similar. We conclude that: (1) Significant modification of the bays, including rim development and basin infilling, occurred during the Holocene; (2) ponds on the early Holocene landscape were larger and more permanent than at present; (3) early Holocene climate, as indicated by both depositional processes and human activity, was not characterized by prolonged periods of extremely dry conditions; and (4) fluvial-centric models of terminal Pleistocene—early Holocene human adaptations require revision to include intensive use of isolated upland ponds. © 1996 John Wiley & Sons, Inc.