绿柱石的辐照赋色与效应

利用电子加速器为辐照源，对四川，新疆等产的无色绿柱石进行了辐照改色处理。在改色实验中，对辐照源的输出功率，电子能量，扫描面积，扫描速度，辐照剂量等参数，及辐照后样品的辐照效应，环境适应性，时效考验等特性进行了较系统的实验研究，并拟定出一套适合不同成因的无色绿柱石辐照改色的优选方案，对绿柱石的辐照机制和应效进行了探讨。     

Valency Study of Vanadium in Stone Coal Ash of Jiangxi Province

Vanadium-bearing stone coal is a new vanadium resource;recovery ofV_2O_5 from the coal has been investigated.It has been found that a satisfactoryextraction of V_2O_5 depends on both the oxidation of V and its reaction with so-dium salt.V in the coal ash of Yushan mainly exists in two oxidation states:98％V(Ⅲ)and2％V(Ⅳ).The distribution of valency of V shows that organicmatter determines V valency at low temperatures,at about470℃,V(Ⅲ)iscompletely oxidized to V(Ⅳ);above500℃,the temperature is the most impor-tant factor for the oxidation of V .At higher temperatures no more V is oxidizedto V(Ⅴ);an equilibrium is established after92％of V is oxidized to V(Ⅴ).The roles of NaCl in the recovery of V_2O_5 from the coal ash were discussed.The best conditions for roasting are temperature750-800℃for1 h.underthe oxidation-chlorination atmosphere.When the ore:NaCl=100:10 by weight,η_roast reaches85.5％.According to the results,a flowsheet for V_2O_5 extrac-tion from coal ash has been proposed.     

Spatial Database of Geological Survey Extent in 20th Century in China

During the whole 20th century in China, especially the latest 50 years, we have gotten much geological information about geological mapping, geophysics, geochemistry, mineral exploration,remote sensing, environmental geology, hydrogeology, engineering geology and oceanic geology etc. by our geologists and explorers. All the information has been accmnulated and can be used as a dcision-making foundation for the future plan of geological survey. The spatial database of geological survey ex-tents has been established by using computer technology. The database contained all kinds of exploration sections and collected about 160 000 records in this database. This paper introduces the data construc-tion ,contents and applying systemof this database, and trys to let people know what kinds of geological survey were finished, when the exploration were carried out, and how and where you can get this infor-mation.     

深层地热水开采与地面沉降的关系研究

本文根据天津塘沽区深层地沉观测标观测到的地面沉降数据,分析了深层地下热水开采对地面沉降的影响比例.在分析地热水开采引起地面沉降机理的基础上,通过统计回归方法建立了深层孔隙型地热水开采量与地面沉降量的相关模型;提出了进行地热尾水回灌和建立深层沉降监测网以加强综合研究的防治对策.     

黄骅坳陷地热资源研究

黄骅坳陷在勘探石油过程中发现了丰富的地下热水。根据实际资料对黄烨坳陷大港探区的地热资源进行了初步评价,提出了黄骅场陷储热系统和热异常区的分布规律,通过水化学分析,指出坳陷补给条件差,可实行人工回灌,增加地下热水资源。     

Elemental characteristics and paleoenvironment reconstruction: a case study of the Triassic lacustrine Zhangjiatan oil shale,southern Ordos Basin,China

Using trace elements to reconstruct paleoenvironment is a current hot topic in geochemistry. Through analytical tests of oil yield, ash yield, calorific value, total sulfur, major elements, trace elements, and X-ray diffraction, the quality, mineral content, occurrence mode of elements, and paleoenvironment of the Zhangjiatan oil shale of the Triassic Yanchang Formation in the southern Ordos Basin were studied. The analyses revealed relatively high oil yield (average 6.63%) and medium quality. The mineral content in the oil shale was mainly clay minerals, quartz, feldspar, and pyrite; an illite–smectite mixed layer comprised the major proportion of clay minerals. Compared with marine oil shale in China, the Zhangjiatan oil shale had higher contents of quartz, feldspar, and clay minerals, and lower calcite content. Silica was mainly in quartz and Fe was associated with organic matter, which is different from marine oil shale. The form of calcium varied. Cluster analyses indicated that Fe, Cu, U, V, Zn, As, Cs, Cd, Mo, Ga, Pb, Co, Ni, Cr, Sc, P, and Mn are associated with organic matter while Ca, Na, Sr, Ba, Si, Zr, K, Al, B, Mg, and Ti are mostly terrigenous. Sr/Cu, Ba/Al, V/(V + Ni), U/Th, AU, and δU of oil shale samples suggest the paleoclimate was warm and humid, paleoproductivity of the lake was relatively high during deposition of the shale—which mainly occurred in fresh water—and the paleo-redox condition was dominated by reducing conditions. Fe/Ti ratios of the oil shale samples suggest clear hydrothermal influence in the eastern portion of the study area and less conspicuous hydrothermal influence in the western portion.     

利用催化动力学原理测定化探样中微量碘的含量

在HAc-NaAc形成的中性缓冲溶液体系中,利用碘的催化动力学原理,使N-N-四甲基-4-4-二氨基二苯甲烷与氯胺T的氧化反应,生成蓝色络合物来测定地探样中微量碘的含量。通过实验,最佳试剂加入量为8%的HAc溶液5mL,8%的Na2CO3溶液3mL,0.1%的N-N-四甲基-4-4-二氨基二苯甲烷溶液5mL所组成的溶液体系中,在加入0.1%的氯胺T1mL显色后,其测定结果准确度、精密度高,检出限低,测定化探样中微量碘时该方法可以推广应用。     

An estimation of internal soliton forces on a pile in the ocean

Internal soliton forces on oil-platform piles in the ocean are estimated with the Morison Formula. Different from sur- face wave forces, which change only in magnitude along a pile, internal soliton forces can be distributed over the entire pile in the water and they change not only in magnitude but also in direction with depth. Our calculations show that the maximum total force caused by a soliton with its associated current of 2.1 m s-1 is nearly equal to the maximum total force exerted by a surface wave with a wavelength of 300 m and a wave-height of 18 m. The total internal soliton force is large enough to affect the operations of marine oil platforms and other facilities. Therefore, the influence of internal solitons should not be neglected in the design of oil platforms.     

Nonlinear coupled analysis of a single point mooring system

Coupled effects on a single point mooring(SPM) system subjected to the combined action of wind,waves and current are studied in this paper. Due to the complicatedness of the sea state and the huge size of the vessel,physical experimental study is both time consuming and uneconomical,whereas the numerical study is cost-effective and DNV software provides powerful SESAM software in solving the issues. This paper focuses on the modeling process of the SPM system,catenary equilibrium calculation,static analysis of the vessel in three different scenarios,and dynamic response simulation of the SPM system under environmental excitations. The three scenarios in study are as follows:the SPM is under the combined function of(a) wind,waves and current,(b) wind and waves,(c) current and waves. They are so set that one can compare the contributions of different types of loads in both static and dynamic studies. Numerical study shows that wind and current are the two major factors contributing to the mooring line tension,and surge and sway are the two dominant motions of the moored vessel subjected to environmental excitations.