Growth patterns and implications of complex dendrites in calcite travertines from Lýsuhóll, Snæfellsnes, Iceland

Calcite dendrite crystals are important but poorly understood components of calcite travertine that forms around many hot springs. The Lýsuhóll hot-spring deposits, located in western Iceland, are formed primarily of siliceous sinters that were precipitated around numerous springs that are now inactive. Calcite travertine formed around the vent and on the discharge apron of one of the springs at the northern edge of the area. The travertine is formed largely of two types (I and II) of complex calcite dendrite crystals, up to 1 cm high, that grew through the gradual addition of trilete sub-crystals. The morphology of the dendrite crystals was controlled by flow direction and the competition for growth space with neighbouring crystals. Densely crowded dendrites with limited branching characterize the rimstone dams whereas widely spaced dendrites with open branching are found in the pools. Many dendrite bushes in the pools nucleated around plant stems. Growth of the dendrite crystals was seasonal and incremental. Calcite precipitation was driven by rapid CO₂ degassing of CO₂-rich spring waters during the spring and summer. During winter, when snow covered the ground and temperatures were low, opal-A precipitated on the exposed surfaces of the dendrites. Segmentation of dendrite branches by discontinuities coated with opal-A and overgrowth development around sub-crystals resulted from this seasonal growth cycle. The calcite dendrite crystals in the Lýsuhóll travertine differ in morphology from those at other hot springs, such as those at Lake Bogoria, Kenya, and Waikite in New Zealand. Comparison with the calcite dendrite crystals found at those sites shows that dendrite morphology is site-specific and probably controlled by carbonate saturation levels that, in turn, are controlled by the rate of CO₂ degassing and location in the spring outflow system.     

Sheetflow fluvial processes in a rapidly subsiding basin, Altiplano plateau, Bolivia

Although facies models of braided, meandering and anastomosing rivers have provided the cornerstones of fluvial sedimentology for several decades, the depositional processes and external controls on sheetflow fluvial systems remain poorly understood. Sheetflow fluvial systems represent a volumetrically significant part of the non‐marine sedimentary record and documented here are the lithofacies, depositional processes and possible roles of rapid subsidence and arid climate in generating a sheetflow‐dominated fluvial system in the Cenozoic hinterland of the central Andes. A 6500 m thick succession comprising the Late Eocene–Oligocene Potoco Formation is exposed continuously for >100 km along the eastern limb of the Corque syncline in the high Altiplano plateau of Bolivia. Fluvial sandstone and mudstone units were deposited over an extensive region (>10 000 km²) with remarkably few incised channels or stacked‐channel complexes. The Potoco succession provides an exceptional example of rapid production of accommodation sustained over a prolonged period of time in a non‐marine setting (>0·45 mm year⁻¹ for 14 Myr). The lower ≈4000 m of the succession coarsens upward and consists of fine‐grained to medium‐grained sandstone, mudstone and gypsum deposits with palaeocurrent indicators demonstrating eastward transport. The upper 2500 m also coarsens upward, but contains mostly fine‐grained to medium‐grained sandstone that exhibits westward palaeoflow. Three facies associations were identified from the Potoco Formation and are interpreted to represent different depositional environments in a sheetflow‐dominated system. (i) Playa lake deposits confined to the lower 750 m are composed of interbedded gypsum, gypsiferous mudstone and sandstone. (ii) Floodplain deposits occur throughout the succession and include laterally extensive (>200 m) laminated to massive mudstone and horizontally stratified and ripple cross‐stratified sandstone. Pedogenic alteration and root casts are common. (iii) Poorly confined channel and unconfined sheet sandstone deposits include laterally continuous beds (50 to >200 m) that are defined primarily by horizontally stratified and ripple cross‐stratified sandstone encased in mudstone‐rich floodplain deposits. The ubiquitous thin‐sheet geometry and spatial distribution of individual facies within channel sandstone and floodplain deposits suggest that confined to unconfined, episodic (flash) flood events were the primary mode of deposition. The laterally extensive deposition and possible distributary nature of this sheetflow‐dominated system are attributed to fluvial fan conditions in an arid to semi‐arid, possibly seasonal, environment. High rates of sediment accumulation and tectonic subsidence during early Andean orogenesis may have favoured the development and long‐term maintenance of a sheetflow system rather than a braided, meandering or anastomosing fluvial style. It is suggested here that rapidly produced accommodation space and a relatively arid, seasonal climate are critical conditions promoting the generation of sheetflow‐dominated fluvial systems.     

Regional Variations in the Mineralogy of Metasomatic Assemblages in Mantle Xenoliths from the West Eifel Volcanic Field, Germany

Xenoliths record two distinct events in the mantle below theQuarternary West Eifel Volcanic Field, Germany. The first, duringthe Hercynian Orogeny, led to widespread formation of secondary,Ti-poor amphibole, clinopyroxene and phlogopite. The signatureof the second event, related to Quaternary volcanism, variesacross the field. At Dreiser Weiher and Meerfelder Maar, thisevent is characterized by amphibole–phlogopite–clinopyroxeneveins, hosted in lherzolite and harzburgite xenoliths broughtto the surface by sodic olivine nephelinite–basanite suitelavas. These veins formed from crystallization of sodic magmathat flowed along fractures in the mantle. At Rockeskyller Kopf,Gees and Baarley, the Quaternary event is characterized by wehrlitexenoliths, many of which have phlogopite–clinopyroxeneveins, that were transported by potassic foid suite lavas. Wehrliteformed by reaction of lherzolite–harzburgite, with a largevolume of potassic magma that flowed along grain boundariesrather than in fractures. During reaction, orthopyroxene wasconsumed and secondary clinopyroxene, olivine and phlogopiteprecipitated. Veins formed in wehrlites only during periodicover-pressure events. The composition of the magmas parentalto the veins is similar to the lavas that carried the xenolithsto surface, indicating that the source of foid and olivine nephelinite–basanitesuite magma is domainal, as was the flow regime and magma flux. KEY WORDS: Eifel; mantle xenoliths; metasomatism; trace elements     

Subtropical to temperate facies from a transition zone, mixed carbonate–siliciclastic system, Palaeogene, North Carolina, USA

Palaeogene passive margin sediments on the US mid‐Atlantic coastal plain provide valuable insight into facies interaction and distribution on mixed carbonate–siliciclastic shelves. This study utilizes well cuttings, outcrop, core, and seismic data to document temporal and spatial variations in admixed bryozoan‐rich skeletal carbonates and sandy siliciclastic units that were deposited on a humid passive margin located in the vicinity of a major marine transition zone. This zone was situated between north‐flowing, warm waters of the ancestral Gulf Stream (carbonate dominated settings) and south‐flowing, cold waters of the ancestral Labrador Current (siliciclastic dominated settings). Some degree of mixing of carbonates and siliciclastics occurs in all facies; however, siliciclastic‐prone sediments predominate in nearshore settings, while carbonate‐prone sediments are more common in more open marine settings of the inner shelf break and deep shelf. A distinctive dual‐break shelf depositional profile originated following a major Late Cretaceous to Palaeocene transgression that drowned the earlier shallow platform. This profile was characterized by prominent mid‐shelf break dividing the shallow shelf from the deep shelf and a major continental shelf/slope break. Incomplete filling of available accommodation space during successive buildup of the shallow shelf preserved the topographic break on this passive margin. Storm wave base also contributed to the preservation of the dual‐break shelf geometry by beveling shallow shelf sediments and transporting them onto and seaward of the mid‐shelf break. Sediment fines in deep shelf facies were produced in place, transported downdip from the shallow shelf by storm ebb currents and boundary currents, and reworked from adjacent areas of the deep shelf by strike‐parallel boundary currents. Regional climate and boundary currents controlled whether carbonate or siliciclastic material was deposited on the shelf, with warmer waters and more humid climates favouring carbonate deposition and cooler, more arid conditions favouring glaucony and siliciclastic dominated deposition. Continuous wave and current sweeping of the shallow shelf favoured deposition of mud‐lean facies across much of the shallow shelf. Skeletal components in much of the carbonate‐rich strata formed in warm, nutrient‐rich subtropical waters, as indicated by widespread occurrences of larger benthic foraminifera and molluscan assemblages. These indicators of warm water deposition within the bryozoan‐mollusk‐rich carbonate assemblage on this shelf provide an example of a warm water bryomol assemblage; such facies generally are associated with cooler water depositional settings.     

Cenozoic temperate and sub‐tropical carbonate sedimentation on an oceanic volcano – Chatham Islands,New Zealand

The Chatham Islands, at the eastern end of the Chatham Rise in the South‐west Pacific, are the emergent part of a Late Cretaceous to Cenozoic stratovolcano complex that is variably covered with limestones and fossiliferous tuffs. Most of these deposits accumulated in relatively shallow, high‐energy, tide‐influenced palaeoenvironments with deposition punctuated by periods of deeper‐water pelagic accumulation. Carbonate components in these neritic deposits are biogenic and dominated by molluscs and bryozoans – a heterozoan assemblage. The widespread Middle to Late Eocene Matanginui Limestone contains local photozoan elements such as large benthonic foraminifera (especially Asterocyclina) and calcareous green algae, reflecting the general Palaeogene sub‐tropical oceanographic setting. More localized Late Eocene to Oligocene deposits (Te One Limestone) as well as Pliocene carbonates (Onoua Limestone) are, however, wholly heterozoan and confirm a generally cooler‐water oceanographic setting, similar to today. Early sea floor diagenesis is interpreted to have removed most aragonite components (infaunal bivalves and epifaunal gastropods). Lack of aragonite resulted in the absence of intergranular calcite cementation during subaerial exposure, such that most carbonates are friable or unlithified. Cementation is, however, present at nodular hardground–firmground caps to metre‐scale cycles. Such cements are microcrystalline or micrometre‐thick isopachous circumgranular rinds with insufficient definitive attributes to pinpoint their environment of formation. The overall palaeoenvironment of deposition is interpreted as mesotrophic, resulting in part from upwelling about the Chatham volcanic massif and in part from nutrient element delivery from the adjacent volcanic terrane and coeval volcanism. Biotic diversity in tuffs is two to three times that in limestones, supporting the notion of especially high nutrient availability during periods of volcanism. These mid‐latitude deposits are strikingly different from their low‐latitude, tropical, photozoan counterparts in the volcanic island–coral reef ecosystem. Ground water seepage and fluvial runoff attenuate coral growth and promote microbial carbonate precipitation in these warm‐water settings. In contrast, nutrients from the same sources feed the system in the Chatham Islands cool‐water setting, promoting active heterozoan carbonate sedimentation.     

Basal Waitemata Group lithofacies: rapid subsidence in an early Miocene interarc basin, New Zealand

The abrupt transition from coastal and shallow shelf sediments to bathyal sediments provides a record of rapid subsidence and deepening of the early Miocene Waitemata basin. Basal shallow marine strata (Kawau Subgroup) accumulated upon a highly dissected surface that overlies deformed Mesozoic metagreywacke. The early Miocene coast was characterized by an embayed and cliffed shoreline with numerous sea stacks and islands. Kawau Subgroup lithofacies, which include pocket beach, shallow shelf and base-of-cliff talus deposits, reflect rapidly changing coastline configuration and water depths as the rugged bedrock surface was buried. The response to continued rapid subsidence and transgression in Waitemata basin was a decrease in the supply of coarse clastic sediment. Beach gravels were locally displaced to greater water depths by avalanching down steep bedrock slopes. The first bathyal turbidite facies, which abruptly overlie the shallow-water Kawau Subgroup, include locally derived sediment gravity flows commonly ponded by remnant bedrock submarine highs. When this local supply of sediment had been exhausted, coarse sediment starvation ensued and bathyal muds accumulated. With the resumption of sediment supply and gradual burial of submarine bedrock relief, submarine fans coalesced and increased in lateral extent. Subsidence of the Waitemata basin to bathyal depths is thought to have occurred in less than a million years. From the above hypothesis, a general model of sedimentation is proposed.     

Sediment suspension under waves and currents: time scales and vertical structure

Field measurements of the vertical structure of near-bed suspended sediment concentrations were obtained from arrays of fast response optical backscatter suspended solids sensors to examine the time-dependent response of sediment resuspension to waves and currents and the constraints imposed by bedforms. Data were recorded from both a nonbarred, marine shoreface and a barred lacustrine shoreface, under both shoaling and breaking waves (significant heights of 0·25–1·50m; peak periods of 3 and 8 s) and in water depths of 0·5–5·0 m. Sediment concentrations are positively correlated with increasing elevation above the bed, but lagged in time. The time lag varies directly with separation distance between measurement locations and inversely with the horizontal component of the near-bed oscillatory velocity. Both the presence of wave groups and the settling velocities of the sediment particules in suspension influence the temporal changes in concentration at a given elevation. Sediment concentrations appear to respond more slowly to the incident wind-wave forcing with distance away from the bed as a result of two factors: (1) the sequential increase in concentration induced by a succession of large waves in a group; and (ii) the relative increase in finer sediments with smaller settling velocities. Bedforms interact with the near-bed horizontal currents to impose a distinct constraint upon the timing of suspension events relative to the phase of the fluid motion, and, therefore, the vertical structure of the suspended sediment concentration at a range of time scales. The near-bed concentrations appear to be strongly dependent upon the vertical convection of sediment associated with the ejection from the wave boundary layer of separation vortices generated in the lee of ripple crests. Concentration gradients in the presence of vortex ripples are large, as are the correlation between concentrations measured at different elevations within the fluid.     

Middle and late Cenomanian oceanic anoxic events in shallow and deeper shelf environments of western Morocco

The response of shallow‐water sequences to oceanic anoxic event 2 and mid‐Cenomanian events 1a and 1b was investigated along the west African margin of Morocco north of Agadir (Azazoul) and correlated with the deep‐water sequence of the Tarfaya Basin (Mohammed Beach) based on biostratigraphy, mineralogy, phosphorus and stable isotopes. In the deeper Mohammed Beach section results show double peaks in δ¹³C_org for mid‐Cenomanian events 1a and 1b (Rotalipora reicheli biozone, lower CC10a biozone), the characteristic oceanic anoxic event 2 δ¹³C excursion (Rotalipora cushmani extinction, top of CC10a biozone) and laminated (anoxic) black shale. In the shallow environment north of Agadir, a fluctuating sea‐level associated with dysoxic, brackish and mesotrophic conditions prevailed during the middle to late Cenomanian, as indicated by oyster biostromes, nannofossils, planktonic and benthonic foraminiferal assemblages. Anoxic conditions characteristic of oceanic anoxic event 2 (for example, laminated black shales) did not reach into shallow‐water environments until the maximum transgression of the early Turonian. Climate conditions decoupled along the western margin of Morocco between mid‐Cenomanian event 1b and the Cenomanian–Turonian boundary, as also observed in eastern Tethys. North of Agadir alternating humid and dry seasonal conditions prevailed, whereas in the Tarfaya Basin the climate was dry and seasonal. This climatic decoupling can be attributed to variations in the Intertropical Convergence Zone and in the intensity of the north‐east trade winds in tropical areas.     

Stratigraphic evolution of an outcropping continental slope system, Tres Pasos Formation at Cerro Divisadero, Chile

Depositional slope systems along continental margins contain a record of sediment transfer from shallow‐water to deep‐water environments and represent an important area for natural resource exploration. However, well‐preserved outcrops of large‐scale depositional slopes with seismic‐scale exposures and tectonically intact stratigraphy are uncommon. Outcrop characterization of smaller‐scale depositional slope systems (i.e. < 700 m of undecompacted shelf‐to‐basin relief) has led to increased understanding of stratigraphic packaging of prograding slopes. Detailed stacking patterns of facies and sedimentary body architecture for larger‐scale slope systems, however, remain understudied. The Cretaceous Tres Pasos Formation of the Magallanes Basin, southern Chile, presents a unique opportunity to evaluate the stratigraphic evolution of such a slope system from an outcrop perspective. Inherited tectonic relief from a precursor oceanic basin phase created shelf‐to‐basin bathymetry comparable with continental margin systems (～1000 m). Sedimentological and architectural data from the Tres Pasos Formation at Cerro Divisadero reveal a record of continental margin‐scale depositional slope progradation and aggradation. Slope progradation is manifested as a vertical pattern exhibiting increasing amounts of sediment bypass upwards, which is interpreted as reflecting increasing gradient conditions. The well‐exposed, seismic‐scale outcrop is characterized by four 20 to 70 m thick sandstone‐rich successions, separated by mudstone‐rich intervals of comparable thickness (40 to 90 m). Sedimentary body geometry, facies distribution, internal bedding architecture, sandstone richness and degree of amalgamation were analysed in detail across a continuous 2·5 km long transect parallel to depositional dip. Deposition in the lower section (Units 1 and 2) was dominated by poorly channellized to unconfined sand‐laden flows and accumulation of mud‐rich mass transport deposits, which is interpreted as representing a base of slope to lower slope setting. Evidence for channellization and indicators of bypass of coarse‐grained turbidity currents are more common in the upper part of the > 600 m thick succession (Units 3 and 4), which is interpreted as reflecting increased gradient conditions as the system accreted basinward.     

Abiotic versus biotic controls on the development of the Fairmont Hot Springs carbonate deposit, British Columbia, Canada

The relict Fairmont Hot Springs deposit, formed largely of carbonates, covers an area of 0·5 km², and is up to 16 m thick. The triangle‐shaped discharge apron, which broadens down‐valley, is divided into a proximal part with beds dipping at <10° and a distal part with beds dipping at 10° to 15°. The deposit is formed of the: (1) Basal Macrophyte; (2) Lower Carbonate; (3) Middle Clastic; (4) Upper Carbonate; and (5) Upper Clastic Sequences. Two charcoal samples embedded in the Lower Carbonate Sequence yielded dates of 8690 ± 90 and 8270 ± 70 cal yr bp , indicating that much of the deposit formed post‐glacially during the Early to Mid‐Holocene. Deposit aggradation ceased in the Mid to Late Holocene when the Fairmont Creek valley was incised. The Lower and Upper Carbonate Sequences, which are the thickest sequences, are composed of nearly equal parts of travertine (abiotic) and tufa (biotic), with feather dendrite travertine, radiating dendrite travertine and stromatolite tufa dominating. Competition between calcite precipitation rates and biotic growth rates controlled the distribution of tufa and travertine across the discharge apron. Calcite and biotic growth rates were controlled largely by flow velocity across the apron which, in turn, was controlled by topography and regular fluctuations in spring water discharge volume. During times of high spring discharge, slow sheet flow over the proximal part of the apron promoted stromatolite growth, whereas fast, turbulent flow on the distal part of the apron induced rapid feather dendrite formation. During times of low spring discharge, quiescent, shallow evaporative pools, conducive to radiating dendrite formation, formed on the proximal part of the apron, whereas slow flow on the distal part promoted stromatolite growth. Facies with high calcite supersaturation experienced rapid abiotic dendrite growth that precluded most biotic growth.