Trace metals and hydrocarbons in sediments from the Southampton water region,with particular reference to the influence of oil refinery effluent

The concentrations of a number of trace metals (Co, Ni, Cu, Zn, Ag, Cd and Hg) have been determined in sediments from cores collected in the Southampton Water region. Measurements of total hydrocarbons were also made on several of the cores. Markedly elevated concentrations of copper, up to 362 μg/g dry wt, were found in sediments which were collected close to the discharge points of oil refinery outfalls and which also showed concentrations of total hydrocarbons considerably greater than the background levels for the estuary. The results of selective chemical extractions showed that much of the copper was present in the non-lattice fraction of the sediment. Although the concentrations of Co, Ni, Zn and Cd were significantly correlated with those of copper in the core showing the highest concentrations of this element, these metals were not enhanced in comparison with the levels found in several other parts of the estuary. Variations in concentrations of metals in sediments throughout the estuary were not correlated with differences in organic carbon content.     

Alboran Sea late cenozoic tectonic and stratigraphic evolution

Analysis of airgun seismic profiles from the Alboran Sea reveals a complex morphostructure with margins, basins, and structural highs. North of the Alboran Ridge, south-facing margins have a passive style of evolution, with thick progradational sequences of post-Messinian deposits, whereas north-facing margins are tectonized along structural highs with reduced sediment cover. Basins are extensional features developed since the Early Miocene by mechanisms of tectonic escape and pull-apart, under generalized northwest-southeast to north-south compression. Depositional sequences in this semi-land-locked sea were controlled by the local tectonism and influenced by global sea-level oscillations.     

Histopathological biomarkers in estuarine fish species for the assessment of biological effects of contaminants

The increasing emphasis on the assessment and monitoring of estuarine ecosystems has highlighted the need to deploy appropriate biological indices for these locations. Fish diseases and histopathology, with a broad range of causes, are increasingly being used as indicators of environmental stress since they provide a definite biological end-point of historical exposure. This study reports on the histopathological alterations observed in selected organs and tissues of three species of estuarine fish (Platichthys flesus, Pomatoschistus minutus and Zoarces viviparus), captured from four British estuaries (the Tyne, Tees, Mersey and Alde), differently impacted by contaminants, including PAHs. A biannual sampling regime was used to identify the important seasonal variations that occur in terms of the observed biological effects. Inflammatory lesions and hepatocellular fibrillar inclusions attained their highest prevalence in P. flesus captured from the Tyne, Tees and Mersey. The presence of pre-neoplastic and neoplastic toxicopathic lesions was highest in P. flesus captured from these sites, when compared to fish from the Aide reference site. In particular, the prevalence of hepatic foci of cellular alteration (up to 43.3%) and hepatocellular adenoma (up to 10%) were highest in P. flesus captured from the Mersey estuary. Intersex (ovotestis) was only recorded in male P.flesus captured from the Mersey estuary (up to 8.3%) and from male Z. viviparous captured from the Tyne estuary (25%). Pathologies associated with the gill and the kidney were also most prevalent in fish captured from the Tyne, Tees and Mersey estuaries. This study has successfully applied histopathology to an estuarine monitoring program, both for the recording of toxicopathic lesions in the liver and other organs, and for the detection of the endpoint of endocrine disruption, intersex. As such, it provides a powerful integrative tool for the assessment of biological effects of contaminants in these environments.     

Physical and anthropogenic effects on observed long-term nutrient changes in the Irish Sea

The trend in Irish Sea nutrient concentrations over the last four decades has been considered to reflect changes in anthropogenic loading. Comparison of a long-term database for the Menai Strait, North Wales, with an established historic data set for the Cypris station, Isle of Man, indicates that climate also has a significant influence on observations of nutrient concentrations. Data are presented detailing long-term shifts in nitrate, phosphate and silicate measurements since the 1960s at these two fixed sampling sites in the Irish Sea. Broad systematic changes observed in all three nutrients over the decades show a rise from the 1960s through to the 1980s, followed generally by an overall decline in the 1990s. Decadal-scale salinity changes occur in the opposite sense to nutrient changes. Anthropogenic inputs from freshwater cannot fully account for observed nutrient trends, neither is there evidence for shifts in nutrient concentrations in oceanic waters over the past four decades. Climatically forced movement in the geographical position of the freshwater/seawater mixing zone over a decadal time scale could, however, give rise to the observed shifts in nutrient concentration and salinity. This cannot alter nutrient concentration and salinity per se, but causes the measurements taken at fixed sampling sites to fluctuate inversely over this time scale. It is concluded that there is complex interplay between anthropogenic loading and climate affecting the distribution of nutrients in the Irish Sea.     

Dynamics and control of a towed underwater vehicle system, part I: model development

Autonomous vehicles are being developed to replace the conventional, manned surface vehicles that tow mine hunting towed platforms. While a wide body of work exists that describes numerical models of towed systems, they usually include relatively simple models of the towed bodies and neglect the dynamics of the towing vehicle. For systems in which the mass of the towing vehicle is comparable to that of the towed vehicle, it becomes important to consider the dynamics of both vehicles. In this work, we describe the development of a numerical model that accurately captures the dynamics of these new mine hunting systems. We use a lumped mass approximation for the towcable and couple this model to non-linear numerical models of an autonomous surface vehicle and an actively controlled towfish. Within the dynamics models of the two vehicles, we include non-linear controllers to allow accurate maneuvering of the towed system.     

Dynamics of climate extremes in northern Eurasia in the late 20th century

Changes in climatic parameters and in temperature and precipitation extremes in northern Eurasia in the late 20th century are analyzed. A spatial distribution of temperature and precipitation anomalies and of a set of indices of climate extremes is presented. Changes in climate extremes show a tendency toward a milder climate, mainly in winter. At the same time, the frost-free period has substantially decreased in the eastern, northern, and central parts of European Russia. In some regions during summer, there is an increase in the frequency of extreme events such as heavy rains, droughts, and sharp cooling. It is shown that the geographic pattern of present-day climate anomalies is linked to variations in the large-scale atmospheric circulation. The main mechanism of the current warming in northern Eurasia is a winter intensification of zonal flow linked to the increased frequency of positive anomalies of the North Atlantic Oscillation index.     

How are large western hemisphere warm pools formed?

During the boreal summer the Western Hemisphere warm pool (WHWP) stretches from the eastern North Pacific to the tropical North Atlantic and is a key feature of the climate of the Americas and Africa. In the summers following nine El Niño events during 1950–2000, there have been five instances of extraordinarily large warm pools averaging about twice the climatological annual size. These large warm pools have induced a strengthened divergent circulation aloft and have been associated with rainfall anomalies throughout the western hemisphere tropics and subtropics and with more frequent hurricanes. However, following four other El Niño events large warm pools did not develop, such that the mere existence of El Niño during the boreal winter does not provide the basis for predicting an anomalously large warm pool the following summer.In this paper, we find consistency with the hypothesis that large warm pools result from an anomalous divergent circulation forced by sea surface temperature (SST) anomalies in the Pacific, the so-called atmospheric bridge. We also find significant explanations for why large warm pools do not always develop. If the El Niño event ends early in the eastern Pacific, the Pacific warm anomaly lacks the persistence needed to force the atmospheric bridge and the Atlantic portion of the warm pool remains normal. If SST anomalies in the eastern Pacific do not last much beyond February of the following year, then the eastern North Pacific portion of the warm pool remains normal. The overall strength of the Pacific El Niño does not appear to be a critical factor. We also find that when conditions favor a developing atmospheric bridge and the winter atmosphere over the North Atlantic conforms to a negative North Atlantic Oscillation (NAO) pattern (as in 1957–58 and 1968–69), the forcing is reinforced and the warm pool is stronger. On the other hand, if a positive NAO pattern develops the warm pool may remain normal even if other circumstances favor the atmospheric bridge, as in 1991–92. Finally, we could find little evidence that interactions internal to the tropical Atlantic are likely to mitigate for or against the formation of the largest warm pools, although they may affect smaller warm pool fluctuations or the warm pool persistence.     

Surface circulation of the Levantine Basin: Comparison of model results with observations

The eastern Mediterranean (Levantine Basin) hydrography and circulation are investigated by comparing the results of a high-resolution primitive equation model with observations. After a 10-year integration, the model is able to reproduce the major water masses and the circulation patterns of the eastern Mediterranean. Comparisons with the POEM hydrographical observations show good agreement. The vertical distribution of the water masses matches that of the observations quite well in terms of monthly mean. The model surface circulation is in agreement with circulation schemes derived from recent observations. Some well-known mesoscale features of the upper thermocline circulation are also realistically reproduced. In agreement with satellite observations, the model shows that high-energy mesoscale eddies dominate the upper thermocline circulation in the southern and the central parts of the Levantine Basin. Most of the Atlantic Water follows the north African coast and forms a strong coastal jet near the Libyan coast rather than forming the Mid-Mediterranean Jet described by several authors. The sub-basin circulation shows a strong seasonal signal. A strong and stable current flows along the isobaths in winter, becoming weaker and with more meanders in summer. The mesoscale eddies throughout the whole basin are more energetic in summer than in winter.