Experimental study of the alteration process of labradorite in acid hydrothermal solutions

Labradorite was altered artificially by HC1 solution ranging from M = 1 to M = 0.003 at 245 and 230°C. The products of alteration were examined by X-ray diffraction, electron microscopy, electron diffraction, infrared spectroscopy and the electron microprobe and the solution was analyzed chemically.Amorphous silica only was formed in solutions with M_HCl = 1 and M_HCl = 0.3. In a solution with M_HCl = 0.2, amorphous silica was initially formed, later dissolved and replaced by kaolinite. A mixture of microcrystalline boehmite and amorphous aluminosilicate was formed, altering to kaolinite in solutions with M_HCl = 0.1 and 0.3. Small amounts of kaolinite were initially formed but the alteration soon stopped in solution with M_HCl = 0.003. Relationships between the alteration processes and pH of the solutions can be roughly explained by using solubility diagrams assuming the congruent dissolution of labradorite and precipitation of the products in partial equilibrium. However, these assumptions are not valid with strongly acid solutions.The rate of dissolution of labradorite is controlled not only by its surface area, but also by the diffusion of matter through the layer of alteration products.     

Re-Os geochronology of the Iimori Besshi-type massive sulfide deposit in the Sanbagawa metamorphic belt, Japan

Besshi-type Cu deposits are strata-bound volcanogenic massive sulfide deposits usually associated with mafic volcanic rocks or their metamorphic equivalents. Although there are numerous Besshi-type deposits in the Sanbagawa metamorphic belt, Japan, their tectonic settings and depositional environments remain controversial because of a lack of depositional age constraints. We report Re-Os data for the Iimori deposit, one of the largest Besshi-type deposits in western Kii Peninsula, in order to examine the robustness of the Re-Os isotope system for dating sulfide minerals in the high-P/T metamorphic belt and to elucidate the primary depositional environment of the Iimori sulfide ores. An 11-point Re-Os isochron plot yields an age of 156.8 ± 3.6 Ma. As this Re-Os isochron age is significantly older than the timing of the Sanbagawa peak metamorphism (110-120 or ∼90 Ma) and a well-defined isochron was obtained, the Re-Os age determined here is most likely the primary depositional age. Despite high-grade metamorphism at up to 520 ± 25 °C and 8-9.5 kbar, the Re-Os isotope system of the Iimori sulfides was not disturbed. Hence, we consider that the whole-rock Re-Os closure temperature for the Iimori sulfide ores was probably higher than 500 °C. As the accretion age of the Sanbagawa metamorphic belt is considered to be 120-130 or 65-90 Ma on the basis of radiolarian and radiometric ages, we estimated the time from the Iimori sulfide deposition on the paleo-seafloor to its accretion at the convergent plate boundary to be greater than 25 Myr. Consequently, the depositional environment of the Iimori sulfide ores was not in the marginal sea, but was truly pelagic.     

Tsunami vulnerability evaluation in the Mentawai islands based on the field survey of the 2010 tsunami

On October 25, 2010, a large earthquake occurred off the coast of the Mentawai islands in Indonesia, generating a tsunami that caused damage to the coastal area of North Pagai, South Pagai, and Sipora islands. Field surveys were conducted soon after the event by several international survey teams, including the authors’. These surveys clarified the tsunami height distribution, the damage that took place, and residents’ awareness of tsunamis in the affected islands. Heights of over 5 m were recorded on the coastal area of the Indian Ocean side of North and South Pagai islands and the south part of Sipora island. In some villages, it was difficult to evacuate immediately after the earthquake because of the lack of routes to higher ground or the presence of rivers. Residents in some villages had taken part in tsunami drills or education; however, not all villages shared awareness of tsunami threats. In the present paper, based on the results of these field surveys, the vulnerability of these islands with regards to future tsunami threats was analyzed. Three important aspects of this tsunami disaster, namely the geographic disadvantage of the islands, the resilience of buildings and other infrastructure, and people’s awareness of tsunamis, are discussed in detail, and corresponding tsunami mitigation strategies are explained.     

Preparation of a New Geological Survey of Japan Geochemical Reference Material: Coral JCp-1

A new geochemical reference material, coral Porites sp. JCp-1 has been prepared by the Geological Survey of Japan (GSJ). Provisional values for twenty one major, minor and trace elements are presented. The homogeneity tests showed that all elements studied are considered to be homogeneously distributed.     

Anomalous thermal expansion in spinel MgAl2O4

The accurate measurement of thermal expansion in spinel MgAl₂O₄ over a temperature range between 30° C and 900° C has revealed an anomalous behaviour indicating a possible presence of a second order phase transition at 660° C.     

Influence of flooding on groundwater flow in central Cambodia

Cambodia is affected by flooding from the Mekong, Tonle Sap and Bassac rivers every year, which harms human populations and damages property, as well as alters the water quality in aquifer systems. The objective of this paper is to highlight the effects of river flooding on groundwater flow using numerical simulation. A two-dimensional groundwater flow model coupled with a groundwater recharge model was applied to the research area in central Cambodia. River level variation was included in model processes, and flood areas and periods were assigned. The results showed that during flooding periods, floodwater from the three rivers played an important role in recharging groundwater. During the dry season, Tonle Sap River received groundwater supply from the northwest, and levels in the Bassac and Mekong River dropped to lower than the groundwater level. This study improves understanding of the surface water and groundwater flow system in the study area.     

Reaction-induced grain boundary cracking and anisotropic fluid flow during prograde devolatilization reactions within subduction zones

Devolatilization reactions during prograde metamorphism are a key control on the fluid distribution within subduction zones. Garnets in Mn-rich quartz schist within the Sanbagawa metamorphic belt of Japan are characterized by skeletal structures containing abundant quartz inclusions. Each quartz inclusion was angular-shaped, and showed random crystallographic orientations, suggesting that these quartz inclusions were trapped via grain boundary cracking during garnet growth. Such skeletal garnet within the quartz schist formed related to decarbonation reactions with a positive total volume change (?V _t > 0), whereas the euhedral garnet within the pelitic schists formed as a result of dehydration reaction with negative ?V _t values. Coupled hydrological–chemical–mechanical processes during metamorphic devolatilization reactions were investigated by a distinct element method (DEM) numerical simulation on a foliated rock that contained reactive minerals and non-reactive matrix minerals. Negative ?V _t reactions cause a decrease in fluid pressure and do not produce fractures within the matrix. In contrast, a fluid pressure increase by positive ?V _t reactions results in hydrofracturing of the matrix. This fracturing preferentially occurs along grain boundaries and causes episodic fluid pulses associated with the development of the fracture network. The precipitation of garnet within grain boundary fractures could explain the formation of the skeletal garnet. Our DEM model also suggests a strong influence of reaction-induced fracturing on anisotropic fluid flow, meaning that dominant fluid flow directions could easily change in response to changes in stress configuration and the magnitude of differential stress during prograde metamorphism within a subduction zone.     

The social and political complexities of learning in carbon capture and storage demonstration projects

Demonstration of a fully integrated power plant with carbon capture and storage (CCS) at scale has not yet been achieved, despite growing international political interest in the potential of the technology to contribute to climate change mitigation and calls from multiple constituents for more demonstration projects. Acknowledging the scale of learning that still must occur for the technology to advance towards deployment, multiple CCS demonstration projects of various scales are emerging globally. Current plans for learning and knowledge sharing associated with demonstration projects, however, seem to be limited and narrowly conceived, raising questions about whether the projects will deliver on the expectations raised. Through a comparison of the structure, framing and socio-political context of three very different CCS demonstration projects in different places and contexts, this paper explores the complexity of social learning associated with demonstration projects. Variety in expectations of the demonstration projects’ objectives, learning processes, information sharing mechanisms, public engagement initiatives, financing and collaborative partnerships are highlighted. The comparison shows that multiple factors including the process of building support for the project, the governance context and the framing of the project matter for the learning in demonstration projects. This analysis supports a broader conceptualization of learning than that currently found in CCS demonstration plans - a result with implications for both future research and practice.     

Viscosity of peridotite liquid up to 13 GPa: Implications for magma ocean viscosities

The viscosity of synthetic peridotite liquid has been investigated at high pressures using in-situ falling sphere viscometry by combining a multi-anvil technique with synchrotron radiation. We used a newly designed capsule containing a small recessed reservoir outside of the hot spot of the heater, in which a viscosity marker sphere is embedded in a forsterite + enstatite mixture having a higher solidus temperature than the peridotite. This experimental setup prevents spheres from falling before a stable temperature above the liquidus is established and thus avoids difficulties in evaluating viscosities from velocities of spheres falling through a partially molten sample.

Experiments have been performed between 2.8 and 13 GPa at temperatures ranging from 2043 to 2523 K. Measured viscosities range from 0.019 (± 0.004) to 0.13 (± 0.02) Pa s. At constant temperature, viscosity increases with increasing pressure up to  8.5 GPa but then decreases between  8.5 and 13 GPa. The change in the pressure dependence of viscosity is likely associated with structural changes of the liquid that occur upon compression. By combining our results with recently published 0.1 MPa peridotite liquid viscosities [D.B. Dingwell, C. Courtial, D. Giordano, A. Nichols, Viscosity of peridotite liquid, Earth Planet. Sci. Lett. 226 (2004) 127–138.], the experimental data can be described by a non-Arrhenian, empirical Vogel-Fulcher-Tamman equation, which has been modified by adding a term to account for the observed pressure dependence of viscosity. This equation reproduces measured viscosities to within 0.08 log₁₀-units on average. We use this model to calculate viscosities of a peridotitic magma ocean along a liquid adiabat to a depth of  400 km and discuss possible effects on viscosity at greater pressures and temperatures than experimentally investigated.