Simple determination of dimethylsulfide (DMS) and dimethylsulfoniopropionate (DMSP) using solid-phase microextraction and gas chromatography-mass spectrometry

Solid-phase microextraction (SPME) is a simple, sensitive and less destructive method for the determination of dimethylsulfide (DMS) in seawater. Combined with detection by gas chromatography-mass spectrometry (GC-MS), the method had sufficient sensitivity (minimum detectable concentration of DMS was 0.05 nM), and practical levels of reproducibility (relative standard deviation ≤7%) and linearity (r ² > 0.995) over a wide concentration range (0.5 to 910 nM). The protocol developed was applied to a Sagami Bay water sample to determine concentrations of DMS and DMSP, and in situ DMSP-lyase activity.     

Eddy Shedding from the Kuroshio Bend at Luzon Strait

TOPEX/POSEDIENT-ERS satellite altimeter data along with the mean state from the Parallel Ocean Climate Model result have been used to investigate the variation of Kuroshio intrusion and eddy shedding at Luzon Strait during 1992–2001. The Kuroshio penetrates into the South China Sea and forms a bend. The Kuroshio bend varies with time, periodically shedding anticyclonic eddies. Criteria of eddy shedding are identified: 1) When the shedding event occurs, there are usually two centers of high Sea Surface Height (SSH) together with negative geostrophic vorticity in the Kuroshio Bend (KB) area. 2) Between the two centers of high SSH there usually exists positive geostrophic vorticity. These criteria have been used to determine the eddy shedding times and locations. The most frequent eddy shedding intervals are 70, 80 and 90 days. In both the winter and summer monsoon period, the most frequent locations are 119.5°E and 120°E, which means that the seasonal variation of eddy shedding location is unclear.     

Jellyfish patch formation investigated by aerial photography and drifter experiment

Jellyfish patch formation is investigated by conducting a drifter experiment combined with aerial photography of a sustained patch of the moon jellyfish in Hokezu Bay, Japan. Jellyfish patches are aggregations of individuals that are caused by a combination of swimming (active influence) and advection by currents (passive influence). The drifter experiment involved the injection of 49 drifters around a distinct surface patch of jellyfish within an area of approximately 300 m × 300 m. The drifters’ motion, caused only by the passive influence, was recorded in a series of 38 aerial photographs taken over approximately 1 h. The ambient uniform current field larger than the patch scale was estimated from the movement of the centroid position of drifters, while the distribution of horizontal divergence and relative vorticity around the patch was estimated from the time-derivative in areas of triangles formed by the drifters. The centroid positions of both drifters and patches moved stably toward the bay head at different speeds. The difference vector between the patch and drifter centroids was directed to the sun, and was opposite to the ambient current. The distributions of vorticity and divergence around patches exhibited inhomogeneity within the patch scale, and the drifters in this nonuniform current field aggregated near the convergence area within 1 h. The results suggest that horizontal patch formation is predominantly influenced by passive factors at the surface of Hokezu Bay. Furthermore, the upward swimming against downwelling may make sustained patch in surface layer.     

Determination of the lithium and rubidium in sea water by double channel flame emission spectrophotometry

A precise and accurate technique for the determination of Li and Rb in sea water has been developed by using a double channel flame emission spectrophotometer. The advantage of this technique is that it is possible to correct the background emission by making use of the double channel system of the apparatus and to obtain constant intensity of emission even if there are large scale changes in the salinity of the sample. Sea water samples collected in the open sea and coastal areas of Japan were analyzed by this method. In one of the coastal areas, an extraordinarily high concentration of Li was found.     

Geodynamics of the deep sedimentary basin of the Caspian Sea region: paragenetic correlation of seismicity and mud volcanism

In this paper we analyze seismic regime and earthquake depth distribution and correlation of seismicity and mud volcanism in the Azerbaijan and the Caspian Sea region. For the present region we have calculated accurate source locations, seismic activity, earthquake repetition and released earthquake energy parameters. It is shown that the active tectonic processes in the region are concentrated within the thick sedimentary cover that we consider as a general source of contemporary stress and a main structural element responsible for the origin of regional earthquakes. The correlation of seismicity and mud volcanism is of paragenetic character.     

Spatial Patterns in Nutrient and In Vivo Fluorescence Distributions in the Marginal Ice Zone and the Seasonally Open Oceanic Zone in the Indian Sector of the Antarctic Ocean, in Austral Summer

Surface temperature, salinity, concentrations of silicate (Si) and nitrate + nitrite (N), and in vivo fluorescence (Fluor) were investigated in the marginal ice zone (MIZ) and the seasonally open oceanic zone (SOOZ) (32–40°E, 64–69°S) from February 23 to 28 1992. In the MIZ the mean Si and N were 67.8 ± 2.2 M and 32.5 ± 1.7 M, respectively. There was a trend that low N values coincided with high Fluor values. Observation conducted at one point (64°S, 38°E) revealed a diel variation pattern in Fluor. Applying this pattern of deviation from noon value, all Fluor data were normalized to value at local noon. In the MIZ a significant negative correlation was observed between the normalized Fluor and N but not Si. On the other hand, Si decreased continuously from south to north in the SOOZ and was negatively correlated with the normalized Fluor. Difference in Si concentration was about 30 M between the sea around 64°S and the MIZ, while the difference in N concentration was estimated as less than 10 M. If diatoms take up silicate and nitrogen at an approximate ratio of 1:1, additional nitrogenous nutrients other than nitrate and nitrite (e.g. ammonia, urea etc.) would be required. In this case, an f-ratio of lower than 33% is obtained. It is suggested that in the MIZ abundance of phytoplankton community dominated by non-diatom increases utilizing nitrate while in the SOOZ abundance of phytoplankton community dominated by diatoms increases consuming Si and regenerated nitrogen.     

A theory of semigeostrophic gravity waves and its application to the intrusion of a density current along a coast

Semigeostrophic gravity waves associated with a coastal boundary current, which has finite and uniform potential vorticity and is bounded away from the coastline by a density front on the ocean surface, are investigated. It is shown that the semigeostrophic coastal current has two waves which are named here the Semigeostrophic Coastal Wave (SCW) and the Semigeostrophic Frontal Wave (SFW). The SCW becomes an elementary Kelvin wave at some limit while the SFW is caused by the existence of the surface density front. The SCW appears mainly as variations in the upper layer depth at the coast and as alongshore velocity at the density front. On the other hand, the SFW appears mainly as variations in the width of the current. When the weak nonlinearity and ageostrophic effect are included, these semigeostrophic gravity waves satisfy the Kortweg- de Vries equation, which suggests that the local changes in the width and/or velocity of the semigeostrophic coastal current propagate as wave-like disturbances.     

Steady Response of a Ventilated Thermocline to Enhanced Ekman Pumping

The steady response of the ventilated thermocline to an increase in Ekman pumping is investigated, focusing on the effect of the mixed layer depth distribution on the subsurface density anomaly. We consider only the subtropical gyre, and the mixed layer is assumed to be deep in the northwest and shallow elsewhere with a narrow transition zone separating the deep and shallow mixed layer regions. At the intersection of this narrow transition zone and the outcrop line, low potential vorticity fluid is subducted into and ventilates the thermocline. In such a situation, an enhancement of the Ekman pumping confined to the northern subtropical gyre leads to pronounced subsurface cold anomalies in the southern subtropics, which is free of anomalous forcing. These density anomalies are much greater than those that occur when either the mixed layer depth is zonally uniform or the Ekman pumping is enhanced in the whole subtropical gyre. They are caused by anomalous changes in the trajectory of the low potential vorticity fluid in response to anomalous Sverdrup flow. This revised version was published online in July 2006 with corrections to the Cover Date.     

A shipborne wave-recording system with digital data processing

A shipborne wave-recording system which consists of a sonic wave gauge, accelerometers, gyroscopes and a computer system is described. Signals from the measuring apparatus are fed directly into a shipborne digital computer system at a prescribed sampling rate. The time series of wave heights and the acceleration are transformed into Fourier series using an algorithm of Fast Fourier Transform. Errors contained in the observed wave heights due to ship motion are corrected in the Fourier series by using the Fourier coefficients for the vertical acceleration. Power spectra and waveforms can also be calculated in a short time with this system from Fourier coefficients. Examples of the observational results obtained in the central part of the East China Sea in 1969 are presented.     

Preserved paleo-oceanic plateaus in accretionary complexes: Implications for the contributions of the Pacific superplume to global environmental change

We have reinvestigated the mid-Cretaceous plume pulse in relation to paleo-oceanic plateaus from accretionary prisms in the circum-Pacific region, and we have correlated the Pacific superplume activity with catastrophic environmental changes since the Neoproterozoic. The Paleo-oceanic plateaus are dated at 75–150 Ma; they were generated in the Pacific superplume region and are preserved in accretionary prisms. The volcanic edifice composed of both modern and paleo-oceanic plateaus is up to 10.7 × 10⁶ km² in area and 19.1 × 10⁷ km³ in volume. The degassing rate of CO₂ (0.82 − 1.1 × 10¹⁸ mol/m.y.) suggests a significant impact on Cretaceous global warming. The synchronous occurrence of paleo-oceanic plateaus in accretionary complexes indicates that Pacific superplume pulse activities roughly coincided at the Permo-Triassic boundary and the Vendian–Cambrian boundary interval. The CO₂ expelled by the Pacific superplume probably contributed to environmental catastrophes. The initiation of the Pacific superplume contributed to the snowball Earth event near the Vendian–Cambrian boundary; this was one of the most dramatic events in Earth's history. The scale of the Pacific superplume activity roughly corresponds to the scale of drastic environmental change.