Sodic granitoids and felsic gneisses associated with uranium-thorium mineralisation,Crockers Well,South Australia

Thorian brannerite mineralisation at the Crockers Well prospect occurs in sodic granitic rocks and associated sodic felsic gneisses. Field, mineralogical and chemical data support the derivation of the granitic rocks from the gneisses by anatexis during high grade metamorphism. The sodic granitic rocks are largely peraluminous, contain high Na₂O, low K₂O, CaO, Rb, Ba, Sr and ferromagnesian elements, and variable but commonly high U, Th, Nb, Ce, Y and F values. Many geochemical parameters are inherited from the compositionally similar sodic felsic gneisses, which are interpreted to be metamorphosed analcime-rich volcano-sedimentary rocks of original intermediate-felsic (alkaline) affinites. Significant U-Th mineralisation is restricted to fractures and local breccia bodies which contain a mineral assemblage rich in quartz, F-bearing phlogopite and minor fluorapatite, sodic plagioclase, niobian rutile, thorian brannerite, monazite, muscovite, chlorite, tourmaline and fluorite. Certain genetic analogies are proposed with porphyry Cu and stockwork Mo deposits, with mineral deposition having occurred in mechanically-induced fractures and breccia bodies developed during sub-solidus cooling of the sodic granitoids.     

Adaptive Delta Management for flood risk and resilience in Dordrecht,The Netherlands

Many countries across the world are experiencing strict austerity measures due to the economic crisis. As a consequence, public financing for stand-alone adaptation to flooding and drought will become scarcer in the (near) future, and this hampers the pursuit of resilience (i.e. the ability to remain functioning under a range of hazard magnitudes). In such times, key challenges for adaptation are further complicated by weaker investment dynamics and an increased tendency to ‘work in silos’. These are: to minimise regret with respect to maladaptation, which results from over- or under-investment in water hazard management; to exploit the opportunities for mainstreaming adaptation to flooding and drought into other investment agendas; and to deliver multiple benefits for society and the economy, such as increased biodiversity, liveability and competitiveness. These common challenges drive the best way in which to adapt to uncertain climate and socio-economic changes. In the Netherlands, the Delta Programme has developed and applied a structured and well-defined approach (called Adaptive Delta Management) for including and acting upon uncertainty around these future changes. This approach allows for greater transparency to decision-makers and stakeholders, because it adheres to four specific steps for strategy development. This paper presents the current understanding of Adaptive Delta Management and an illustration of the approach for the management of flood risk and resilience in Dordrecht. It examines the added value and limitations of Adaptive Delta Management concerning its application in the context of the Delta Programme, with a specific emphasis on the lessons learned from Dordrecht.     

Exposure age and erosional history of an upland planation surface in the US Atlantic Piedmont

The upland planation surface in the Piedmont of central New Jersey consists of summit flats, as much as 130 km² in area, that truncate bedding and structure in diabase, basalt, sandstone, mudstone and gneiss. These flats define a low‐relief regional surface that corresponds in elevation to residual hills in the adjacent Coastal Plain capped by a fluvial gravel of late Miocene age. A Pliocene fluvial sand is inset 50 m below the upland features. These associations suggest a late Miocene or early Pliocene age for the surface. To assess exposure age and erosional history, a 4·4 m core of clayey diabase saprolite on a 3 km² remnant of the surface was sampled at six depths for atmospherically produced cosmogenic ¹⁰Be. The measured inventory, assuming a deposition rate of 1·3 × 10⁶ atoms cm⁻² a⁻¹, yields a minimum exposure age of 227 000 years, or, assuming continuous surface erosion, a constant erosion rate of 10 m Ma⁻¹. Because the sample site lies about 60 m above the aggradation surface of the Pliocene fluvial deposit, and itself supports a pre‐Pliocene fluvial gravel lag, this erosion rate is too high. Rather, episodic surface erosion and runoff bypassing probably have produced an inventory deficit. Reasonable estimates of surface erosion (up to 10 m) and bypassing (up to 50 per cent of total precipitation) yield exposure ages of as much as 6·4 Ma. These results indicate that (1) the surface is probably of pre‐Pleistocene age and has been modified by Pleistocene erosion, and (2) exposure ages based on ¹⁰Be inventories are highly sensitive to surface erosion and runoff bypassing. Copyright © 2000 John Wiley & Sons, Ltd.     

Exploring landscape and geologic controls on spatial patterning of streambank groundwater discharge in a mixed land use watershed

Preferential groundwater discharge features along stream corridors are ecologically important at local and stream network scales, yet we lack quantification of the multiscale controls on the spatial patterning of groundwater discharge. Here we identify physical attributes that best explain variation in the presence and lateral extent of preferential groundwater discharges along two 5th order streams, the Housatonic and Farmington Rivers, and 32 1st to 4th order reaches across the Farmington River network. We mapped locations of preferential groundwater discharge exposed along streambanks using handheld thermal infrared cameras paired with high-resolution topographic and land use land cover datasets, surficial soil characteristic maps, and depth-to-bedrock geophysical measurements. The unconfined Housatonic River, MA, USA (12 km) had fewer discharge locations and less lateral extent (41 discharge locations with 38 m of active discharge/km of river) compared to the partially confined Farmington River, CT, USA (26 km; 169 discharge locations with 129 m of active discharge/km of river). Using a moving window analysis, we found along both rivers that discharge was more likely to occur where bank slopes were steeper, floodplain extent was narrower, and degree of confinement was higher. Along the Farmington River, groundwater discharge was more likely to occur where saturated hydraulic conductivity was higher and depth-to-bedrock was shallower. Among the 32 stream reaches surveyed (33.2 km of total stream length) within the Farmington River watershed, preferential discharge was observed in all but two stream reaches, varied from 0 to 25% of lateral extent along stream banks (mean = 6%), and was more likely to occur where stream reach slopes were steep, saturated hydraulic conductivity was high, and watershed urbanization was low. Our results show that, though both surface (e.g., topographic, land use land cover) and subsurface (e.g., soil characteristics, bedrock depth) factors control the prevalence of streambank preferential groundwater discharge, the dominant controls vary across valley settings and stream sizes.     

Oyster (<Emphasis Type="Italic">Crassostrea virginica</Emphasis>) Aquaculture Shifts Sediment Nitrogen Processes toward Mineralization over Denitrification

Filter-feeding bivalves, like oysters, couple pelagic primary production with benthic microbial processes by consuming plankton from the water column and depositing unassimilated material on sediment. Conceptual models suggest that at low to moderate oyster densities, this deposition can stimulate benthic denitrification by providing denitrifying bacteria with organic carbon and nitrogen (N). While enhanced denitrification has been found at oyster reefs, data from oyster aquaculture are limited and equivocal. This study measured seasonal rates of denitrification, as well as dissimilatory nitrate reduction to ammonium (DNRA), and dissolved inorganic N fluxes at a rack and bag eastern oyster (Crassostrea virginica) aquaculture farm. Consistent with models, denitrification was enhanced within the farm, with an average annual increase of 350% compared to a reference site. However, absolute denitrification rates were low relative to other coastal systems, reaching a maximum of 19.2 μmol m^?2 h^?1. Denitrification appeared to be nitrate (NO₃ ^?) limited, likely due to inhibited nitrification caused by sediment anoxia. Denitrification may also have been limited by competition for NO₃ ^? with DNRA, which accounted for an average of 76% of NO₃ ^? reduction. Consequently, direct release of ammonium (NH₄ ⁺) from mineralization to the water column was the most significant benthic N pathway, with seasonal rates exceeding 900 μmol m^?2 h^?1 within the farm. The enhanced N processes were spatially limited however, with significantly higher rates directly under oysters, compared to in between oyster racks. For commercial aquaculture farms like this, with moderate oyster densities (100–200 oysters m^?2), denitrification may be enhanced, but nonetheless limited by biodeposition-induced sediment anoxia. The resulting shift in the sediment N balance toward processes that regenerate reactive N to the water column rather than remove N is an important consideration for water quality.     

Trickle or treat: The dynamics of nutrient export from polar glaciers

Cold‐based polar glacier watersheds contain well‐defined supraglacial, ice‐marginal, and proglacial elements that differ in their degree of hydrologic connectivity, sources of water (e.g., snow, ice, and/or sediment pore water), meltwater residence times, allochthonous and autochthonous nutrient, and sediment loads. We investigated 11 distinct hydrological units along the supraglacial, ice marginal, and proglacial flow paths that drain Joyce Glacier in the McMurdo Dry Valleys of Antarctica. We found that these units play unique and important roles as sources and/or sinks for dissolved inorganic nitrogen and dissolved inorganic phosphorus and for specific fractions of dissolved organic matter (DOM) as waters are routed from the glacier into nutrient‐poor downstream ecosystems. Changes in nutrient export from the glacial system as a whole were observed as the routing and residence times of meltwater changed throughout the melt season. The concentrations of major ions in the proglacial stream were inversely proportional to discharge, such that there was a relatively constant “trickle” of these solutes into downstream ecosystems. In contrast, NO₃^? concentrations generally increased with discharge, resulting in delivery of episodic pulses of dissolved inorganic nitrogen‐rich water (“treats”) into those same ecosystems during high discharge events. DOM concentrations or fluorescence did not correlate with discharge rate, but high variability in DOM concentrations or fluorescence suggests that DOM may be exported downstream as episodic treats, but with spatial and/or temporal patterns that remain poorly understood. The strong, nutrient‐specific responses to changes in hydrology suggest that polar glacier drainage systems may export meltwater with nutrient compositions that vary within and between melt seasons and watersheds. Because nutrient dynamics identified in this study differ between glacier watersheds with broadly similar hydrology, climate, and geology, we emphasize the need to develop conceptual models of nutrient export that thoroughly integrate the biogeochemical and hydrological processes that control the sources, fate, and export of nutrients from each system.     

Mineralogy and origin of rhizoliths on the margins of saline,alkaline Lake Bogoria,Kenya Rift Valley

A wide range of rhizoliths occurs around the margins of Lake Bogoria, Kenya. These include root casts, moulds, tubules, rhizocretions, and permineralised root systems. These rhizoliths are variably composed of opaline silica, calcite, zeolites (mainly analcime), fluorite, and possibly fluorapatite, either alone or in combinations. Some rhizoliths are infilled moulds with detrital silicate grains. Most rhizoliths are in situ, showing both vertical and horizontal orientations. Reworked rhizoliths have been concentrated locally to form dense rhizolites.Hot-spring fluids, concentrated by evapotranspiration and capillary evaporation, have provided most of the silica for the permineralisation of the plant tissues. Precipitation involved the growth of silica nanospheres and microspheres that coalesced into homogeneous masses. Calcite rhizoliths formed following evaporative concentration, evapotranspiration, and (or) CO₂ degassing of Ca-bearing runoff water that infiltrated the sediment, or by mixing of runoff with saline, alkaline groundwater. Fluorite precipitated in areas where mixing of hot-spring and meteoric waters occurred, or possibly where hot-spring fluids came into contact with pre-existing calcite. Zeolitic rhizoliths formed during a prolonged period of aridity, when capillary rise and evaporative pumping brought saline, alkaline waters into contact with detrital silicate minerals around roots.