Geochemical processes controlling arsenic mobility in groundwater: A case study of arsenic mobilization and natural attenuation

The behavior of As in the subsurface environment was examined along a transect of groundwater monitoring wells at a Superfund site, where enhanced reductive dechlorination (ERD) is being used for the remediation of groundwater contaminated with chlorinated solvents. The transect was installed parallel to the groundwater flow direction through the treatment area. The ERD technology involves the injection of organic C (OC) to stimulate in situ microbial dechlorination processes. A secondary effect of the ERD treatment at this site, however, is the mobilization of As, as well as Fe and Mn. The concentrations of these elements are low in groundwater collected upgradient of the ERD treatment area, indicating that, in the absence of the injected OC, the As that occurs naturally in the sediment is relatively immobile. Batch experiments conducted using sediments from the site inoculated with an Fe(III)- and As(V)-reducing bacterium and amended with lactate resulted in mobilization of As, Fe and Mn, suggesting that As mobilization in the field is due to microbial processes.     

Factors influencing the stability of smectite sealants

Smectite is a mineral, but a mineral with distinct chemical properties. Structural changes in minerals may require millions of years of aging to complete, but a chemical reaction may be completed in only 4 to 5 min.

Some of the problems of smectite seals are described in this paper, together with methods of avoiding these hazards.     

The Atacama Cosmology Telescope project: A progress report

The Atacama Cosmology Telescope is a project to map the microwave background radiation at arcminute angular resolution and high sensitivity in three frequency bands over substantial sky areas. Cosmological signals driving such an experiment are reviewed, and current progress in hardware construction is summarized. Complementary astronomical observations in other wavebands are also discussed.     

The Fayette County,Texas, meteorites

Abstract— We report the first petrologic examination of all stone meteorites of Fayette County, Texas. The 10 stones represent four or five different fall events. The three recovered Bluff stones represent two falls. Bluff (a), which includes the 145.5-kg Bluff #1 stone, is classified as L5(S4), whereas Bluff (b) is classified as L4(S3) and is represented by a single stone. The studied Cedar stones are classified as H4(S3), and all four Cedar stones appear to define a strewnfield. Round Top (a), classified as L5(S3) and represented by two stones, is unrelated to either Bluff or Cedar. Round Top (b) [H4(S3); 1 stone], whose exact provenance is unknown, might be a transported fragment of the Cedar shower.     

Equilibrium solutions of the restricted problem of 2+2 bodies

Fourteen equilibrium solutions of the restricted problem of 2+2 bodies are shown to exist. Six of these solutions are located about the collinear Lagrangian points of the classical restricted problem of three bodies. Eight solutions are found in the neighborhood of the triangular Lagrangian points. Linear stability analysis reveals that all of the equilibrium solutions are unstable with the exception of four solutions; two in the vicinity of each of the triangular Lagrangian points. These four solutions are found to be stable provided the mass parameter of the primary masses is less than a critical value which depends also on the mass of the minor bodies.     

Photoionized Regions Around Supernova Remnants

The radiation produced by the gas cooling behind a fast supernova remnant shock in the interstellar medium is capable of ionizing the undisturbed medium ahead of the shock wave. In this work I investigate the nonequilibrium evolution of these photoionized precursor regions by means of radiation-hydrodynamic simulations of supernova remnant evolution. This revised version was published online in September 2006 with corrections to the Cover Date.     

Classification of four ordinary chondrites from the Monnig Meteorite Collection

Abstract— We classified four ordinary chondrites from the Monnig Meteorite Collection into compositional groups, petrologic types and shock stages, based on optical microscopy in transmitted and reflected light, and electron microprobe and modal analyses. These meteorites are Allen, Texas, H4(S2); May Day, Kansas, H4(S2); Pony Creek, Texas, H4(S3); and Springer, Oklahoma, H5(S3).     

Intertidal macroalgae and macroinvertebrates: Seasonal and spatial abundance patterns along an estuarine gradient

Quantitative sampling of the dominant intertidal epibiota was conducted seasonally along an estuarine gradient within the Great Bay Estuary System, New Hampshire, U.S.A. The abundance and zonation of the dominant macroorganisms varied with distance into the estuary. Replacement of marine by estuarine species occurred, and overall abundance and species richness decreased along the estuarine gradient. Zonation patterns within the inner estuary were primarily allied with substrata. Maximum abundance of invertebrates occurred in the mid-intertidal zone where a dense fucoid canopy provided habitat heterogeneity. Densities of epibiotic organisms decreased toward low water, especially in the inner estuary where hard substratum was limiting. Settlement blocks, introduced into the low intertidal zone, were dominated by barnacles and fucoid algae; after 16 months, the species composition on the settlement blocks resembled the adjacent community. Semibalanus balanoides settled in the spring, while Fucus vesiculosus var. spiralis exhibited low but constant settlement. Despite the physical rigors of the estuarine environment, only Semibalanus balanoides, Ilyanassa obsoleta and Spartina alterniflora showed significant seasonal changes in density. Thus, there are predictable and persistent epibiotic species assemblages within the intertidal zone of the Great Bay Estuary System.     

The flux of meteorites on the Earth's surface

Abstract— We derive values for the number and size distributions of meteorites landing on Earth from a study of photographic observations of bright fireballs with the Canadian camera network. The observations cover 11 years from 1974 to 1985. This analysis is an extension of a previous study and represents a 30% increase in the data base. The cumulative plot of numbers vs estimated mass of the largest fragment for each event shows a change in slope near 0.6 kg due to a deficiency of small meteorites surviving from the group of slow fireballs. The change can be explained by a mass dependence of the fraction of the incoming object that survives as the largest fragment. For larger falls, the main mass appears to represent a decreasing fraction of the total mass of the surviving meteorites and estimates of these effects are used to derive the final distribution of both main masses and total masses of meteoritic events. For total masses greater than 1 kg the population index is 1.82, close to previous estimates. About 9 events per year drop at least 1 kg of meteorites in an area of a million square km and the same area receives an annual influx of 54 kg from meteorite events with total masses between 0.01 and 100 kg. There is sufficient confidence in these results that they may be used for comparison of the present flux of meteorites with values inferred for other times, in particular the long accumulation times of the Antarctic meteorite collections.