Compositional and lithological diversity among brecciated lunar meteorites of intermediate iron concentration

Abstract— We present new compositional data for 30 lunar stones representing about 19 meteorites. Most have iron concentrations intermediate to those of the numerous feldspathic lunar meteorites (3–7% FeO) and the basaltic lunar meteorites (17–23% FeO). All but one are polymict breccias. Some, as implied by their intermediate composition, are mainly mixtures of brecciated anorthosite and mare basalt, with low concentrations of incompatible elements such as Sm (1–3 μg/g). These breccias likely originate from points on the Moon where mare basalt has mixed with material of the FHT (Feldspathic Highlands Terrane). Others, however, are not anorthosite‐basalt mixtures. Three (17–75 μ/g Sm) consist mainly of nonmare mafic material from the nearside PKT (Procellarum KREEP Terrane) and a few are ternary mixtures of material from the FHT, PKT, and maria. Some contain mafic, nonmare lithologies like anorthositic norites, norites, gabbronorites, and troctolite. These breccias are largely unlike breccias of the Apollo collection in that they are poor in Sm as well as highly feldspathic anorthosite such as that common at the Apollo 16 site. Several have high Th/Sm compared to Apollo breccias. Dhofar 961, which is olivine gabbronoritic and moderately rich in Sm, has lower Eu/Sm than Apollo samples of similar Sm concentration. This difference indicates that the carrier of rare earth elements is not KREEP, as known from the Apollo missions. On the basis of our present knowledge from remote sensing, among lunar meteorites Dhofar 961 is the one most likely to have originated from South Pole‐Aitken basin on the lunar far side.     

Numerical modelling of Cretaceous Pyrenean Rifting: The interaction between mantle exhumation and syn-rift salt tectonics

The preshortening Cretaceous Pyrenean Rift is an outstanding geological laboratory to investigate the effects of a pre-rift salt layer at the sedimentary base on lithospheric rifting. The occurrence of a pre-rift km-scale layer of evaporites and shales promoted the activation of syn-rift salt tectonics from the onset of rifting. The pre- and syn-rift sediments are locally affected by high-temperature metamorphism related to mantle ascent up to shallow depths during rifting. The thermo-mechanical interaction between décollement along the pre-existing salt layer and mantle ascent makes the Cretaceous Pyrenean Rifting drastically different from the type of rifting that shaped most Atlantic-type passive margins where salt deposition is syn-rift and gravity-driven salt tectonics has been postrift. To unravel the dynamic evolution of the Cretaceous Pyrenean Rift, we carried out a set of numerical models of lithosphere-scale extension, calibrated using the available geological constraints. Models are used to investigate the effects of a km-scale pre-rift salt layer, located at the sedimentary cover base, on the dynamics of rifting. Our results highlight the key role of the décollement layer at cover base that can alone explain both salt tectonics deformation style and high-temperature metamorphism of the pre-rift and syn-rift sedimentary cover. On the other hand, in the absence of décollement, our model predicts symmetric necking of the lithosphere devoid of any structure and related thermal regime geologically relevant to the Pyrenean case.     

Bringing GEOSS Services into Practice: A Capacity Building Resource on Spatial Data Infrastructures (SDI)

Data discoverability, accessibility, and integration are frequent barriers for scientists and a major obstacle for favorable results on environmental research. To tackle this issue, the Group on Earth Observations (GEO) is leading the development of the Global Earth Observation System of Systems (GEOSS), a voluntary effort that connects Earth Observation resources world‐wide, acting as a gateway between producers and users of environmental data. GEO recognizes the importance of capacity building and education to reach large adoption, acceptance and commitment on data sharing principles to increase the capacity to access and use Earth Observations data. This article presents “Bringing GEOSS services into practice” (BGSIP), an integrated set of teaching material and software to facilitate the publication and use of environmental data through standardized discovery, view, download, and processing services, further facilitating the registration of data into GEOSS. So far, 520 participants in 10 countries have been trained using this material, leading to numerous Spatial Data Infrastructure implementations and 1,000 tutorial downloads. This workshop lowers the entry barriers for both data providers and users, facilitates the development of technical skills, and empowers people.     

Examining the geometry,age and genesis of buried Quaternary valley systems in the Midland Valley of Scotland,UK

Buried palaeo‐valley systems have been identified widely beneath lowland parts of the UK including eastern England, central England, south Wales and the North Sea. In the Midland Valley of Scotland palaeo‐valleys have been identified yet the age and genesis of these enigmatic features remain poorly understood. This study utilizes a digital data set of over 100 000 boreholes that penetrate the full thickness of deposits in the Midland Valley of Scotland. It identified 18 buried palaeo‐valleys, which range from 4 to 36 km in length and 24 to 162 m in depth. Geometric analysis has revealed four distinct valley morphologies, which were formed by different subglacial and subaerial processes. Some palaeo‐valleys cross‐cut each other with the deepest features aligning east–west. These east–west features align with the reconstructed ice‐flow direction under maximum conditions of the Main Late Devensian glaciation. The shallower features appear more aligned to ice‐flow direction during ice‐sheet retreat, and were therefore probably incised under more restricted ice‐sheet configurations. The bedrock lithology influences and enhances the position and depth of palaeo‐valleys in this lowland glacial terrain. Faults have juxtaposed Palaeozoic sedimentary and igneous rocks and the deepest palaeo‐valleys occur immediately down‐ice of knick‐points in the more resistant igneous bedrock. The features are regularly reused and the fills are dominated by glacial fluvial and glacial marine deposits. This suggests that the majority of infilling of the features happened during deglaciation and may be unrelated to the processes that cut them.     

Estimation of diaphragm wall deflections for deep braced excavation in anisotropic clays using ensemble learning

This paper adopts the NGI-ADP soil model to carry out finite element analysis,based on which the effects of soft clay anisotropy on the diaphragm wall deflections in the braced excavation were evaluated.More than one thousand finite element cases were numerically analyzed,followed by extensive parametric studies.Surrogate models were developed via ensemble learning methods(ELMs),including the e Xtreme Gradient Boosting(XGBoost),and Random Forest Regression(RFR)to predict the maximum lateral wall deformation(δhmax).Then the results of ELMs were compared with conventional soft computing methods such as Decision Tree Regression(DTR),Multilayer Perceptron Regression(MLPR),and Multivariate Adaptive Regression Splines(MARS).This study presents a cutting-edge application of ensemble learning in geotechnical engineering and a reasonable methodology that allows engineers to determine the wall deflection in a fast,alternative way.     

An apatite U-Pb thermal history map for the northern Gawler Craton,South Australia

Apatite U-Pb thermochronology was applied to granitoid basement samples across the northern Gawler Craton to unravel the Proterozoic, post-orogenic, cooling history and to examine the role of major fault zones during cooling. Our observations indicate that cooling following the ~2500 Ma Sleaford Orogeny and ~1700 Ma Kimban Orogeny is restricted to the Christie and Wilgena Domains of the central northern Gawler Craton. The northern Gawler Craton mainly records post-Hiltaba Event(~1590 Ma) U-Pb cooling ages. Cooling following the ~1560 Ma Kararan Orogeny is preserved within the Coober Pedy Ridge,Nawa Domain and along major shear zones within the south-western Fowler Domain. The Nawa Domain samples preserve U-Pb cooling ages that are 150 Ma younger than the samples within the Coober Pedy Ridge and Fowler Domain, indicating that later(~1300 Ma) fault movement within the Nawa Domain facilitated cooling of these samples, caused by arc collision in the Madura Province of eastern Western Australia. When compared to~(40)Ar/~(39) Ar from muscovite, biotite and hornblende, our new apatite U-Pb ages correlate well, particularly in regions of higher data density. Our data also preserve a progressive younging of U-Pb ages from the nucleus of the craton to the periphery with a stark contrast in U-Pb ages across major structures such as the Karari Shear Zone and the Southern Overthrust, which indicates the timing of reactivation of these major crustal structures. Although this interpolation was based solely on thermochronological data and did not take into account structural or other geological data, these maps are consistent with the structural architecture of the Gawler Craton and reveal the thermal footprint of known tectonic and magmatic events in the Gawler Craton.     

A structured analysis of uncertainty surrounding modeled impacts of groundwater-extraction rules

Integrating economic and groundwater models for groundwater-management can help improve understanding of trade-offs involved between conflicting socioeconomic and biophysical objectives. However, there is significant uncertainty in most strategic decision-making situations, including in the models constructed to represent them. If not addressed, this uncertainty may be used to challenge the legitimacy of the models and decisions made using them. In this context, a preliminary uncertainty analysis was conducted of a dynamic coupled economic-groundwater model aimed at assessing groundwater extraction rules. The analysis demonstrates how a variety of uncertainties in such a model can be addressed. A number of methods are used including propagation of scenarios and bounds on parameters, multiple models, block bootstrap time-series sampling and robust linear regression for model calibration. These methods are described within the context of a theoretical uncertainty management framework, using a set of fundamental uncertainty management tasks and an uncertainty typology.     

Projected Reorganization of Florida Bay Seagrass Communities in Response to the Increased Freshwater Inflow of Everglades Restoration

Historic changes in water-use management in the Florida Everglades have caused the quantity of freshwater inflow to Florida Bay to decline by approximately 60% while altering its timing and spatial distribution. Two consequences have been (1) increased salinity throughout the bay, including occurrences of hypersalinity, coupled with a decrease in salinity variability, and (2) change in benthic habitat structure. Restoration goals have been proposed to return the salinity climates (salinity and its variability) of Florida Bay to more estuarine conditions through changes in upstream water management, thereby returning seagrass species cover to a more historic state. To assess the potential for meeting those goals, we used two modeling approaches and long-term monitoring data. First, we applied the hydrological mass balance model FATHOM to predict salinity climate changes in sub-basins throughout the bay in response to a broad range of freshwater inflow from the Everglades. Second, because seagrass species exhibit different sensitivities to salinity climates, we used the FATHOM-modeled salinity climates as input to a statistical discriminant function model that associates eight seagrass community types with water quality variables including salinity, salinity variability, total organic carbon, total phosphorus, nitrate, and ammonium, as well as sediment depth and light reaching the benthos. Salinity climates in the western sub-basins bordering the Gulf of Mexico were insensitive to even the largest (5-fold) modeled increases in freshwater inflow. However, the north, northeastern, and eastern sub-basins were highly sensitive to freshwater inflow and responded to comparatively small increases with decreased salinity and increased salinity variability. The discriminant function model predicted increased occurrences of Halodule wrightii communities and decreased occurrences of Thalassia testudinum communities in response to the more estuarine salinity climates. The shift in community composition represents a return to the historically observed state and suggests that restoration goals for Florida Bay can be achieved through restoration of freshwater inflow from the Everglades.     

Selected geochemical factors influencing diagenesis of eocene carbonate rocks,peninsular Florida,U.S.A.

The geochemical significance of three selected ions (Mg²⁺, Na⁺, and Sr²⁺) supports a model of dolomitization by brackish groundwater. This groundwater zone contains sufficient quantities of Mg²⁺ to facilitate dolomitization ($\text{Mg}\text{Ca}\text{ratios 1}$). Rising and falling of sea level and fluctuations of the phreatic zone related to climatic variations account for the thickness of the dolomite layers and the chemical distributions within these layers. Sodium concentrations in the calcite are 70–185 ppm, indicating formation in brackish water. Dolomite has sodium concentrations between 50–1400 ppm, suggesting formation in waters of similar salinity.Strontium in calcite ranges from 320–600 ppm, suggesting diagenesis in slightly saline waters in an open system. Dolomite contains 241 ppm Sr²⁺ on the average and calcite has 418 ppm Sr²⁺. The Sr²⁺ concentrations of the dolomite are characteristic of diagenesis in water less saline than sea water. Average strontium concentrations in the dolomite occur in two distinct groups, 260 ppm for dolomite with 39–43 mole-% MgCo₃ and 195 ppm for the dolomite with 44–50 mole-% MgCO₃. The difference in the Sr²⁺ concentrations of the two dolomite groups indicates the higher mole-% MgCO₃ dolomite recrystallized in a less saline environment than the lower mole-% MgCO₃ dolomite. These different environments are attributed to a relatively more saline coastal environment and a less saline inland environment.The more nearly stoichiometric dolomite (44–50 mole-% MgCO₃) has less scatter when mole-% MgCO₃ is plotted against Sr²⁺ and Na⁺. This suggests a greater approach to equilibrium with the dolomitizing fluid than the lower mole-% MgCO₃ (39–43) dolomite. The more saline environment has higher Mg/Ca ratios and promotes more calcium-rich dolomite during diagenesis because of the inhibition from competing foreign ions and because it is thermodynamically a more favorable environment which causes more rapid crystallization. The less saline waters allow recrystallization to proceed more slowly, producing better ordering in the dolomites, textural preservation and development of subhedral to euhedral rhombic crystals.