The role of collisional tectonics in the metallogeny of the Central Andean tin belt

The Inner Arc of the Central Andes, broadly corresponding to the Eastern Cordillera, is the location of a rich Tertiary and Triassic Sn–W–(Ag-base metal) metallogenic province, commonly referred to as the Bolivian tin belt. We propose that the Tertiary metallogeny, which generated most of the tin ores, was a direct consequence of discrete “collisions” between the South American plate and the Nazca slab and sub-slab mantle, during the ongoing Andean orogeny. Evidence supporting this proposal include: (1) the coincidence of the tin province and the Inner Arc in a marked “hump” in the Andean orogen, which may represent tectonic indentation; (2) the symmetry of the tin province with respect to the Bolivian orocline, the axis of which corresponds to the direction of highest compression; (3) the relative symmetry of the magmatism and tin mineralization with respect to this axis; (4) the concurrent timing of mineralization and compressional pulses; (5) the similar host rock geochemistry and ore lead isotope data, testifying to a common crustal reservoir; and (6) the striking similarity of the igneous suites, associated with the ore deposits to those from “typical” collisional orogens. A number of studies have called upon a persistent tin anomaly to explain the metallogeny of the region. We propose, instead, that the latter is better explained by periodic compressional interaction between the Farallon/Nazca oceanic plate and the South American continent. This led to the generation of peraluminous magmas, which during fractional crystallization exsolved the fluids responsible for the voluminous Sn–W mineralization.     

Mercury concentrations and omega-3 fatty acids in fish and shrimp: Preferential consumption for maximum health benefits

The consumption of fish and shrimp containing omega-3 fatty acids can result in protective health effects including a reduced risk of cardiovascular disease, stroke, and diabetes. These protective effects may be decreased by the presence of mercury in the muscle tissue of fish and shellfish. Mercury can increase the risk of cardiovascular problems and impede neurological development. The objective of this project was to determine appropriate consumption amounts of selected fish species and shrimp based on mercury levels and recommended intake levels of omega-3 fatty acids. Species that are high in omega-3s and low in mercury include salmon, trout, and shrimp. Species with both high levels of mercury and omega-3 fatty acids include tuna, shark, and halibut, swordfish, and sea bass.     

Geomorphic process signatures reshaping sub-humid Mediterranean badlands: 2. Application to 5-year dataset

Badland landscapes exhibit high erosion rates and represent the main source of fine sediments in some catchments. Advances in high-resolution topographic methods allow analysis of topographic changes at high temporal and spatial scales. We apply the Mapping Geomorphic Processes in the Environment (MaGPiE) algorithm to infer the main geomorphic process signatures operating in two sub-humid badlands with contrasting morphometric attributes located in the Southern Pyrenees. By interrogating a 5-year dataset of seasonal and annual topographic changes, we examine the variability of geomorphic processes at multiple temporal scales. The magnitude of geomorphic processes is linked to landform attributes and meteorological variables. Morphometric differences between both adjacent badlands allow us to analyse the role of landform attributes in the main geomorphic process reshaping landscapes subjected to the same external forcing (i.e. rainfall and temperature). The dominant geomorphic process signatures observed in both badlands are different, despite their close proximity and the same rainfall and temperature regimes. Process signatures determining surface lowering in the gently sloping south-facing badland, characterized by lower connectivity and more vegetation cover, are driven by surface runoff-based processes, both diffuse (causing sheet washing) and concentrated (determining cutting and filling, rilling and gullying). The steeper, more connected north-facing slopes of the other badland are reshaped by means of gravitational processes, with mass wasting dominating topographic changes. In terms of processes determining surface raising, both mass wasting and cutting and filling are most frequently observed in both badlands. There is a clear near-balanced feedback between both surface-raising and -lowering processes that becomes unbalanced at larger temporal scales due to the thresholds overcome, as the volume associated with surface lowering becomes higher than that associated with raising-based processes. Rainfall variables control surface flow processes, while those variables associated with low temperature have a significant relation with mass movement-based processes and other localized processes such as regolith cohesion loss. Finally, our results point out that morphometry (slope and connectivity) together with vegetation cover are key factors determining geomorphic processes and associated topographic changes. © 2020 John Wiley & Sons, Ltd.     

Amounts,forms, and management of nitrogen and phosphorus export from agricultural peatlands

Peatlands provide a setting that is well suited for cranberry agriculture in the Northeastern United States. However, misconceptions exist about the amounts and forms of nitrogen (N) and phosphorus (P) export from cranberry farms. In this study, we report inorganic and organic forms of N and P export from five peatlands cultivated for cranberry production in southeastern, Massachusetts, United States. We then compare N loading rates among cranberry farms in southeastern Massachusetts, row crop farms in the Midwestern United States, and uncultivated peatlands in the United States and United Kingdom. Based on a fluvial mass balance analysis, we find that nonriparian cranberry farms export 2.56 kg of P ha⁻¹ year⁻¹of total P and 12.1 kg of N ha⁻¹ year⁻¹of total N. Total N export from riparian or “flow through” farms is two times higher than nonriparian farms due to less retention of N fertilizer in the vadose zone of riparian farms. Gross total N export from riparian and nonriparian cranberry farms consists of 35% particulate organic N, 26% dissolved organic N, 31% ammonium (NH₄⁺), and 8% nitrate (NO₃⁻). The low proportions of NO₃⁻ export (13% of total dissolved N [TDN]) for cranberry farms differ from NO₃⁻ export for row crop farms (75% of TDN; p < .001) but not for uncultivated peatlands (17% of TDN; p = .61). Despite being highly modified by fertilizers and artificial drainage, low NO₃⁻ export (2.2 kg of N ha⁻¹ year⁻¹) from cranberry farms is consistent with field measurements of rapid N turnover in uncultivated peatlands. This finding suggests that state-funded wetland restoration efforts to restore denitrification in retired cranberry farms may be limited by NO₃⁻ rather than soil moisture or organic matter.     

Isotope-aided modelling of ecohydrologic fluxes and water ages under mixed land use in Central Europe: The 2018 drought and its recovery

Understanding the interactions of vegetation and soil water under varying hydrological conditions is crucial to aid quantitative assessment of land-use sustainability for maintaining water supply for humans and plants. Isolating and estimating the volume and ages of water stored within different compartments of the critical zone, and the associated fluxes of evaporation, transpiration, and groundwater recharge, facilitates quantification of these soil–plant-water interactions and the response of ecohydrological fluxes to wet and dry periods. We used the tracer-aided ecohydrological model EcH₂O-iso to examine the response of water ages of soil water storage, groundwater recharge, evaporation, and root-uptake at a mixed land use site, in northeastern Germany during the drought of 2018 and in the following winter months. The approach applied uses a dynamic vegetation routine which constrains water use by ecological mechanisms. Two sites with regionally typical land-use types were investigated: a forested site with sandy soils and a deep rooting zone and a grassland site, with loamier soils and shallower rooting zone. This results in much younger water ages (<1 year) through the soil profile in the forest compared to the grass, coupled with younger groundwater recharge. The higher water use in the forest resulted in a more pronounced annual cycle of water ages compared to the more consistent water age in the loamier soil of the grasslands. The deeper rooting zone of the forested site also resulted in older root-uptake water usage relative to soil evaporation, while the grassland site root-uptake was similar to that of soil evaporation. Besides more dynamic water ages in the forest, replenishment of younger soil waters to soil storage was within 6 months following the drought (cf. >8 months in the grassland). The temporal evaluation of the responsiveness of soil and vegetation interactions in hydrologic extremes such as 2018 is essential to understand changes in hydrological processes and the resilience of the landscape to the longer and more severe summer droughts predicted under future climate change.     

3‐D uncertainty‐based topographic change detection with structure‐from‐motion photogrammetry: precision maps for ground control and directly georeferenced surveys

Structure‐from‐motion (SfM) photogrammetry is revolutionising the collection of detailed topographic data, but insight into geomorphological processes is currently restricted by our limited understanding of SfM survey uncertainties. Here, we present an approach that, for the first time, specifically accounts for the spatially variable precision inherent to photo‐based surveys, and enables confidence‐bounded quantification of 3D topographic change. The method uses novel 3D precision maps that describe the 3D photogrammetric and georeferencing uncertainty, and determines change through an adapted state‐of‐the‐art fully 3D point‐cloud comparison (M3C2), which is particularly valuable for complex topography. We introduce this method by: (1) using simulated UAV surveys, processed in photogrammetric software, to illustrate the spatial variability of precision and the relative influences of photogrammetric (e.g. image network geometry, tie point quality) and georeferencing (e.g. control measurement) considerations; (2) we then present a new Monte Carlo procedure for deriving this information using standard SfM software and integrate it into confidence‐bounded change detection; before (3) demonstrating geomorphological application in which we use benchmark TLS data for validation and then estimate sediment budgets through differencing annual SfM surveys of an eroding badland. We show how 3D precision maps enable more probable erosion patterns to be identified than existing analyses, and how a similar overall survey precision could have been achieved with direct survey georeferencing for camera position data with precision half as good as the GCPs'. Where precision is limited by weak georeferencing (e.g. camera positions with multi‐metre precision, such as from a consumer UAV), then overall survey precision can scale as n^‐½ of the control precision (n = number of images). Our method also provides variance–covariance information for all parameters. Thus, we now open the door for SfM practitioners to use the comprehensive analyses that have underpinned rigorous photogrammetric approaches over the last half‐century. Copyright © 2017 John Wiley & Sons, Ltd.     

Quantification of bank erosion in a drained agricultural lowland catchment

The long‐term and current volumes of sediment exported from stream banks were calculated as potential sources of sediment in a large pond located at the catchment outlet of a small agricultural lowland basin strongly affected by anthropogenic pressure in France. Bank erosion was measured over a short period using a network of erosion pins along a small stream (1400 m long) to quantify the material exported during a single winter (2012–2013). The material exported by this same stream over the last 69 years was quantified using an original approach involving the comparison of a compilation of three‐dimensional historical stream redesign plans that date back to 1944 with the state of the banks in 2013 (differential global positioning system and LiDAR data). The results suggest that a global trend of material loss along the stream banks monitored by erosion pins, with an average erosion rate of 17.7 mm year^?1 and an average volume of exported material of 75 t km^?1. Over 69 years, this same stream exported an average of 36 t km^?1 year^?1, and the average loss of material from the banks throughout the whole catchment was estimated to be 14 t km^?1 year^?1. The contribution of bank material to the filling of the pond over the last 10 years is between 46% and 52% based on an extrapolation of erosion pin dynamics or between 27% and 30% based on the comparison of LiDAR data to the average historical profile extrapolated for the catchment. These results suggest that bank erosion represents a major source of sediment in degraded waters in traditionally understudied agricultural lowland catchments, where anthropogenic pressures are high.     

An Evaluation of Temporal Changes in Sediment Accumulation and Impacts on Carbon Burial in Mobile Bay,Alabama, USA

The estuarine environment can serve as either a source or sink of carbon relative to the coastal ocean carbon budget. A variety of time-dependent processes such as sedimentation, carbon supply, and productivity dictate how estuarine systems operate, and Mobile Bay is a system that has experienced both natural and anthropogenic perturbations that influenced depositional processes and carbon cycling. Sediments from eight box cores provide a record of change in bulk sediment accumulation and carbon burial over the past 110 years. Accumulation rates in the central part of the basin (0.09 g cm^?2) were 60–80 % less than those observed at the head (0.361 g cm^?2) and mouth (0.564 g cm^?2) of the bay. Sediment accumulation in the central bay decreased during the past 90 years in response to both anthropogenic (causeway construction) and natural (tropical cyclones) perturbations. Sediment accumulation inevitably increased the residence time of organic carbon in the oxic zone, as observed in modeled remineralization rates, and reduced the overall carbon burial. Such observations highlight the critical balance among sediment accumulation, carbon remineralization, and carbon burial in dynamic coastal environments. Time-series analysis based solely on short-term observation would not capture the long-term effects of changes in sedimentation on carbon cycling. Identifying these relationships over longer timescales (multi-annual to decadal) will provide a far better evaluation of coastal ocean carbon budgets.     

Evaluation of Geochemical Reference Standards by X-Ray Fluorescence Analysis

Twenty five elements in twenty six geochemical reference standards analyzed by X-ray fluorescence spectrometry yield major and trace element concentrations close to consensus values. Ninety percent of our analyses agree with consensus values for standards to within pm 0.5 to 1.5 relative percent for major elements and pm 3 to 5 relative percent or pm 1-3 ppm, whichever is higher, for trace elements. Consistent divergences from consensus values of trace elements are noted.     

Dispersion into pisolitic laterite from the greenbushes mineralized Sn-Ta pegmatite system, Western Australia

A study of dispersion into pisolitic laterite duricrust in the Archaean Greeenbushes mineralized pegmatite district reveals a geochemical anomaly that measures some 20 km by 12 km centred on the ore deposits that, prior to commencement of mining operations, were concealed. The anomaly is broadest for As, Sn, Be and Sb, all of which show well-defined centres over the swarm of mineralized pegmatites. Coincident highs of Nb, Ta and B also define the 5 km by 1 km anomaly centre. Over the strongest part of the multi-element anomaly, the following levels in ppm are reached in the pisolitic laterite: As 1150, Sb 75, Sn 4200, Nb 75, Ta 75, W 30, Li 100, B 500 and Be 60.The immediate source for the dispersion anomaly is the swarm of soft, weathered pegmatites and their wall rocks, most of which occur within a 5 km by 1 km area, elongated along strike. The source, as judged from past production plus soft pegmatite reserves, was a mass of some 30–40 million tonnes with an approximate average grade of 220 ppm Sn, 25 ppm Nb and 30 ppm Ta.The geochemical expression of the multi-element anomaly can conveniently be expressed in a map of pegmatite-associated elements. For example, the index PEG-4*X which uses an empirically derived weighted linear combination 0.09As + 1.33Sb + Sn + 0.6Nb + Ta (where values for each element are in ppm) gives a broad consistent anomaly.Investigation of dispersion processes shows that mechanical dispersion of cassiterite and columbo-tantalite took place for distances of at least 5 km during laterite formation along gradients ranging from 5 m to 20 m per km. The occurrence of anomalous As in the skins of pisolites indicates hydromorphic dispersion during laterite formation, but mechanical dispersion of goethitic material with scavenged As has also taken place.The size of the geochemical dispersion anomaly, together with its contrast and consistency, shows that it is feasible in the Australian environment to explore for concealed mineral deposits using low-density surface sampling. Sample spacings of 3 km are being tested in an extension of this approach to exploration.