Petrogenesis of lunar impact melt rock meteorite Oued Awlitis 001

Oued Awlitis 001 is a highly feldspathic, moderately equilibrated, clast‐rich, poikilitic impact melt rock lunar meteorite that was recovered in 2014. Its poikilitic texture formed due to moderately slow cooling, which judging from textures of rocks in melt sheets of terrestrial impact structures, is observed in impact melt volumes at least 100 m thick. Such coherent impact melt volumes occur in lunar craters larger than ~50 km in diameter. The composition of Oued Awlitis 001 points toward a crustal origin distant from incompatible‐element‐rich regions. Comparison of the bulk composition of Oued Awlitis 001 with Lunar Prospector 5° γ‐ray spectrometer data indicates a limited region of matches on the lunar farside. After its initial formation in an impact crater larger than ~50 km in diameter, Oued Awlitis 001 was excavated from a depth greater than ~50 m. The cosmogenic nuclide inventory of Oued Awlitis 001 records ejection from the Moon 0.3 Ma ago from a depth of at least 4 m and little mass loss due to ablation during its passage through Earth's atmosphere. The terrestrial residence time must have been very short, probably less than a few hundred years; its exact determination was precluded by a high concentration of solar cosmic ray‐produced ¹⁴C. If the impact that excavated Oued Awlitis 001 also launched it, this event likely produced an impact crater >10 km in diameter. Using petrologic constraints and Lunar Reconnaissance Orbiter Camera and Diviner data, we test Giordano Bruno and Pierazzo as possible launch craters for Oued Awlitis 001.     

Highly siderophile element and 187Re‐187Os isotopic systematics of ungrouped achondrite Northwest Africa 7325: Evidence for complex planetary processes

The abundances of highly siderophile elements (HSE; including Re, Os, Ir, Ru, Pt, and Pd) and ¹⁸⁷Re‐¹⁸⁷Os isotopic systematics were determined for two fragments from ungrouped achondrite NWA 7325. Rhenium‐Os systematics are consistent with closed‐system behavior since formation or soon after. The abundances of the HSE were therefore largely unaffected by late‐stage secondary processes such as shock or terrestrial weathering. As an olivine gabbro cumulate, this meteorite has a bulk composition consistent with derivation from a body that produced a core, mantle, and crust. Also consistent with derivation from a body that produced a core, both fragments of NWA 7325 have HSE abundances that are highly depleted compared to bulk chondrites. One fragment has ~0.002× CI chondrite Ir and relative HSE abundances similar to bulk chondrites. The other fragment has ~0.0002× CI chondrite Ir and relative HSE abundances that are fractionated compared to bulk chondrites. The chondritic relative HSE abundances of the fragment characterized by higher HSE abundances most likely reflect the addition of exogenous chondritic material during or after crystallization by surface impacts. The HSE in the other fragment is likely more representative of the parent body crust. One formation model that can broadly account for the HSE abundances in this fragment is multiple episodes of low‐pressure metal‐silicate equilibration, followed by limited late accretion and mantle homogenization. Given the different HSE compositions of the two adjoining fragments, this meteorite provides an example of the overprint of global processes (differentiation and late accretion) by localized impact contamination.     

The chlorine isotope composition of iron meteorites: Evidence for the Cl isotope composition of the solar nebula and implications for extensive devolatilization during planet formation

The bulk chlorine concentrations and isotopic compositions of a suite of non‐carbonaceous (NC) and carbonaceous (CC) iron meteorites were measured using gas source mass spectrometry. The δ³⁷Cl values of magmatic irons range from ?7.2 to 18.0‰ versus standard mean ocean chloride and are unrelated to their chlorine concentrations, which range from 0.3 to 161 ppm. Nonmagmatic IAB irons are comparatively Cl‐rich containing >161 ppm with δ³⁷Cl values ranging from ?6.1 to ?3.2‰. The anomalously high and low δ³⁷Cl values are inconsistent with a terrestrial source, and as Cl contents in magmatic irons are largely consistent with derivation from a chondrite‐like silicate complement, we suggest that Cl is indigenous to iron meteorites. Two NC irons, Cape York and Gibeon, have high cooling rates with anomalously high δ³⁷Cl values of 13.4 and 18.0‰. We interpret these high isotopic compositions to result from Cl degassing during the disruption of their parent bodies, consistent with their low volatile contents (Ga, Ge, Ag). As no relevant mechanisms in iron meteorite parent bodies are expected to decrease δ³⁷Cl values, whereas volatilization is known to increase δ³⁷Cl values by the preferential loss of light isotopes, we interpret the low isotope values of <?5‰ and down to ?7.2‰ to most closely represent the primordial isotopic composition of Cl in the solar nebula. Similar conclusions have been derived from low δ³⁷Cl values down to ?6, and ?3.8‰ measured in Martian and Vestan meteorites, respectively. These low δ³⁷Cl values are in contrast to those of chondrites which average around 0‰ previously explained by the incorporation of isotopically heavy HCl clathrate into chondrite parent bodies. The poor retention of low δ³⁷Cl values in many differentiated planetary materials suggest that extensive devolatilization occurred during planet formation, which can explain Earth's high δ³⁷Cl value by the loss of approximately 60% of the initial Cl content.     

Comment on Malanson(2017) “Mixed signals in trends of variance in high-elevation tree ring chronologies” published in Journal of Mountain Science

In a recent paper published in Journal of Mountain Science, Malanson (2017) explored variance changes in Rocky Mountains tree-ring chronologies. This commentary points out some methodological issues related to systematic bias in evolving tree-ring chronology variance and suggests that analyzing the slopes of linear regression lines may be suboptimal for identifying temporal changes in variance. The journal editor invited the original article’s authors Dr. Malandson to respond to the comments. Thus Dr. Malandson’s response is attached behind the comments.     

Fluid fluxes during low-temperature alteration: implications of multi-style alteration assemblages from the Welsh Borderland,UK

Localized (domainal) low-temperature alteration may indicate variations in the chemistry of alteration fluids and/or discrete fluid flow paths during metamorphism. Occurrences of epidote- and pumpellyite-dominated domains are often used as evidence for large fluxes of Ca-rich fluids. However, comparative studies of two domainal alteration styles from basaltic to andesitic lavas and volcaniclastic rocks at Builth Wells, Wales, UK suggest that such interpretations cannot be applied universally. Here, only one set of domains can be attributed to large fluxes of Ca-rich fluids. In contrast, the second set of domains formed where the host rock supplied the necessary Ca, and fluid/rock ratios were relatively low. These domains are hosted by rocks which show a Caledonian regional metamorphic imprint, characterized by the alteration assemblage albite+chlorite+titanite±prehnite±pumpellyite±calcite±muscovite±quartz (considered to have formed at c. 200°C and ≤2.5 kbar). Type 1 domains lie along fluid channelways, such as veins. Pumpellyite is the dominant secondary mineral, but the alteration assemblage is variable with pumpellyite±prehnite±calcite±titanite±chlorite (±quartz). The domains formed at temperatures of 130–230°C during Ordovician hydrothermal activity, before the peak of regional metamorphism. In contrast, Type 2 domains are not associated with obvious fluid channelways. A central prehnite-dominated zone typically has a rim with the assemblage pumpellyite+calcite±prehnite±chlorite±titanite±K-rich phyllosilicate. These domains probably formed from pelitic xenoliths which contained a volcaniclastic component at temperatures of 130–230°C and at relatively low fluid/rock ratios. However, the timing of domain formation is uncertain. Pyrobitumen, in veins and disseminated throughout the rock, may have influenced the formation of both types of domain by stabilizing pumpellyite in preference to epidote and causing metamorphic calcite formation through the release of CO₂ to the alteration fluids. © 1996 John Wiley & Sons, Ltd.     

A simulation study of the role of raindrop erosion in the formation of desert pavements

A simple model of raindrop erosion—the combined effects of the detachment of sediment by raindrops and its transport by splash or by overland flow—is developed to examine the role of this process in the formation of desert pavements. Application of the model to soils in areas of existing pavement initially simulates the formation of pavements, but the changing sediment size distributions lead to the subsequent destruction of these modelled surfaces. An improved model that accounts for the feedback effects of the changing size distributions on infiltration and microtopography is then developed. Incorporating these effects allows simulated pavements to be maintained over longer periods. The model yields desert pavements whose particle size compositions differ in response to differences in initial soil characteristics, slope and rainfall intensity. This model is tested against empirical data from a site where there is intershrub pavement and associated mounds of fines beneath desert shrubs. The results successfully predict the accumulation of fines under shrubs but underestimate the development of the pavement between shrubs. These findings suggest that the raindrop erosion mechanism on its own cannot account for the development of the pavement and that some other mechanism leading to the surface concentration of coarse particles must also be operating.     

Prediction of the calcium carbonate budget in a sedimentary basin: A “source-to-sink” approach applied to Great Salt Lake,Utah, USA

Most source-to-sink studies typically focus on the dynamics of clastic sediments and consider erosion, transport and deposition of sediment particles as the sole contributors. Although often neglected, dissolved solids produced by weathering processes contribute significantly in the sedimentary dynamics of basins, supporting chemical and/or biological precipitation. Calcium ions are usually a major dissolved constituent of water drained through the watershed and may facilitate the precipitation of calcium carbonate when supersaturating conditions are reached. The high mobility of Ca²⁺ ions may cause outflow from an open system and consequently loss. In contrast, in closed basins, all dissolved (i.e. non-volatile) inputs converge at the lowest point of the basin. The endoreic Great Salt Lake basin constitutes an excellent natural laboratory to study the dynamics of calcium on a basin scale, from the erosion and transport through the watershed to the sink, including sedimentation in lake's waterbody. The current investigation focused on the Holocene epoch. Despite successive lake level fluctuations (amplitude around 10 m), the average water level seems to have not been affected by any significant long-term change (i.e. no increasing or decreasing trend, but fairly stable across the Holocene). Weathering of calcium-rich minerals in the watershed mobilizes Ca²⁺ ions that are transported by surface streams and subsurface flow to the Great Salt Lake (GSL). Monitoring data of these flows was corrected for recent anthropogenic activity (river management) and combined with direct precipitation (i.e. rain and snow) and atmospheric dust income into the lake, allowing estimating the amount of calcium delivered to the GSL. These values were then extrapolated through the Holocene period and compared to the estimated amount of calcium stored in GSL water column, porewater and sediments (using hydrochemical, mapping, coring and petrophysical estimates). The similar estimate of calcium delivered (4.88 Gt) and calcium stored (3.94 Gt) is consistent with the premise of the source-to-sink approach: a mass balance between eroded and transported compounds and the sinks. The amount of calcium deposited in the basin can therefore be predicted indirectly from the different inputs, which can be assessed with more confidence. When monitoring is unavailable (e.g. in the fossil record), the geodynamic context, the average lithology of the watershed and the bioclimatic classification of an endoreic basin are alternative properties that may be used to estimate the inputs. We show that this approach is sufficiently accurate to predict the amount of calcium captured in a basin and can be extended to the whole fossil record and inform on the storage of calcium.     

Design of Buoys for Mounting Wind Turbines at Exposed Sites

In this study, two designs for a buoy capable of supporting a 10 kW wind turbine and its tower were developed to operate at the University of New Hampshire’s Center of Ocean Renewable Energy testing site located off the Isles of Shoals, New Hampshire. The buoys are to be moored by a catenary chain system. To evaluate wave response, two Froude-scaled models were constructed, tested, and compared at the Ocean Engineering wave tank at the University of New Hampshire. These buoys have been implemented and compared with wave tank measurements of the spar displacement at a reference elevation 2.44 m above the mean water level.     

Community involvement in fisheries management: Experiences in the Gulf of Thailand countries

This paper examines the involvement of coastal communities in fisheries management among the countries of the Gulf of Thailand—Malaysia, Vietnam, Cambodia and Thailand. Initiatives to decentralize management to local governing bodies, to utilize traditional management methods and to engage in community agreements to protect local resources are explored. An examination of recent experiences indicates some movement toward more local involvement in management. However, the study also leads to several suggestions for the future: in Vietnam and Cambodia, there is a need for significant legislation to control fisheries operations and greater clarity of the role of communities in management; in Malaysia, there is an overall need for more support to local fisheries management; and in Thailand, the need is for greater support of local-level enforcement and monitoring activities.     

Tuning a physically-based model of the air–sea gas transfer velocity

Air–sea gas transfer velocities are estimated for one year using a 1-D upper-ocean model (GOTM) and a modified version of the NOAA–COARE transfer velocity parameterization. Tuning parameters are evaluated with the aim of bringing the physically based NOAA–COARE parameterization in line with current estimates, based on simple wind-speed dependent models derived from bomb-radiocarbon inventories and deliberate tracer release experiments. We suggest that A = 1.3 and B = 1.0, for the sub-layer scaling parameter and the bubble mediated exchange, respectively, are consistent with the global average CO₂ transfer velocity k. Using these parameters and a simple 2nd order polynomial approximation, with respect to wind speed, we estimate a global annual average k for CO₂ of 16.4 ± 5.6 cm h^?1 when using global mean winds of 6.89 m s^?1 from the NCEP/NCAR Reanalysis 1 1954–2000. The tuned model can be used to predict the transfer velocity of any gas, with appropriate treatment of the dependence on molecular properties including the strong solubility dependence of bubble-mediated transfer. For example, an initial estimate of the global average transfer velocity of DMS (a relatively soluble gas) is only 11.9 cm h^?1 whilst for less soluble methane the estimate is 18.0 cm h^?1.