Impact of nitrogenous fertilizers on carbonate dissolution in small agricultural catchments: Implications for weathering CO2 uptake at regional and global scales

The goal of this study was to highlight the occurrence of an additional proton-promoted weathering pathway of carbonate rocks in agricultural areas where N-fertilizers are extensively spread, and to estimate its consequences on riverine alkalinity and uptake of CO₂ by weathering. We surveyed 25 small streams in the calcareous molassic Gascogne area located in the Garonne river basin (south-western France) that drain cultivated or forested catchments for their major element compositions during different hydrologic periods. Among these catchments, the Hay and the Montoussé, two experimental catchments, were monitored on a weekly basis. Studies in the literature from other small carbonate catchments in Europe were dissected in the same way. In areas of intensive agriculture, the molar ratio (Ca + Mg)/HCO₃ in surface waters is significantly higher (0.7 on average) than in areas of low anthropogenic pressure (0.5). This corresponds to a decrease in riverine alkalinity, which can reach 80% during storm events. This relative loss of alkalinity correlates well with the content in surface waters. In cultivated areas, the contribution of atmospheric/soil CO₂ to the total riverine alkalinity (CO_{2 ATM-SOIL}/HCO₃) is less than 50% (expected value for carbonate basins), and it decreases when the nitrate concentration increases. This loss of alkalinity can be attributed to the substitution of carbonic acid (natural weathering pathway) by protons produced by nitrification of N-fertilizers (anthropogenic weathering pathway) occurring in soils during carbonate dissolution. As a consequence of these processes, the alkalinity over the last 30 years shows a decreasing trend in the Save river (one of the main Garonne river tributaries, draining an agricultural catchment), while the nitrate and calcium plus magnesium contents are increasing.We estimated that the contribution of atmospheric/soil CO₂ to riverine alkalinity decreased by about 7-17% on average for all the studied catchments. Using these values, the deficit of CO₂ uptake can be estimated as up to 0.22-0.53 and 12-29 Tg¹ yr⁻¹ CO₂ on a country scale (France) and a global scale, respectively. These losses represent up to 5.7-13.4% and only 1.6-3.8% of the total CO₂ flux naturally consumed by carbonate dissolution, for France and on a global scale, respectively. Nevertheless, this loss of alkalinity relative to the Ca + Mg content relates to carbonate weathering by protons from N-fertilizers nitrification, which is a net source of CO₂ for the atmosphere. This anthropogenic CO₂ source is not negligible since it could reach 6-15% of CO₂ uptake by natural silicate weathering and could consequently partly counterbalance this natural CO₂ sink.     

Dating of marine aragonite by electron spin resonance

Marine aragonite, in the form of corals and/or shells, provides useful markers of geological and archaeological events. It is, therefore, important to have simple and accurate methods of dating these materials. Electron spin resonance (ESR) has previously been shown to be a reliable method for establishing the age of aragonitic coral samples in the time period approximately 100 ka B.P. The primary purpose of the present work is to discuss the problems encountered in extending this method to considerably older samples, up to 600 ka BP in age. In this time period there are questions about the stability of the ESR signal. The samples investigated are aragonitic corals from reef terraces of Barbados, West Indies, all of which have previously been dated by the methods, and by U-series disequilibrium, for samples below the limit of this method. There is generally good agreement for samples up to about 300 ka in age; older samples, even unrecrystallized, appear younger when dated by ESR than by . The source of this discrepancy is not clear. The explanation of thermal fading is not adequate. However, it appears likely that in most cases ESR will be able to be used to date materials up to this age. Further investigation is needed to determine tests that will distinguish datable samples from non-datable ones.     

Heat capacity, entropy, and magnetic properties of jarosite-group compounds

Jarosite phases are common minerals in acidic, sulfate-rich environments. Here, we report heat capacities (C _p) and standard entropies (S°) for a number of jarosite samples. Most samples are close to the nominal composition AFe₃(SO₄)₂(OH)₆, where A = K, Na, Rb, and NH₄. One of the samples has a significant number of defects on the Fe sites and is called the defect jarosite; others are referred to as A-jarosite. The samples, their compositions, and the entropies at T = 298.15 K are:

A study of intergranular and fissure permeability in Chalk and Permian aquifers,using double-packer injection testing

Double-packer injection tests have been carried out in a borehole in the Chalk of Hampshire and a borehole in the Permian Penrith Sandstone of Cumbria, England. The tests have been supplemented by borehole logging and television inspections and by laboratory measurements on cores. A new mathematical treatment has enabled results to be calculated for injection test intervals containing fissures. In both formations, transmissivity immediately around the borehole is dominated by a few major fissures. In the Penrith Sandstone there is good agreement between intergranular hydraulic conductivity measurements and packer-test results in the portions of the borehole which do not contain major fissures. In the Chalk, the packer-test values are always higher than the intergranular measurements, suggesting that some degree of fissuring is present throughout.     

Parasitic barnacles (Cirripedia: Rhizocephala) from New Zealand off‐shore waters

Nine genera and species of rhizocephalans were recorded from the off‐shore waters around New Zealand. Mitochondrial and nuclear gene sequences were used to examine base differences between the European and New Zealand species of Parthenopea. Serial sections to study the internal structures of the reproductive organs were made for the genera Thylacoplethus and Thompsonia. Two species, Parthenopea australis n. sp. and Thylacoplethus novaezealandiae n. sp. are new to science and described in detail. Parthenopea australis n. sp. is the first rhizocephalan species recorded from the vicinity of active cold seeps. Three rhizocephalans could not be identified as they were parasitised by hyperparasitic cryptoniscine isopods. The decapodhost species comprised the taxa Paguridae, Lithodidae, Galatheidae, Chirostylidae, and Callianassidae.     

Retrograde fluid infiltration in the high-grade Modum Complex South Norway: evidence for age,source and REE mobility

The high-grade metamorphic basement of the Modum Complex, South Norway,exhibits retrogradation and alteration due to late stage fluid infiltration.Extensive alteration zones of albite-and calcite-rich veining occur especiallywithin and around numerous metagabbros. The gabbros, intruded at 1224±15Ma, are now partly altered to amphibolites due to the subsequent high-grade metamorphism.Two generations of albite-rich rocks have been recognized: (1) a fine-grained, foliated type;(2) a coarse-grained, crosscutting type. Both types show a typical greenschist facies mineralassemblage; albite ± actinolite ± chlorite ± talc. The calcite veins/dykesrepresent a younger generation of veins than both albite-rich types. U–Pb data for spheneof type (1) yielded an age of 1080±3 Ma, determining a point on the retrogradeP-T-t path of the Modum Complex. Increasing albitisation of themetagabbros leads to a decrease in(¹⁴³ND/¹⁴⁴Nd)_oand an increase in (⁸⁷Sr/⁸⁶)_o.Albite- and calcite-rich samples show negative _Nd and positive _Sr, suggesting that fluids which interacted with the metagabbros originated from a crustal reservoir. The Nd and Sr isotopic data show disequilibrium at the microscale as well as at the macroscale. Negative Sm–Nd model ages of the albite-rich rocks demonstrate that rare-earth elements (REEs) were mobile and fractionated during albitisation.     

Tectonique transpressive en terre Adélie au Paléoprotérozoı̈que (Est Antarctique)Palaeoproterozoic transpression in Terre Adélie (East Antarctica)

The Palaeoproterozoic units of Terre Adélie show two types of structural domains associated with HT–LP metamorphic conditions: domes and NS–N340° striking vertical shear zones. Shear zones reflect dextral transpressive motions. Domes reflect sub-vertical shortening and principal stretching subparallel to shear zones. They could partly result from longitudinal flow coeval with transpression. Deformations are comparable to those described along the eastern and western boundaries of the Archean Gawler Craton (South-East Australia), which underlines the continuity between these two areas before opening of the Austral Ocean. To cite this article: A. Pelletier et al., C. R. Geoscience 334 (2002) 505–511.     

Coasts, water levels, and climate change: A Great Lakes perspective

The North American Laurentian Great Lakes hold nearly 20 % of the earth’s unfrozen fresh surface water and have a length of coastline, and a coastal population, comparable to frequently-studied marine coasts. The surface water elevations of the Great Lakes, in particular, are an ideal metric for understanding impacts of climate change on large hydrologic systems, and for assessing adaption measures for absorbing those impacts. In light of the importance of the Great Lakes to the North American and global economies, the Great Lakes and the surrounding region also serve as an important benchmark for hydroclimate research, and offer an example of successful adaptive management under changing climate conditions. Here, we communicate some of the important lessons to be learned from the Great Lakes by examining how the coastline, water level, and water budget dynamics of the Great Lakes relate to other large coastal systems, along with implications for water resource management strategies and climate scenario-derived projections of future conditions. This improved understanding fills a critical gap in freshwater and marine global coastal research.