Element partitioning during precipitation of aragonite from seawater: A framework for understanding paleoproxies

This study presents the results from precipitation experiments carried out to investigate the partitioning of the alkaline earth cations Mg²⁺, Ca²⁺, Sr²⁺, and Ba²⁺ between abiogenic aragonite and seawater as a function of temperature. Experiments were carried out at 5 to 75 °C, using the protocol of Kinsman and Holland [Kinsman, D.J.J., Holland, H.D., 1969. The coprecipitation of cations with CaCO₃ IV. The coprecipitation of Sr²⁺ with aragonite between 16 and 96 °C. Geochim. Cosmochim. Acta33, 1-17.] The concentrations of Mg Sr and Ba were determined in the fluid from each experiment by inductively coupled plasma-mass spectrometry, and in individual aragonite grains by secondary ion mass spectrometry. The experimentally produced aragonite grains are enriched in trace components (“impurities”) relative to the concentrations expected from crystal-fluid equilibrium, indicating that kinetic processes are controlling element distribution. Our data are not consistent with fractionations produced kinetically in a boundary layer adjacent to the growing crystal because Sr²⁺, a compatible element, is enriched rather than depleted in the aragonite. Element compatibilities, and the systematic change in partitioning with temperature, can be explained by the process of surface entrapment proposed by Watson and Liang [Watson, E.B., Liang, Y., 1995. A simple model for sector zoning in slowly grown crystals: implications for growth rate and lattice diffusion, with emphasis on accessory minerals in crustal rocks. Am. Mineral.80, 1179-1187] and Watson [Watson, E.B., 1996. Surface enrichment and trace-element uptake during crystal growth. Geochim. Cosmochim. Acta60, 5013-5020; Watson, E.B., 2004. A conceptual model for near-surface kinetic controls on the trace-element and stable isotope composition of abiogenic calcite crystals. Geochim. Cosmochim. Acta68, 1473-1488]. This process is thought to operate in regimes where the competition between crystal growth rate and diffusivity in the near-surface region limits the extent to which the solid can achieve partitioning equilibrium with the fluid. A comparison of the skeletal composition of Diploria labyrinthiformis (brain coral) collected on Bermuda with results from precipitation calculations carried out using our experimentally determined partition coefficients indicate that the fluid from which coral skeleton precipitates has a Sr/Ca ratio comparable to that of seawater, but is depleted in Mg and Ba, and that there are seasonal fluctuations in the mass fraction of aragonite precipitated from the calcifying fluid (“precipitation efficiency”). The combined effects of surface entrapment during aragonite growth and seasonal fluctuations in “precipitation efficiency” likely forms the basis for the temperature information recorded in the aragonite skeletons of Scleractinian corals.     

Analysis of the Devonian (Frasnian) platform from Belgium: a multi‐faceted approach for basin evolution reconstruction

This study undertakes a multi‐disciplinary approach (sedimentology, carbon isotopes, magnetic susceptibility and thickness distribution) to improve understanding of a major Palaeozoic carbonate platform, the Frasnian platform of Belgium. These combined techniques are used to reconstruct the platform history, which evolved in two main steps. During the first phase, the basin was strongly influenced by faulting, producing notable thickness and facies variations, with open ocean conditions, with good water circulation and no/or limited barrier reef. The second phase of platform development was less influenced by differential subsidence, as indicated by homogeneous facies distribution. However, this platform developed under restricted waters, with low circulation which is likely related to the development of a barrier reef.     

The Livelihood Vulnerability Index: A pragmatic approach to assessing risks from climate variability and change—A case study in Mozambique

We developed the Livelihood Vulnerability Index (LVI) to estimate climate change vulnerability in the Mabote and Moma Districts of Mozambique. We surveyed 200 households in each district to collect data on socio-demographics, livelihoods, social networks, health, food and water security, natural disasters and climate variability. Data were aggregated using a composite index and differential vulnerabilities were compared. Results suggest that Moma may be more vulnerable in terms of water resources while Mabote may be more vulnerable in terms of socio-demographic structure. This pragmatic approach may be used to monitor vulnerability, program resources for assistance, and/or evaluate potential program/policy effectiveness in data-scarce regions by introducing scenarios into the LVI model for baseline comparison.     

New snow metrics for a warming world

Snow is Earth's most climatically sensitive land cover type. Traditional snow metrics may not be able to adequately capture the changing nature of snow cover. For example, April 1 snow water equivalent (SWE) has been an effective index for streamflow forecasting, but it cannot express the effects of midwinter melt events, now expected in warming snow climates, nor can we assume that station-based measurements will be representative of snow conditions in future decades. Remote sensing and climate model data provide capacity for a suite of multi-use snow metrics from local to global scales. Such indicators need to be simple enough to “tell the story” of snowpack changes over space and time, but not overly simplistic or overly complicated in their interpretation. We describe a suite of spatially explicit, multi-temporal snow metrics based on global satellite data from NASA's Moderate Resolution Imaging Spectroradiometer (MODIS) and downscaled climate model output for the U.S. We describe and provide examples for Snow Cover Frequency (SCF), Snow Disappearance Date (SDD), At-Risk Snow (ARS), and Frequency of a Warm Winter (FWW). Using these retrospective and prospective snow metrics, we assess the current and future snow-related conditions in three hydroclimatically different U.S. watersheds: the Truckee, Colorado Headwaters, and Upper Connecticut. In the two western U.S. watersheds, SCF and SDD show greater sensitivity to annual differences in snow cover compared with data from the ground-based Snow Telemetry (SNOTEL) network. The eastern U.S. watershed does not have a ground-based network of data, so these MODIS-derived metrics provide uniquely valuable snow information. The ARS and FWW metrics show that the Truckee Watershed is highly vulnerable to conversion from snowfall to rainfall (ARS) and midwinter melt events (FWW) throughout the seasonal snow zone. In comparison, the Colorado Headwaters and Upper Connecticut Watersheds are colder and much less vulnerable through mid- and late-century.     

Northern boundary current variability and mesoscale dynamics: a long-term HF RADAR monitoring in the North-Western Mediterranean Sea

Ocean Dynamics - Coastal waters are globally challenging areas to monitor not only because of the high resolution needed to resolve the scales at stake but also because most satellites are not yet...     

Dynamics and transport from the boundary Northern Current toward the Toulon Bay: multi-platform observations and downscaling modelling approaches

Ocean Dynamics - Coastal regions are vulnerable areas with often high population density, as well as tourism and maritime activities that may have negative impact on the environment. From a...     

A Titanosaurian Sauropod Dinosaur with Opisthocoelous Caudal Vertebrae from the Early Late Cretaceous of Liaoning Province, China

We describe a new titanosaurian sauropod dinosaur, Borealosaurus wimani gen. et sp. nov., based on a distinctive mid-distal caudal vertebra from the early Late Cretaceous Sunjiawan Formation exposed in the Shuangmiao village of Beipiao in Liaoning, China. We provisionally refer an isolated tooth crown, a middle caudal vertebra, and a right humerus from the same locality and horizon to this taxon. Borealosaurus is distinguished from other sauropods in its possession of opisthocoelous mid-distal caudal vertebrae. The occurrence of opisthocoelous caudals in Borealosaurus and the Mongolian sauropod Opisthocoelicaudia raises the possibility that these taxa pertain to an as-yet unrecognized titanosaurian subclade endemic to the Cretaceous Asia.     

Planetary perturbations on Mercury’s libration in longitude

Two space missions dedicated to Mercury (MESSENGER and BepiColombo) aim at understanding its rotation and confirming the existence of a liquid core. This double challenge requires much more accurate models for the spin-orbit resonant rotation of Mercury. The purpose of this paper is to introduce planetary perturbations on Mercury’s rotation using an analytical method and to analyse the influence of the perturbations on the libration in longitude. Applying a perturbation theory based on the Lie triangle, we were able to re-introduce short periodic terms into the averaged Hamiltonian and to compute the evolution of the rotational variables. The perturbations on Mercury’s forced libration in longitude mainly come from the orbital motion of Mercury (with an amplitude around 41 arcsec that depends on the momenta of inertia). It is completed by various effects from Jupiter (11.86 and 5.93 year-periods), Venus (with a 5.66 year-period), Saturn (14.73 year-period), and the Earth (6.58 year-period). The amplitudes of the oscillations due to Jupiter and Venus are approximately 33% and 10% of those from the orbital motion of Mercury and the amplitudes of the oscillations due to Saturn and the Earth are approximately 3% and 2%. We compare the analytical results with the solution obtained from the spin-orbit numerical model SONYR.     

贝塞尔曲线在虚拟森林景观单树几何模型构建中的应用

虚拟景观模型的生成,需要对实际景观进行抽象和简化。树几何模型和数字高程模型(DEM)是构成虚拟森林景观的两大要素。而树几何模型的构建又是林业GIS三维可视化的基础。在树几何建模中,树干及树枝形状的可视化表达具有突出意义。由于实际树种的复杂性,在计算机中建树模型,通常采用基于过程建模的方式,而这将面临用户如何对模型进行交互式控制的问题：参数太少,不足以描述树形态特征,而参数太多,则模型难以生成和理解。为了解决这个问题,我们引进贝塞尔(Bezier)曲线这种基于控制点的自由曲线来描述树木中的树干以及树枝形状,利用对曲线控制点的变动来控制曲线的形状,进而生成形态各异的树形状,对此,我们基于ActiveX技术生成Bezier曲线控件。结果表明,该方法能够表示多种形状的树干与树枝,具有操作简捷、计算速度快,可视化效果良好的优点。