Calcium Carbonate and Phosphate Reference Materials for Monitoring Bulk and Microanalytical Determination of Sr Isotopes

In situ laser ablation analyses rely on the microanalytical homogeneity of reference materials (RMs) and a similar matrix and mass fraction between unknown samples and RMs to obtain reliable results. Suitable carbonate and phosphate RMs for determination of Sr isotope ratios in such materials are limited. Thus, we determined ⁸⁷Sr/⁸⁶Sr ratios of several carbonate (JCt‐1, JCp‐1, MACS‐1, MACS‐3) and phosphate (MAPS‐4, MAPS‐5, NIST SRM 1400, NIST SRM 1486) international RMs using dissolved samples and two different multi‐collector inductively coupled plasma‐mass spectrometers (MC‐ICP‐MS). Our Sr isotope data are in agreement with published data and have an improved measurement precision for some RMs. For MACS‐1, we present the first ⁸⁷Sr/⁸⁶Sr value. We tested the suitability of these materials for microanalytical analyses by LA‐MC‐ICP‐MS, with two different laser ablation systems: a conventional nanosecond laser and a state‐of‐the‐art femtosecond laser. We investigated the RMs micro‐homogeneity and compared the data with our solution data. Both laser ablation systems yielded identical ⁸⁷Sr/⁸⁶Sr ratios within uncertainty to the solution data for RMs with low interferences of REEs. Therefore, these carbonate and phosphate RMs can be used to achieve accurate and precise results for in situ Sr isotope investigations by LA‐MC‐ICP‐MS of similar materials.     

Rapid characterisation of the extremely large landslide threatening the Rules Reservoir (Southern Spain)

Landslides - When an active landslide is first identified in an artificial reservoir, a comprehensive study has to be quickly conducted to analyse the possible hazard that it may represent to such...     

Dating recent floodplain sediments in the Hawkesbury‐Nepean River system,eastern Australia using single‐grain quartz OSL

Two fluvial sediment cores taken from a floodplain of the Hawkesbury‐Nepean River system in the Sydney region, eastern Australia are dated using Optically Stimulated Luminescence (OSL) to provide a reliable chronology essential for the management and planning of water resources. Nine charcoal ¹⁴C (AMS) dates constrain these OSL ages. Quartz extracted from seven OSL samples from each of the cores was measured using both single‐grain and multi‐grain OSL techniques. Three of the single‐grain natural dose distributions appear to be well bleached, but the others appear to be incompletely bleached to various degrees. Three minimum‐age models (MAM, MAM_UL and IEU) are applied to the single‐grain dose distributions. We conclude that these models give consistent age estimates. For one of the cores it appears to be necessary to use a minimum‐age model to obtain accurate ages, but in the other core incomplete bleaching is probably less important than postdepositional mixing and mixing during sampling. As a result, the burial age is probably best estimated using the weighted average of the individual single‐grain dose estimates. The application of multi‐grain OSL techniques to these samples results in an average apparent age overestimation of ～200 years, which is significant for these samples, but negligible for sediments older than a few thousand years. The intention is that the chronology obtained in this study will be used in conjunction with a proxy flood record, derived from floodplain sediments, to gain an understanding of the long‐term variability in periods of high and low rainfall in eastern Australia.     

Meso-scale variability of coastal suprabenthic communities in the southern Tyrrhenian Sea (western Mediterranean)

Meso-scale spatial variability of coastal suprabenthic communities inhabiting muddy bottoms at 50–80 m depth in three gulfs of northern Sicily (Western Mediterranean) was here investigated. Although similar as concerns the hydrological and oceanographic conditions, the three areas, that encompass a large portion of the continental shelf (135 km), are characterized by different geo-morphological features. In addition, they are subjected to different trawl fishery pressures. The Gulf of Castellammare is a semi-enclosed bay, where the trawling activity has been banned since 1990. The Gulf of Termini Imerese and the Gulf of Sant’Agata are open areas, subjected to high trawl fishing intensity. In terms of density, gammarid amphipods showed differences among the three gulfs; in terms of biomass, cumaceans and amphipods were more abundant in the Gulf of Castellammare than in the other two areas. Multivariate analyses provided evidence for separation of suprabenthic assemblages between the Gulf of Castellammare and the other two gulfs. The Gulf of Castellammare seemed to host the most diversified and stable community according to α- and β-diversity indices. In the same way the low value of δ¹³C vs. δ¹⁵N correlation found in the gulf of Castellammare, which evidences the occurrence of several food sources, supports the idea of a higher stability in the semi-enclosed, trawl-ban area. In the other two areas δ¹³C vs. δ¹⁵N correlations were high, suggesting the existence of a pelagic source sustaining the suprabenthic communities. This is also confirmed by the lower δ¹³C concentrations found in suprabenthic species. Taking into account the homogeneous oceanographic conditions among gulfs, other factors, such as geo-morphology and trawling pressure should be involved in the observed differences among the three areas in terms of assemblage structure, diversity, and trophodynamics of suprabenthic communities.     

Shallow fault segmentation of the Alpine fault zone,New Zealand revealed from 2- and 3-D GPR surveying

Where they are preserved, landforms that have been truncated and offset by past fault movements provide potentially valuable quantitative data that can be used to estimate slip rates. At such locations, it is important to investigate the fault zone in sufficient detail to understand how displacements are accommodated on individual fault strands. At a site along a northern section of the Alpine fault zone on the South Island of New Zealand, surface mapping of a series of faulted river terraces and channels has revealed a complicated and poorly understood paleoearthquake history. We have acquired high-resolution 2- and 3-D ground-penetrating radar (GPR) data over a large area (~ 500 × 500 m) of the terraces to map along-strike changes in shallow (<20 m) fault zone morphology. By identifying distinct reflection patterns within the topographically migrated 3-D GPR volumes and extrapolating them to the longer and more widely spaced GPR profiles, we determined the subsurface extent of two main structural/depositional facies that were juxtaposed by three left-stepping en-echelon fault strands. Two regions of warped strata are interpreted to result from transpressive folding between the overlapping strands, where displacement is transferred from one fault to the next. We suggest that diffuse deformation between the overlapping fault tips results in anomalously low estimates for horizontal and vertical fault displacements of some geomorphic features.     

Last glacial ice‐rafted debris off southwestern Europe: the role of the British–Irish Ice Sheet

Ice‐rafted debris (IRD) seeded into the ocean from Northern Hemisphere ice sheets is found in ocean cores along the southwestern European margin through the last glacial period. It is known that the origin of this IRD, especially off Iberia, can vary between North America and western Europe during short‐lived episodes of greatly enhanced iceberg flux, known as Heinrich events, although in most Heinrich events the IRD has a North American source. During the longer times of much lower IRD fluxes between Heinrich events, use of an intermediate complexity climate model, coupled to an iceberg dynamic and thermodynamic model, shows that background levels of IRD most likely originate from western Europe, particularly the British–Irish Ice Sheet. Combining modelling with palaeoceanographic evidence supports reconstructions of a short‐lived, but substantial, Celtic and Irish Sea Ice Stream around 23 ka. Copyright © 2010 John Wiley & Sons, Ltd.     

Bacterial accumulation by Branchiomma luctuosum (Annelida: Polychaeta): a tool for biomonitoring marine systems and restoring polluted waters

In this study, we examined the bacterial accumulation in the filter feeder polychaete Branchiomma luctuosumGrube (Sabellidae). Analyses were performed on worm homogenates from 'unstarved' and 'starved' individuals, and seawater from the same sampling site (Gulf of Taranto, Western Mediterranean, Italy). Densities of culturable heterotrophic bacteria (22 degrees C), total culturable bacteria at 37 degrees C and halophilic vibrios at 22 and 35 degrees C were measured on Marine Agar 2216, Plate Count Agar and thiosulphate-citrate-bile-salt-agar (TCBS) plus 2% NaCl, respectively. Total and faecal coliforms as well as faecal streptococci were determined by the Most Probable Number method. Results showed that B. luctuosum is able to accumulate all the considered six microbiological groups with a higher efficiency for autochthonous bacteria. The analysis also indicated that bacterial groups differ in their resistance to digestion by B. luctuosum. Our data suggest the potential role of B. luctuosum as an useful bioindicator to assess low levels of microbiological water pollution as well as bioremediator of microbial polluted waters.     

Platinum-group elements in ores from the Kalmakyr porphyry Cu–Au–Mo deposit, Uzbekistan: bulk geochemical and laser ablation ICP-MS data

We studied primary ore samples from Kalmakyr, a giant Cu–Au–Mo porphyry deposit in eastern Uzbekistan. Disseminated and stockwork-type high-grade Cu–Au–Mo mineralization showed average concentrations of 55 ppb Pd, 5.5 ppb Pt, 0.95 ppb Rh, 0.49 ppb Ir, and 4.1 ppm Au (n = 8). This type of mineralization is characterized by the presence of pyrite, chalcopyrite, molybdenite, and gold. A peak Pd content of 292 ppb was determined in a base-metal-rich quartz vein in granodiorite porphyry, which contains galena, sphalerite, chalcopyrite, tetrahedrite, and gold. Palladium correlates with Cu, Ag, Se, and S. Mineralogical and laser ablation ICP-MS study confirmed that Pd is homogeneously distributed in chalcopyrite, which contains up to 110 ppm Pd, and tetrahedrite, containing up to 20 ppm Pd. An assessment of the Pd and Pt budget at Kalmakyr showed the potential of approximately 17 t of Pd and 1.7 t of Pt.     

Hydrological responses to rainfall events including the extratropical cyclone Gloria in two contrasting Mediterranean headwaters in Spain; the perennial font del Regàs and the intermittent Fuirosos

Catchment hydrological responses to precipitation inputs, particularly during exceptionally large storms, are complex and variable, and our understanding of the associated runoff generation processes during those events is limited. Hydrological monitoring of climatically and hydrologically distinct catchments can help to improve this understanding by shedding light on the interplay between antecedent soil moisture conditions, hydrological connectivity, and rainfall event characteristics. This knowledge is urgently needed considering that both the frequency and magnitude of extreme precipitation events are increasing worldwide as a consequence of climate change. In autumn 2018, we installed water level sensors to monitor stream water and near-stream groundwater levels at two Mediterranean forest headwater catchments with contrasting hydrological regimes: Font del Regàs (sub-humid climate, perennial flow regime) and Fuirosos (semi-arid climate, intermittent flow regime). Both catchments are located in northeastern Spain, where the extratropical cyclone Gloria hit in January 2020 and left in ca. 65 h outstanding accumulated rainfalls of 424 mm in Font del Regàs and 230 mm in Fuirosos. During rainfall events of low mean intensity, hydrological responses to precipitation inputs at the semi-arid Fuirosos were more delayed and more variable than at the sub-humid Font del Regàs. We explain these divergences by differences in antecedent soil moisture conditions and associated differences in catchment hydrological connectivity between the two catchments, which in this case are likely driven by differences in local climate rather than by differences in local topography. In contrast, during events of moderate and high mean rainfall intensities, including the storm Gloria, precipitation inputs and hydrological responses correlated similarly in the two catchments. We explain this convergence by rapid development of hydrological connectivity independently of antecedent soil moisture conditions. The data set presented here is unique and contributes to our mechanistic understanding on how streams respond to rainfall events and exceptionally large storms in catchments with contrasting flow regimes.