Low-molecular weight hydrocarbons in vent fluids from the Main Endeavour Field, northern Juan de Fuca Ridge

Despite its location on sediment-free basalt, vent fluids from the Main Endeavour Field (MEF) contain chemical species that indicate fluids have interacted with sediments during circulation. We report on the distribution and isotopic abundances of organic compounds (C₁-C₃ alkanes and alkenes, benzene and toluene) in fluids collected from the Main Endeavour Field (MEF) in July, 2000, to understand the processes that regulate their abundances and characterize fluid sources. Aqueous organic compounds are derived from the thermal alteration of sedimentary organic matter and subsequently undergo further oxidation reactions during fluid flow. Fluid:sediment mass ratios calculated using ΣNH₄ concentrations indicate that the sediments are distal to the MEF, resulting in a common reservoir of fluids for all of the vents. Following the generation from sediment alteration, aqueous organic compounds undergo secondary alteration reactions via a stepwise oxidation reaction mechanism. Alkane distributions and isotopic compositions indicate that organic compounds in MEF fluids have undergone a greater extent of alteration as compared to Middle Valley fluids, either due to differences in subsurface redox conditions or the residence time of fluids at subsurface conditions. The distributions of the aromatic compounds benzene and toluene are qualitatively consistent with the subsurface conditions indicated by equilibration of aqueous alkanes and alkanes. However, benzene and toluene do not achieve chemical equilibrium in the subsurface. Methane and CO₂ also do not equilibrate chemically or isotopically at reaction zone temperatures, a likely result of an insufficient reaction time after addition of CO₂ from magmatic sources during upflow. The organic geochemistry supports the assumption that the sediments with which MEF fluids interact has the same composition as sediments present in Middle Valley itself, and highlight differences in subsurface reaction zone conditions and fluid flow pathways at these two sites.     

Methane and sulfide fluxes in permanent anoxia: In situ studies at the Dvurechenskii mud volcano (Sorokin Trough, Black Sea)

The Dvurechenskii mud volcano (DMV) is located in permanently anoxic waters at 2060 m depth (Sorokin Trough, Black Sea). The DMV was studied during the RV Meteor expedition M72/2 as an example of an active mud volcano system, to investigate the significance of submarine mud volcanism for the methane and sulfide budget of the anoxic Black Sea hydrosphere. Our studies included benthic fluxes of methane and sulfide, as well as the factors controlling transport, consumption and production of both compounds within the sediment. The pie-shaped mud volcano showed temperature anomalies as well as solute and gas fluxes indicating high fluid flow at its summit north of the geographical center. The anaerobic oxidation of methane (AOM) coupled to sulfate reduction (SR) was repressed in this zone due to the upward flow of sulfate-depleted fluids through recently deposited subsurface muds, apparently limiting microbial methanotrophic activity. Consequently, the emission of dissolved methane into the water column was high, with an estimated rate of 0.46 mol m⁻² d⁻¹. On the wide plateau and edge of the mud volcano surrounding the summit, fluid flow and total methane flux were lower, allowing higher SR and AOM rates correlated with an increase in sulfate penetration into the sediment. Here, between 50% and 70% of the methane flux (0.07-0.1 mol m⁻² d⁻¹) was consumed within the upper 10 cm of the sediment. The overall amount of dissolved methane released from the entire mud volcano structure into the water column was significant with a discharge of 1.3 × 10⁷ mol yr⁻¹. The DMV maintains also high areal rates of methane-fueled sulfide production and emission of on average 0.05 mol m⁻² d⁻¹. This is a difference to mud volcanoes in oxic waters, which emit similar amounts of methane, but not sulfide. However, based on a comparison of this and other mud volcanoes of the Black Sea, we conclude that sulfide and methane emission into the hydrosphere from deep-water mud volcanoes does not significantly contribute to the sulfide and methane inventory of the Black Sea.     

Comparative studies on compounds occluded inside asphaltenes hierarchically released by increasing amounts of H2O2/CH3COOH

Being the heaviest fraction of crude oils, asphaltenes are liable to aggregate, and other molecules in the oils can be steadily adsorbed onto, and even occluded inside the macromolecular structures of the asphaltenes. These occluded compounds inside the asphaltenes can survive over geological time in oil reservoirs owing to effective protection by the macromolecular structures of the asphaltenes. The asphaltenes of a crude oil (ZG31) from the central Tarim Basin, NW China, were hierarchically degraded by increasing the amount of H₂O₂/CH₃COOH to release the occluded compounds. Besides the common components, series of even numbered n-alk-1-enes and 3-ethylalkanes were detected among the occluded compounds. Comparison of the biomarker distributions and the compound-specific C isotopic results between the compounds from the maltenes and those from the occluded fraction, the ZG31 reservoir was suggested to have been charged multiple times, with different charges being derived from different strata of source rocks.     

Links Between Bottom-Water Anoxia,the Polychaete <Emphasis Type="Italic">Nereis diversicolor</Emphasis>, and the Growth of Green-Algal Mats

Sediment–water incubations were used to study effects of episodic anoxia on filamentous Ulva sp. Treatments included undisturbed sediment with (AnoxSed) and without (NatSed) exposure to 5 days of anoxia, and cores with only the top 0.5 cm of sediment (SurfSed; no macrofauna, restricted pore-water nutrient pool). All three treatments contained Ulva propagules. An Ulva mat developed in the SurfSed, and after the anoxic period in the AnoxSed cores. No growth was observed in the NatSed treatment. In the AnoxSed, Ulva was progressively removed upon reoxygenation through grazing by Nereis. The results suggest that episodic anoxia stimulates the growth of macroalgal mats not only by increasing the availability of nutrients from the sediment, but also by reducing macrofaunal grazing pressure. Infauna (grazing and bioturbation), benthic microalgae (nutrient competition and retention), and pore-water nutrients appear key components in a biogeochemical network with complex feedbacks controlling the growth of green-algal mats in shallow-water systems.     

A Plan to Push Limits? Investigating the ecologically sustainable development dimensions of Melbourne's Central Region sustainable water strategy

Drawing upon theory from the field of urban political ecology, we analyse a major strategic water plan for Melbourne, Australia—the Sustainable water strategy for the Central Region, published in 2006. We assess the extent to which the strategy identified and addressed ecological sustainability in terms of: cultural frames; ecological context; social equity; and engagement processes. We identify that the strategy's framing of water was largely separate from its social and ecological context. This framing resulted in the importance of issues such as environmental flows, social equity and cultural values being diminished, thus avoiding the inevitable confrontation with environmental limits needed to ensure long-term ecological sustainability. Our analysis shows that the discursive dominance of economics limited the response to persuasive scientific arguments for greater ecological consideration in the strategy. Our findings suggest that broadening engagement with the diverse ways in which water is valued is likely to contribute to more equitable and ecologically sustainable water futures.     

Geochronology and paleoenvironment of pluvial Harper Lake,Mojave Desert,California, USA

Accurate reconstruction of the paleo-Mojave River and pluvial lake (Harper, Manix, Cronese, and Mojave) system of southern California is critical to understanding paleoclimate and the North American polar jet stream position over the last 500 ka. Previous studies inferred a polar jet stream south of 35°N at 18 ka and at ~ 40°N at 17–14 ka. Highstand sediments of Harper Lake, the upstream-most pluvial lake along the Mojave River, have yielded uncalibrated radiocarbon ages ranging from 24,000 to > 30,000 ¹⁴C yr BP. Based on geologic mapping, radiocarbon and optically stimulated luminescence dating, we infer a ~ 45–40 ka age for the Harper Lake highstand sediments. Combining the Harper Lake highstand with other Great Basin pluvial lake/spring and marine climate records, we infer that the North American polar jet stream was south of 35°N about 45–40 ka, but shifted to 40°N by ~ 35 ka. Ostracodes (Limnocythere ceriotuberosa) from Harper Lake highstand sediments are consistent with an alkaline lake environment that received seasonal inflow from the Mojave River, thus confirming the lake was fed by the Mojave River. The ~ 45–40 ka highstand at Harper Lake coincides with a shallowing interval at downstream Lake Manix.     

Multi-risk governance for natural hazards in Naples and Guadeloupe

Technical and institutional capacities are strongly related and must be jointly developed to guarantee effective natural risk governance. Indeed, the available technical solutions and decision support tools influence the development of institutional frameworks and disaster policies. This paper analyses technical and institutional capacities, by providing a comparative evaluation of governance systems in Italy and France. The focus is on two case studies: Naples and Guadeloupe. Both areas are exposed to multiple hazards, including earthquakes, volcanic eruptions, landslides, floods, tsunamis, fires, cyclones, and marine inundations Cascade and conjoint effects such as seismic swarms triggered by volcanic activity have also been taken into account. The research design is based on a documentary analysis of laws and policy documents informed by semi-structured interviews and focus groups with stakeholders at the local level. This leads to the identification of three sets of governance characteristics that cover the key issues of: (1) stakeholders and governance level; (2) decision support tools and mitigation measures; and (3) stakeholder cooperation and communication. The results provide an overview of the similarities and differences as well as the strengths and weaknesses of the governance systems across risks. Both case studies have developed adequate decision support tools for most of the hazards of concern. Warning systems, and the assessment of hazards and exposure are the main strengths. While technical/scientific capacities are very well developed, the main weaknesses involve the interagency communication and cooperation, and the use and dissemination of scientific knowledge when developing policies and practices. The consequences for multi-risk governance are outlined in the discussion.     

Lessons learned from two case histories of seismic microzonation in Italy

The prediction of the variability of the seismic ground motion in a given built-up area is considered an effective tool to plan appropriate urban development, to undertake actions on seismic risk mitigation and to understand the damage pattern caused by a strong-motion event. The procedures for studying the seismic response and the seismic microzonation of an urban area are well established; nevertheless, some controversial points still exists and are discussed here. In this paper, the selection of a reference input motion, the construction of a subsoil model and the seismic response analysis procedures are discussed in detail, based on the authors’ experience in two Italian case histories: the seismic microzonation of the city of Benevento, which was a predictive study, and the simulation of seismic response and damage distribution in the village of San Giuliano di Puglia, which was a retrospective analysis.     

Neutron star retention and millisecond pulsar production in globular clusters

We investigate the conditions by which neutron star retention in globular clusters is favoured. We find that neutron stars formed in massive binaries are far more likely to be retained. Such binaries are likely to then evolve into contact before encountering other stars, possibly producing a single neutron star after a common envelope phase. A large fraction of the single neutron stars in globular clusters are then likely to exchange into binaries containing moderate-mass main-sequence stars, replacing the lower-mass components of the original systems. These binaries will become intermediate-mass X-ray binaries (IMXBs), once the moderate-mass star evolves off the main sequence, as mass is transferred on to the neutron star, possibly spinning it up in the process. Such systems may be responsible for the population of millisecond pulsars (MSPs) that has been observed in globular clusters. Additionally, the period of mass-transfer (and thus X-ray visibility) in the vast majority of such systems will have occurred 5–10 Gyr ago, thus explaining the observed relative paucity of X-ray binaries today, given the MSP population.