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231.
Distinguishing Iron-Reducing from Sulfate-Reducing Conditions 总被引:2,自引:0,他引:2
by Francis H. Chapelle Paul M. Bradley Mary Ann Thomas and Peter B. McMahon 《Ground water》2009,47(2):300-305
Ground water systems dominated by iron‐ or sulfate‐reducing conditions may be distinguished by observing concentrations of dissolved iron (Fe2+) and sulfide (sum of H2S, HS?, and S= species and denoted here as “H2S”). This approach is based on the observation that concentrations of Fe2+ and H2S in ground water systems tend to be inversely related according to a hyperbolic function. That is, when Fe2+ concentrations are high, H2S concentrations tend to be low and vice versa. This relation partly reflects the rapid reaction kinetics of Fe2+ with H2S to produce relatively insoluble ferrous sulfides (FeS). This relation also reflects competition for organic substrates between the iron‐ and the sulfate‐reducing microorganisms that catalyze the production of Fe2+ and H2S. These solubility and microbial constraints operate in tandem, resulting in the observed hyperbolic relation between Fe2+ and H2S concentrations. Concentrations of redox indicators, including dissolved hydrogen (H2) measured in a shallow aquifer in Hanahan, South Carolina, suggest that if the Fe2+/H2S mass ratio (units of mg/L) exceeded 10, the screened interval being tapped was consistently iron reducing (H2~0.2 to 0.8 nM). Conversely, if the Fe2+/H2S ratio was less than 0.30, consistent sulfate‐reducing (H2~1 to 5 nM) conditions were observed over time. Concomitantly high Fe2+ and H2S concentrations were associated with H2 concentrations that varied between 0.2 and 5.0 nM over time, suggesting mixing of water from adjacent iron‐ and sulfate‐reducing zones or concomitant iron and sulfate reduction under nonelectron donor–limited conditions. These observations suggest that Fe2+/H2S mass ratios may provide useful information concerning the occurrence and distribution of iron and sulfate reduction in ground water systems. 相似文献
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233.
螺旋藻(Spirulina)对慢性肝损伤小鼠肝组织抗氧化能力的影响 总被引:3,自引:0,他引:3
用四氯化碳导致小鼠肝损伤,各组每日灌胃不同剂量螺旋藻,检测了饲养45d的小鼠血清的ALT活力、肝组织的SOD活力和MDA含量,分别建立ALT、SOD活力以及MDA含量随剂量(C)变化的函数,求出各项临界参数值,并对参数的生物学意义进行解释,以观察螺旋藻对肝损伤小鼠肝组织中SOD活力和MDA的影响.实验结果显示:螺旋藻能提高小鼠SOD的活力并降低其MDA含量,进一步验证了螺旋藻可提高肝损伤小鼠肝组织的抗氧化能力,分析结果还显示螺旋藻对肝组织抗氧化能力的提高既具有一定的量效累积性,也存在量效局限性. 相似文献
234.
Heterogeneous water storage and thermal regime of supraglacial ponds on debris‐covered glaciers
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Cameron Scott Watson Duncan J. Quincey Jonathan L. Carrivick Mark W. Smith Ann V. Rowan Robert Richardson 《地球表面变化过程与地形》2018,43(1):229-241
The water storage and energy transfer roles of supraglacial ponds are poorly constrained, yet they are thought to be important components of debris‐covered glacier ablation budgets. We used an unmanned surface vessel (USV) to collect sonar depth measurements for 24 ponds to derive the first empirical relationship between their area and volume applicable to the size distribution of ponds commonly encountered on debris‐covered glaciers. Additionally, we instrumented nine ponds with thermistors and three with pressure transducers, characterizing their thermal regime and capturing three pond drainage events. The deepest and most irregularly‐shaped ponds were those associated with ice cliffs, which were connected to the surface or englacial hydrology network (maximum depth = 45.6 m), whereas hydrologically‐isolated ponds without ice cliffs were both more circular and shallower (maximum depth = 9.9 m). The englacial drainage of three ponds had the potential to melt ~100 ± 20 × 103 kg to ~470 ± 90 × 103 kg of glacier ice owing to the large volumes of stored water. Our observations of seasonal pond growth and drainage with their associated calculations of stored thermal energy have implications for glacier ice flow, the progressive enlargement and sudden collapse of englacial conduits, and the location of glacier ablation hot‐spots where ponds and ice cliffs interact. Additionally, the evolutionary trajectory of these ponds controls large proglacial lake formation in deglaciating environments. Copyright © 2017 John Wiley & Sons, Ltd. 相似文献
235.
Ann Pomeroy 《New Zealand geographer》2019,75(3):204-215
A review of social research on rural New Zealand undertaken as part of the National Science Challenge (NSC 11) “Building Better Homes, Towns and Cities” allows a fresh look at rural development within the context of New Zealand's colonial history. The research suggests that government development programmes and legislation privileged those responsible for producing the bulk of New Zealand's export income. Cultural attitudes, structural inequalities and a failure to understand how the character of, and social relations in, rural areas have changed has impeded particularly Māori economic growth, the participation of women, and non‐farm sectors of rural society, to the detriment of all. 相似文献
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237.
The effects of phase fractionation on the composition of oils, condensates and gases 总被引:1,自引:0,他引:1
The effects of phase fractionation on the composition of oils, condensates and gases have been studied in the laboratory by a differential evaporation experiment. The experiment was designed to simulate the behaviour of a single-charge petroleum during (upward) migration or in a reservoir undergoing uplift, scenarios thought to be typical for the Norwegian continental shelf. After each pressure reduction step, samples from all phases (oil, condensate, free and associated gas) were collected and analysed. The results show that, in general, small molecules are preferentially enriched in the gas phase, both at elevated pressure and temperature and under standard conditions (15°C, 1 bar). The solvent power of the gas phase for large molecules is drastically reduced at lower pressures (here below approx. 300 bar). Carbon isotope ratios of individual compound are not affected, while variations in isotope ratios of fractions can be explained by changes in the fraction compositions. Individual geochemical parameters behave as can be expected based on the molecular size and structure of the compounds involved. However, a generally valid, quantitative prediction of how geochemical parameters vary as a result of phase fractionation is very difficult, as this will depend not only on the pressure and temperature of fractionation, but also on the composition and amounts of the oil and gas that are involved. The observations from this study confirm the importance of phase fractionation as an important process to consider when interpreting geochemical data for both condensates and oils. 相似文献
238.
Erik E. Cordes Marina R. Cunha Joëlle Galéron Camilo Mora Karine Olu-Le Roy Myriam Sibuet Saskia Van Gaever Ann Vanreusel & Lisa A. Levin 《Marine Ecology》2010,31(1):51-65
Cold seeps are among the most heterogeneous of all continental margin habitats. Abiotic sources of heterogeneity in these systems include local variability in fluid flow, geochemistry, and substrate type, which give rise to different sets of microbial communities, microbial symbiont-bearing foundation species, and associated heterotrophic species. Biogenic habitats created by microbial mats and the symbiotic species including vesicomyid clams, bathymodiolin mussels, and siboglinid tubeworms add an additional layer of complexity to seep habitats. These forms of habitat heterogeneity result in a variety of macrofaunal and meiofaunal communities that respond to changes in structural complexity, habitat geochemistry, nutrient sources, and interspecific interactions in different ways and at different scales. These responses are predicted by a set of theoretical metacommunity models, the most appropriate of which for seep systems appears to be the 'species sorting' concept, an extension of niche theory. This concept is demonstrated through predictable patterns of community assembly, succession, and beta-level diversity. These processes are described using a newly developed analytical technique examining the change in the slope of the species accumulation curve with the number of habitats examined. The diversity response to heterogeneity has a consistent form, but quantitatively changes at different seep sites around the world as the types of habitats present and the size-classes of fauna analyzed change. The increase in beta diversity across seep habitat types demonstrates that cold seeps and associated biogenic habitats are significant sources of heterogeneity on continental margins globally. 相似文献
239.
Meiobenthos assemblages in eight estuaries of the Mekong river system were investigated in August 2008 (from the Cua Tieu estuary to the Tran De estuary). In each estuary, one sampling station was established for meiobenthos sampling. Twelve major taxa of meiobenthos were recorded in this estuarine system, including Nematoda, Copepoda, Turbellaria, Polychaeta, Oligochaeta, Tardigrada, Bivalvia, Ostracoda, Amphipoda, Cumacea, Gastrotricha, Gastropoda, and Crustacean Nauplii larvae. The densities of the meiobenthos range from 581 to 3168 inds/10 cm2. Nematodes always occupy the highest numbers with a percentage ranging from 64–99%. There are 135 nematode genera recorded in this study with the following as dominant genera Desmodora, Leptolaimus, Halalaimus, Thalassomonhystera, Theristus, Daptonema, Rhynchonema, Parodontophora, and Oncholaimus. Although the biodiversity of the meiobenthos at higher taxa level is not high compared to other marine environments, the estimates of nematode biodiversity at the genus level indicates high values. The increase in number of genera with increasing sampling intensity illustrate that the diversity is underestimated and would have been higher if the authors had considered a larger number of individuals, more replicates per station, and more sampling stations. 相似文献
240.
Ann E. Jochens Steven F. DiMarco 《Deep Sea Research Part II: Topical Studies in Oceanography》2008,55(24-26):2541
The circulation and distribution of water properties in the water column of the Gulf of Mexico influence the flux of carbon to the benthic environment. The eddy field of the upper 1000 m creates environmental conditions that are favorable for biological productivity in an otherwise oligotrophic subtropical ocean. This eddy field results in the transport of nutrients and organic matter into the photic zone through cross-margin flow of shelf waters, upwelling in cyclones, and uplift from the interaction of anticyclones with bathymetry. These conditions then allow the productivity that becomes a possible source of carbon to the benthos.Data from four cruises during summers of 2000–2002 are used to describe the currents and water property distributions in the deepwater Gulf of Mexico, which consists of water depths greater than 400 m. Comparisons are made to historical data sets to provide an understanding of the persistence of the characteristics of the Gulf and the processes that occur there.The currents in the Gulf are surface intensified, have minimum in 800–1000 m depths, and also exhibit bottom intensification, especially near sloping topography. Historical time series records show current speeds near-bottom reach 50–100 cm s−1. At basin scales, these currents tend to flow cyclonically (counter-clockwise) along the bathymetry. These near-bottom, episodic, high-speed currents provide a mechanism for the transport of organic material, in both large and small particle sizes, from one benthic area to another.The distributions of temperature, salinity, nutrients, and dissolved oxygen during the study appear to be unchanged from historical findings. The source waters for the deep Gulf are the water masses brought into the Gulf by the Loop Current system. The properties in the upper 100–200 m are the most variable of the water column, consistent with their proximity to wind mixing, river discharge mixing, and atmospheric influences. Below 1500 m, there are no major horizontal variations in these water properties. 相似文献