Petrological, organic geochemical and geochemical characteristics of coal from the Soko mine, Serbia

A petrological, organic geochemical and geochemical study was performed on coal samples from the Soko Mine, Soko Banja basin, Serbia. Ten coal and two carbonaceous clay samples were collected from fresh, working faces in the underground brown coal mine from different parts of the main coal seam. The Lower Miocene, low-rank coal of the Soko Mine is a typical humic coal with huminite concentrations of up to 76.2 vol.%, liptinite less than 14 vol.% and inertinite less than 11 vol.%. Ulminite is the most abundant maceral with variable amounts of densinite and clay minerals. Sporinite and resinite are the most common macerals of the liptinite group. Inertodetrinite is the most abundant maceral of the inertinite group. The mineral-bituminous groundmass identified in some coal samples, and carbonaceous marly clay, indicate sub-aquatic origin and strong bacterial decomposition. The mean random huminite reflectance (ulminite B) for the main coal seam is 0.40 ± 0.05% Rr, which is typical for an immature to early mature stage of organic matter.The extract yields from the coal of the Soko Banja basin ranges from 9413 to 14,096 ppm, in which alkanes constituted 1.0–20.1%, aromatics 1.3–14.7%, asphaltenes 28.1–76.2% and resins 20.2–43.5%. The saturated hydrocarbon fractions included n-C₁₅ to n-C₃₂, with an odd carbon number that predominate in almost all the samples. The contents of n-C₂₇ and n-C₂₉ alkanes are extremely high in some samples, as a contribution of epicuticular waxes from higher plants. Acyclic isoprenoid hydrocarbons are minor constituents in the aliphatic fraction, and the pristane/phytane (Pr/Ph) ratio varies between 0.56 and 3.13, which implies anaerobic to oxic conditions during sedimentation. The most abundant diterpanes were abietane, dehydroabietane and 16α(H)-phyllocladane. In samples from the upper part of the coal seam, diterpanes are the dominant constituents of the alkane fraction. Polycyclic alkanes of the triterpane type are important constituents of alkane fractions. The occurrence of ββ- and αβ-type hopanes from C₂₇ to C₃₁, but without C₂₈, is typical for the Soko Banja coals.The major and trace elements in the coal were analysed using X-ray fluorescence (XRF), and inductively coupled plasma-mass spectrometry (ICP-MS). In comparison with world lignites, using the geometric mean value, the coal from the Soko Banja Basin has a high content of strontium (306.953 mg/kg). Higher values than the world lignites were obtained for Mo (3.614 mg/kg), Ni (8.119 mg/kg), Se (0.884 mg/kg), U (2.642 mg/kg) and W (0.148 mg/kg). Correlation analysis shows inorganic affinity for almost all the major and trace elements, except for S, which has an organic affinity.     

Extending Service Life of Household Water Filters by Mixing Metallic Iron with Sand

The use of metallic iron filters (Fe⁰ filters) has been discussed as a promising low‐cost option for safe drinking water production at household level. Filter clogging due to the volumetric expansive nature of iron corrosion has been identified as the major problem of Fe⁰ filters. Mixing Fe⁰ and sand (yielding Fe⁰/sand filters) has been proposed as a tool to extent filter service life. However, no systematic discussion rationalizing Fe⁰/sand mixtures is yet available. This communication theoretically discussed suitable Fe⁰/sand proportions for efficient filters. Results suggested that Fe⁰/sand filters should not contain more that 50 vol% Fe⁰ (25 wt% when Fe⁰ is mixed with quartz). The actual Fe⁰ percentage in a filter will depend on its intrinsic reactivity.     

Aluminous websterite and granulite xenoliths from the Chyulu Hills volcanic field, Kenya: gabbro–troctolitic cumulates subjected to lithospheric foundering

Whole rock major and trace element abundances in aluminous garnet–spinel websterite, sapphirine-bearing Mg–Al granulite and hibonite-bearing Ca–Al granulite xenoliths from the Chyulu Hills volcanic field, Kenya, suggest that the samples represent a meta-igneous suite linked by fractionation. The incompatible major element contents increase from the websterites to the Mg–Al granulites and further to the Ca–Al granulites. High bulk rock Mg#s and very low concentrations of most incompatible trace elements indicate that the rocks are cumulates rather than crystallized melts. Elevated Ni abundances, impoverishment in Cr and HFSE and high contents of normative plagioclase and olivine in the granulites indicate that their protoliths were similar to troctolite. The textures and metamorphic reaction paths recorded in the granulites suggest igneous emplacement in the crust and cooling from igneous to ambient crustal temperatures accompanied or followed by compression. For the websterite xenoliths, there is an apparent contradiction between the results of P–T calculations that suggest high P and T of crystallization of early generation pyroxenes and elevated P–T conditions during final equilibration (1.4–2.2 GPa/740–980°C) on the one hand and the positive Eu anomaly that suggests shallow-level plagioclase accumulation on the other hand. This contradiction can be reconciled by a model of compression of a plagioclase-bearing (gabbroic) protolith to mantle depths where it recrystallized to an ultramafic assemblage, which requires foundering of dense lower crustal material into the mantle.     

Aluminous granulites from the Pulur complex, NE Turkey: a case of partial melting, efficient melt extraction and crystallisation

In the Pulur complex, NE Turkey, a heterogeneous rock sequence ranging from quartz-rich mesocratic gneisses to silica- and alkali-deficient, Fe-, Mg- and Al-rich melanocratic rocks is characterized by granulite-facies assemblages involving garnet, cordierite, sillimanite, ilmenite, ±spinel, ±plagioclase, ±quartz, ±biotite, ±corundum, rutile and monazite. Textural evidence for partial melting in the aluminous granulites, particularly leucosomes, is largely absent or strongly obliterated by a late-stage hydrothermal overprint. However, inclusion relations, high peak P–T conditions, the refractory modes, bulk and biotite compositions of the melanocratic rocks strongly support a model of partial melting. The melt was almost completely removed from the melanocratic rocks and crystallised within the adjacent mesocratic gneisses which are silica-rich, bear evidence of former feldspar and show a large range in major element concentrations as well as a negative correlation of most elements with SiO₂. Peak conditions are estimated to be ≥800 °C and 0.7–0.8 GPa. Subsequent near-isothermal decompression to 0.4–0.5 GPa at 800–730 °C is suggested by the formation of cordierite coronas and cordierite–spinel symplectites around garnet and in the matrix. Sm–Nd, Rb–Sr and ⁴⁰Ar/³⁹Ar isotope data indicate peak conditions at 330 Ma and cooling below 300 °C at 310 Ma.     

Detrital,metamorphic and metasomatic tourmaline in high-pressure metasediments from Syros (Greece): intra-grain boron isotope patterns determined by secondary-ion mass spectrometry

The boron isotopic composition of zoned tourmaline in two metasediments from the island of Syros, determined by secondary-ion mass spectrometry (SIMS), reflects the sedimentary and metamorphic record of the rocks. Tourmaline from a silicate-bearing marble contains small (≤20 μm) detrital cores with highly variable δ ¹¹B values (−10.7 to +3.6‰), pointing to a heterogeneous protolith derived from multiple sources. The sedimentary B isotopic record survived the entire metamorphic cycle with peak temperatures of ∼500°C. Prograde to peak metamorphic rims are homogeneous and similar among all analysed grains (δ ¹¹B ≈ +0.9‰). The varying δ ¹¹B values of detrital cores in the siliceous marble demonstrate that in situ B isotope analysis of tourmaline by SIMS is a potentially powerful tool for provenance studies not only in sediments but also in metasediments. A meta-tuffitic blueschist bears abundant tourmaline with dravitic cores of detrital or authigenic origin (δ ¹¹B ≈ −3.3‰), and prograde to peak metamorphic overgrowth zones (−1.6‰). Fe-rich rims, formed during influx of B-bearing fluids under retrograde conditions, show strongly increasing δ ¹¹B values (up to +7.7‰) towards the margins of the grains. The δ ¹¹B values of metamorphic tourmaline from Syros, formed in mixed terrigenous–marine sediments, reflect the B signal blended from these two different sources, and was probably not altered by dehydration during subduction.     

Towards a typology of urban centers and subcenters – evidence from German city regions

This study aims to characterize urban spatial structure with respect to its multidimensionality. Using an encompassing data set of socioeconomic variables, as well as variables pertaining to the built environment, accessibility and land use, we suggest a quantitatively based urban (sub-) center typology. The fine-grained spatial scale of 1 km² grid cells permits a higher spatial resolution than that used in most previous studies. Our suggested typology is two-layered: a “macro layer” based on cluster analyses sheds light on urban spatial configurations. A corresponding threshold-based “micro layer” identifies distinctive types of centers and subcenters at the local level. The application of this multi-scale and multivariate typology to four German city regions indicates both the core cities’ morphological dominance and the formation of subcenters with distinct profiles of regional economic importance, land use patterns and urban form. However, a substantial degree of spatial dispersion is observed because much activity is located in non-central locations.     

The need for data: natural disasters and the challenges of database management

Hundreds of natural catastrophes occur worldwide every year—there were 780 loss events per year on average over the last 10 years. Since 1980, these disasters have claimed over two million lives and caused losses worth US$ 3,000 billion. The deadliest disasters were caused by earthquakes: the tsunami following the Sumatra quake (2004) and the Haiti earthquake (2010) claimed more than 220,000 lives each. The Great East Japan Earthquake of 11 March 2011 was the costliest natural disaster of all times, with total losses of US$ 210 billion. Hurricane Katrina, in 2005, was the second costliest disaster, with total losses of US$ 140 billion (in 2010 values). To ensure that high-quality natural disaster analyses can be performed, the data have to be collected, checked and managed with a high degree of expertise and professionality. Scientists, governmental and non-governmental organisations and the finance industry make use of global databases that contain losses attributable to natural catastrophes. At present, there are three global and multi-peril loss databases: NatCatSERVICE (Munich Re), Sigma (Swiss Re) and EM-Dat (Centre for Research on the Epidemiology of Disasters). They are supplemented by numerous databases focusing on national or regional issues, certain hazards and specific sectors. This paper outlines the criteria and definitions relating to how global and multi-peril databases are operated, and the efforts being made to ensure consistent and internationally recognised standards of data management. In addition, it presents the concept and methodology underlying the NatCatSERVICE database, and points out the many challenges associated with data acquisition and data management.