Magnetic properties and Archeointensity of Earth’s magnetic field recovered from El Opeño,earliest funeral architecture known in Western Mesoamerica

Despite of the impressive cultural heritage and abundant archaeological sites, absolute geomagnetic intensity data from Mesoamerica are still sparse. Archeointensity determinations using the Coe variant of the Thellier and Thellier method have been carried out on some selected pottery fragments from the El Opeño archeological site which has the earliest funeral architecture known in western Mesoamerica. The El Opeño chronology is supported by six C¹⁴ datings performed on carbon-bearing materials. Detailed rock magnetic experiments including susceptibility vs. temperature curves, hysteresis cycles and thermal demagnetization procedures were carried out in order to estimate the magnetic carriers and their stability. Cooling rate and anisotropy remanence corrected intensity values range from 25.0 ± 2.3 to 40.2 ± 3.0 μT and corresponding virtual axial dipole moments (VADM) range from 5.6 ± 0.5 to 8.9 ± 0.7 × 10²² Am². In addition, we present here a new compilation and analysis of existing absolute intensity data in order to try to estimate the variation of the Earth’s magnetic field over the past three millennia. The mean archeointensity obtained in the present study agrees reasonably well with the predicted absolute intensities retrieved from the CALS7K main field model. Other available Mesoamerican data, however, differ from this model. Most of available archeointensity data from Mesoamerica agree reasonably well with the ARCH3K main field model prediction. The broad peak defined at about 50 A.D. by our data is also predicted by the CALS3k.3 main field model but slightly displaced to the right while two smaller peaks are observed on the ARCH3K curve for the same time interval. The intensity value obtained at about 200 B.C. is a clear outlier and thus its geomagnetic significance should be confirmed by further investigations.     

Plankton carbon metabolism and air–water CO2 fluxes at a hypereutrophic tropical estuary

Multiple biotic and abiotic drivers regulate the balance between CO₂ assimilation and release in surface waters. In the present study, we compared in situ measurements of plankton carbon metabolism (primary production and respiration) to calculated air–water CO₂ fluxes (based on abiotic parameters) during 1 year (2008) in a hypereutrophic tropical estuary (Recife Harbor, NE Brazil – 08°03′S, 34°52′W) to test the hypothesis that high productivity leads to a net CO₂ flux from the atmosphere. The calculated CO₂ fluxes through the air–water interface (FCO₂) were negative throughout the year (FCO₂: –2 to –9 mmol C·m^?2·day^?1), indicating that Recife Harbor is an atmospheric CO₂ sink. Respiration rates of the plankton community ranged from 2 to 45 mmol C·m^?2·hr^?1. Gross primary production ranged from 0.2 to 281 mmol C·m^?2·hr^?1, exceeding respiration during most of the year (net autotrophy), except for the end of the wet season, when the water column was net heterotrophic. The present results highlight the importance of including eutrophic tropical shallow estuaries in global air–water CO₂ flux studies, in order to better understand their role as a sink of atmospheric CO₂.     

Assessment of the distribution of sponge chips in the sediment of East Pacific Ocean reefs

Sponges are one of the principal agents of bioerosion and sediment production in coral reefs. They generate small carbonate chips that can be found in the sediments, and we investigated whether these could provide a means for assessment of bioerosion applicable to reef monitoring. We tested this hypothesis on samples from 12 Mexican coral reefs distributed along the Pacific coast, where boring sponges were particularly abundant, and quantified the amount of chips in samples of superficial sediment in three grain‐size fractions: fine (<44 μm), medium (44–210 μm) and coarse (>210 μm). The grain‐size distribution varied among reefs, with the majority of the sediment of most reefs being composed of coarse sands, and the medium and fine fractions dominating only at La Entrega and Playa Blanca. All the reefs presented clear evidence of bioerosion by sponges, with the characteristic chips present in the sediment, although at most sites the percentage of chips was very low (from 1% to 3% of the total sediment). Only at La Entrega and Playa Blanca did they constitute a significant fraction of the total sediment (18% and 16%, respectively). While not statistically significant, there was an interesting trend between sponge chips versus sponge abundance that suggests that quantification of the chips in the sediment could be used as a proxy for sponge erosion of the entire community, which cannot be estimated in by laboratory experiments. However, while this methodology could provide an integrated approach to monitor sponge bioerosion, more studies are necessary due to the influence of environmental factors on the transport and deposition of these chips.     

A depositional model for offshore deposits of the lower Blue Gate Member,Mancos Shale,Uinta Basin,Utah, USA

Depositional models that use heterogeneity in mud‐dominated successions to distinguish and diagnose environments within the offshore realm are still in their infancy, despite significant recent advances in understanding the complex and dynamic processes of mud deposition. Six cored intervals of the main body of the Mancos Shale, the lower Blue Gate Member, Uinta Basin, were examined sedimentologically, stratigraphically and geochemically in order to evaluate facies heterogeneity and depositional mechanisms. Unique sedimentological and geochemical features are used to identify three offshore environments of deposition: the prodelta, the mudbelt and the sediment‐starved shelf. Prodelta deposits consist of interlaminated siltstone and sandstone and exhibit variable and stressed trace fossil assemblages, and indicators of high sedimentation rates. The prodelta was dominated by river‐fed hyperpycnal flow. Mudbelt deposits consist of interlaminated siltstone and sandstone and are characterized by higher bioturbation indices and more diverse trace fossil assemblages. Ripples, scours, truncations and normally graded laminations are abundant in prodelta and mudbelt deposits indicating dynamic current conditions. Mudbelt sediment dispersal was achieved by both combined flow above storm wave base and current‐enhanced and wave‐enhanced sediment gravity flows below storm wave base. Sediment‐starved shelf deposits are dominantly siltstone to claystone with the highest calcite and organic content. Bioturbation is limited to absent. Sediment‐starved shelf deposits were the result of a combination of shelfal currents and hypopycnal settling of sediment. Despite representing the smallest volume, sediment‐starved shelf deposits are the most prospective for shale hydrocarbon resource development, due to elevated organic and carbonate content. Sediment‐starved shelf deposits are found in either retrogradational to aggradational parasequence sets or early distal aggradational to progradational parasequence sets, bounding the maximum flooding surface. An improved framework classification of offshore mudstone depositional processes based on diagnostic sedimentary criteria advances our predictive ability in complex and dynamic mud‐dominated environments and informs resource prospectivity.     

The EU directive on port reception facilities for ship-generated waste and cargo residues: current availability of facilities in the North Sea

The aim of this paper is to evaluate the current availability of port reception facilities within the North Sea area. The evaluation is based primarily on original survey data from the summer of 2001, supplemented by existing information from surveys conducted by the International Maritime Organization. The EU Directive on port reception facilities for ship-generated waste etc. (Directive 2000/59/EC) requires that all ports provide facilities to meet the needs of those vessels normally calling in at them. In order for the Directive to be implemented effectively, the physical availability of such facilities is vital. This paper audits the wide range of port types within the region and also outlines the wide range of vessel types using these ports, and their requirements for a range of facilities. On the basis of this analysis, conclusions are drawn about the extent to which the provision requirement of the Directive is already being met.     

Rummaging through Earth's Attic for Remains of Ancient Life

We explore the likelihood that early remains of Earth, Mars, and Venus have been preserved on the Moon in high enough concentrations to motivate a search mission. During the Late Heavy Bombardment, the inner planets experienced frequent large impacts. Material ejected by these impacts near the escape velocity would have had the potential to land and be preserved on the surface of the Moon. Such ejecta could yield information on the geochemical and biological state of early Earth, Mars, and Venus. To determine whether the Moon has preserved enough ejecta to justify a search mission, we calculate the amount of terran material incident on the Moon over its history by considering the distribution of ejecta launched from the Earth by large impacts. In addition, we make analogous estimates for Mars and Venus. We find, for a well-mixed regolith, that the median surface abundance of terran material is roughly 7 ppm, corresponding to a mass of approximately 20,000 kg of terran material over a 10×10-square-km area. Over the same area, the amount of material transferred from Venus is 1-30 kg and material from Mars as much as 180 kg. Given that the amount of terran material is substantial, we estimate the fraction of this material surviving impact with intact geochemical and biological tracers.     

Adatom Fe(III) on the hematite surface: Observation of a key reactive surface species

The reactivity of a mineral surface is determined by the variety and population of different types of surface sites (e.g., step, kink, adatom, and defect sites). The concept of "adsorbed nutrient" has been built into crystal growth theories, and many other studies of mineral surface reactivity appeal to ill-defined "active sites." Despite their theoretical importance, there has been little direct experimental or analytical investigation of the structure and properties of such species. Here, we use ex-situ and in-situ scanning tunneling microcopy (STM) combined with calculated images based on a resonant tunneling model to show that observed nonperiodic protrusions and depressions on the hematite (001) surface can be explained as Fe in an adsorbed or adatom state occupying sites different from those that result from simple termination of the bulk mineral. The number of such sites varies with sample preparation history, consistent with their removal from the surface in low pH solutions.     

Storm-intensity criteria for several classes of the driving interplanetary structures

In this paper we discuss the main-phase evolution of intense magnetic storms, associated with the passage of different interplanetary magnetic structures. It is shown that their evolution, driven by intense magnetic fields in the sheath region just behind interplanetary shocks, evolves faster (implying physically different magnetospheric configurations) than that associated with intense magnetic fields in the ejecta itself and in corotating streams. The estimated ring-current injection rate for the main phase of intense magnetic storms caused by sheath fields is ～10 times greater than the estimated injection rate for N–S magnetic clouds. Based on these results, we propose storm-intensity criteria for several classes of the driving interplanetary structures. The time necessary to reach a Dst/SYM index threshold level is an important parameter for a space weather forecast.