Chloride source delineation in an urban-agricultural watershed: Deicing agents versus agricultural contributions

Analyses (n = 525) of chloride (Cl⁻), bromide (Br⁻), nitrate as nitrogen (NO₃-N), sodium (Na⁺), calcium (Ca²⁺) and potassium (K⁺) in stream water, tile-drain water and groundwater were conducted in an urban-agricultural watershed (10% urban/impervious, 87% agriculture) to explore potential differences in the signature of Cl⁻ originating from an urban source as compared with an agricultural source. Only during winter recharge events did measured Cl⁻ concentrations exceed the 230 mg/L chronic threshold. At base flow, nearly all surface water and tile water samples had Cl⁻ concentrations above the calculated background threshold of 18 mg/L. Mann–Whitney U tests revealed ratios of Cl⁻ to Br⁻ (p = .045), to NO₃-N (p < .0001), to Ca²⁺ (p < .0001), and to Na⁺ (p < .0001) to be significantly different between urban and agricultural waters. While Cl⁻ ratios indicate that road salt was the dominant source of Cl⁻ in the watershed, potassium chloride fertilizer contributed as an important secondary source. Deicing in watersheds where urban land use is minimal had a profound impact on Cl⁻ dynamics; however, agricultural practices contributed Cl⁻ year-round, elevating stream base flow Cl⁻ concentrations above the background level.     

Prediction of thermal conductivity in reservoir rocks using fabric theory

An accurate prediction of the thermal conductivity of reservoir rocks in the subsurface is extremely important for a quantitative analysis of basin thermal history and hydrocarbon maturation. A model for calculating the thermal conductivity of reservoir rocks as a function of mineral composition, porosity, fluid type, and temperature has been developed based on fabric theory and experimental data. The study indicates that thermal conductivities of reservoir rocks are dependent on the volume fraction of components (minerals, porosity, and fluids), the temperature, and the fraction of series elements (FSE) which represents the way that the mineral components aggregate. The sensitivity test of the fabric model shows that quartz is the most sensitive mineral for the thermal conductivity of clastic rocks. The study results indicate that the FSE value is very critical. Different lithologies have different optimum FSE values because of different textures and sedimentary structures. The optimum FSE values are defined as those which result in the least error in the model computation of the thermal conductivity of the rocks. These values are 0.444 for water-saturated clay rocks, 0.498 for water-saturated sandstones, and 0.337 for water-saturated carbonates. Compared with the geometric mean model, the fabric model yields better results for the thermal conductivity, largely because the model parameters can be adjusted to satisfy different lithologies and to minimize the mean errors. The fabric model provides a good approach for estimating paleothermal conductivity in complex rock systems based on the mineral composition and pore fluid saturation of the rocks.     

Granitic plutonism as an indicator of microplates in the Palaeozoic of central and eastern Maine

Oxygen and strontium isotope ratios have been used to characterize source regions for granitic magmas for a transect across the northern Appalachian orogen in central and eastern Maine. The northwestern plutons (Katahdin and Seboeis) have δ¹⁸O values of 10.3–13.3 and initial ⁸⁷Sr/⁸⁶Sr ratios of 0.7083 and 0.7066, respectively. The central plutons (Bottle Lake and Center Pond) have lower δ¹⁸O values (8.2–9.9) and initial ⁸⁷Sr/⁸⁶Sr ratios (0.7043–0.7055). The southeastern plutons (Lucerne and Deblois) have δ¹⁸O values (9.0–11.0) but initial ⁸⁷Sr/⁸⁶Sr ratios (0.7077 and 0.7041, respectively) which are intermediate between the northwestern and central plutons.Source models derived from these results and other petrological and geochemical data reflect the juxtaposition of discrete source regions by transcurrent faulting, which may be related to oblique plate motions. This model illustrates the importance of microplate accretion in the Palaeozoic history of the northern Appalachian orogen.     

Prevalence and distribution of fecal indicator organisms in South Florida beach sand and preliminary assessment of health effects associated with beach sand exposure

Fecal indicator levels in nearshore waters of South Florida are routinely monitored to assess microbial contamination at recreational beaches. However, samples of sand from the surf zone and upper beach are not monitored which is surprising since sand may accumulate and harbor fecal-derived organisms. This study examined the prevalence of fecal indicator organisms in tidally-affected beach sand and in upper beach sand and compared these counts to levels in the water. Since indicator organisms were statistically elevated in sand relative to water, the study also considered the potential health risks associated with beach use and exposure to sand. Fecal coliforms, Escherichia coli, enterococci, somatic coliphages, and F(+)-specific coliphages were enumerated from sand and water at three South Florida beaches (Ft. Lauderdale Beach, Hollywood Beach, and Hobie Beach) over a 2-year period. Bacteria were consistently more concentrated in 100g samples of beach sand (2-23 fold in wet sand and 30-460 fold in dry sand) compared to 100ml samples of water. Somatic coliphages were commonly recovered from both sand and water while F(+)-specific coliphages were less commonly detected. Seeding experiments revealed that a single specimen of gull feces significantly influenced enterococci levels in some 3.1m(2) of beach sand. Examination of beach sand on a micro-spatial scale demonstrated that the variation in enterococci density over short distances was considerable. Results of multiple linear regression analysis showed that the physical and chemical parameters monitored in this study could only minimally account for the variation observed in indicator densities. A pilot epidemiological study was conducted to examine whether the length of exposure to beach water and sand could be correlated with health risk. Logistic regression analysis results provided preliminary evidence that time spent in the wet sand and time spent in the water were associated with a dose-dependent increase in gastrointestinal illness.     

Characteristics of aeolian grain transport over a fluvio-glacial lacustrine braid delta,Lake Tekapo,New Zealand

This paper presents results from one of the few scientific studies to examine the physical characteristics of aeolian sediment transport in an alpine area, where topographically reinforced foehn winds initiate dust storm events. The major objective of this study is to improve knowledge of aeolian processes in mid-latitude alpine regions experiencing extreme wind speeds. Of particular interest is the role of surface characteristics in contributing to the unusually deep saltation layer which is seen to form over fluvio-glacial deposits in the Southern Alps of New Zealand. Sediment was collected at several heights (0ċ5, 1, 2 and 4 m) and locations over a large alpine braided river delta, and standard laboratory techniques used to examine grain size characteristics. An image processing technique was also used to evaluate grain roundness. Grains filtered from the airstream at 0ċ5 m and 1 m above such surfaces were found to display a mean grain size of approximately 300 to 435 μm, resembling grain size characteristics of saltation clouds previously observed in high latitude, cold climate locations, in contrast to desert and prairie environments. Samples collected at 2 and 4 m above the surface were found to consist of 60 to 65 per cent sand-sized material, with some grains exceeding 1–1ċ5 mm in diameter. Grain shape analysis conducted on silt- and clay-sized grains filtered from the airstream above mixed sand and gravel surfaces showed such grains to display an increase in grain roundness with height. This characteristic is thought to reflect the airstream's shape-sorting ability and has important implications with respect to the often observed increase in grain roundness in aeolian deposits with increasing distance from source areas. Namely, if more rounded grains are preferentially carried higher into the airstream and therefore into regions of higher wind speed, they should theoretically be transported further from the entrainment zone before being deposited. The high wind speeds observed, often exceeding 30 m s⁻¹, are seen to transport significantly larger sediment than reported in the literature for desert and prairie environments. In addition, the mixture of grain sizes, and especially the pebble- and cobble-sized clasts that dominate the fluvio-glacial deposits associated with the braided rivers in this mountain region, also appear to increase significantly the trajectory height of saltating sand grains. As a result of these two factors, the depth of the saltation cloud often exceeds 1 m. Observations made in this study therefore highlight the need for field and laboratory aeolian process studies to be extended to examine grain transport over coarse-grained beds during much higher wind velocities than typically reported in the literature. Such studies would provide a valuable insight into aeolian processes in high latitude/altitude environments, such as loess genesis. © 1997 by John Wiley & Sons, Ltd.     

A Comparative Plume Study of DRO,GRO, Benzene,and MTBE: Implications for Risk Management

Groundwater remediation and no-further action decision making at petroleum underground storage tank (UST) sites has largely been based on an understanding of plume length, plume stability, and attenuation rates for key hydrocarbon constituents. Regulatory guidance to support and guide such decisions is based in part on plume studies involving individual hydrocarbon constituents, namely benzene and methyl tert-butyl ether (MTBE). Questions remain regarding whether current guidance is applicable to chemical mixtures such as gasoline range organics (GRO), diesel range organics (DRO), and oxygen containing organic compounds (OCOCs) resulting from hydrocarbon biodegradation. To help address this concern, data from California's GeoTracker database were used to estimate maximum plume lengths, plume stability, and attenuation rates of DRO (which can be used as an analytical surrogate for OCOCs) and GRO relative to benzene and MTBE. The distributions of maximum plume lengths were similar for the four constituents with medians ranging from 27 to 32 m. The fraction of monitoring wells with a decreasing concentration trend ranged from 19% for DRO to 40% for MTBE, while fewer than 7% of the wells had an increasing concentration trend for any of the constituents. Median attenuation rates ranged from 0.10% day⁻¹ for DRO to 0.17% day⁻¹ for MTBE. The results suggest attenuation based risk management is appropriate for DRO and GRO plumes at most petroleum UST sites.     

The termination of the last major phase of aeolian sand movement,coastal dunefields,Denmark

Optically stimulated luminescence (OSL) dating of sand samples from stabilized (or inactive) coastal dunes in Denmark provides information on the age of the termination phase of the last major aeolian activity period. A total of 26 sand samples were taken from four different coastal dunefields around the North Sea, Skagerrak and Kattegat coasts of Denmark. The OSL dates indicate that the last major phase of aeolian activity terminated between ad 1860 and 1905. Most of the dunes examined in this study were active around 1820, during a period documented to have been very stormy. A dune management scheme started around 1792, and this no doubt was a major cause of dunefield stabilization, but an overall decline of storminess, particularly spring and summer storminess, around the end of the 19th century must also have contributed to the increasing inactivity of coastal dunes. The new OSL dates on aeolian sand movement agree well with historical data and data from topographic maps on dune movement. This agreement supports the observation from earlier work that OSL dating of recent aeolian sand movement is accurate over the last few decades to centuries. Copyright © 2005 John Wiley & Sons, Ltd.     

System identification of the Vincent Thomas suspension bridge using earthquake records

The Vincent Thomas Bridge in the Los Angeles metropolitan area, is a critical artery for commercial traffic flow in and out of the Los Angeles Harbor, and is at risk in the seismically active Southern California region, particularly because it straddles the Palos Verdes fault zone. A combination of linear and non‐linear system identification techniques is employed to obtain a complete reduced‐order, multi‐input–multi‐output (MIMO) dynamic model of the Vincent Thomas Bridge based on the dynamic response of the structure to the 1987 Whittier and 1994 Northridge earthquakes. Starting with the available acceleration measurements (which consists of 15 accelerometers on the bridge structure and 10 accelerometers at various locations on its base), an efficient least‐squares‐based time‐domain identification procedure is applied to the data set to develop a reduced‐order, equivalent linear, multi‐degree‐of‐freedom model. Although not the main focus of this study, the linear system identification method is also combined with a non‐parametric identification technique, to generate a reduced‐order non‐linear mathematical model suitable for use in subsequent studies to predict, with good fidelity, the total response of the bridge under arbitrary dynamic environments. Results of this study yield measurements of the equivalent linear modal properties (frequencies, mode shapes and non‐proportional damping) as well as quantitative measures of the extent and nature of non‐linear interaction forces arising from strong ground shaking. It is shown that, for the particular subset of observations used in the identification procedure, the apparent non‐linearities in the system restoring forces are quite significant, and they contribute substantially to the improved fidelity of the model. Also shown is the potential of the identification technique under discussion to detect slight changes in the structure's influence coefficients, which may be indicators of damage and degradation in the structure being monitored. Difficulties associated with accurately estimating damping for lightly damped long‐span structures from their earthquake response are discussed. The technical issues raised in this paper indicate the need for added spatial resolution in sensor instrumentation to obtain identified mathematical models of structural systems with the broadest range of validity. Copyright © 2003 John Wiley & Sons, Ltd.