Role of superoxide in the photochemical reduction of iron in seawater

We have conducted a series of laboratory studies to investigate the generation of ferrous iron and reactive oxygen species when solutions of seawater containing natural organic matter (NOM) and ferric iron are exposed to simulated sunlight. Total ferrous iron and hydrogen peroxide were measured at nanomolar concentrations with high temporal resolution using chemiluminescence-based methods. In all cases, ferrous iron concentrations rapidly peaked at several nanomoles per litre after a few minutes, and then declined over time, while hydrogen peroxide concentrations increased in a non-linear manner. Although concentrations of both species depended on the concentration of NOM, hydrogen peroxide concentrations were only minimally affected by the presence of iron. Increasing the NOM concentration while the total iron concentration was maintained constant led to an increase in the maximum ferrous iron concentration, suggesting that superoxide-mediated reduction of iron may be a major pathway for ferrous iron formation. This was supported by measurements of superoxide production from irradiation of NOM in the absence of iron and kinetic calculations, as well as an experiment in which superoxide dismutase was added. Further analysis of the data suggested that dissolved oxygen and photo-produced hydrogen peroxide were the primary oxidants of the Fe(II) formed. Thus we propose that superoxide and ferrous iron may be intricately coupled in the system, and that their generation is determined by the supply of NOM available to harvest light and donate electrons.     

Collisional evolution of the asteroid belt

A new synthesis of asteroid collisional evolution is motivated by the question of whether most asteroids larger than ∼1 km size are strengthless gravitational aggregates (rubble piles). NEAR found Eros not to be a rubble pile, but a shattered collisional fragment, with a through-going fracture system, and an average of about 20 m regolith cover. Of four asteroids visited by spacecraft, none appears likely to be a rubble pile, except perhaps Mathilde. Nevertheless, current understanding of asteroid collisions and size-dependent strength, and the observed distribution of rotation rates versus size, have led to a theoretical consensus that many or most asteroids larger than 1 km should be rubble piles. Is Eros, the best-observed asteroid, highly unusual because it is not a rubble pile? Is Mathilde, if it is a rubble pile, like most asteroids? What would be expected for the small asteroid Itokawa, the MUSES-C sample return target? An asteroid size distribution is synthesized from the Minor Planet Center listing and results of the Sloan Digital Sky Survey, an Infrared Space Observatory survey, the Small Main-belt Asteroid Spectroscopic Survey and the Infrared Astronomical Satellite survey. A new picture emerges of asteroid collisional evolution, in which the well-known Dohnanyi result, that the size distribution tends toward a self-similar form with a 2.5-index power law, is overturned because of scale-dependent collision physics. Survival of a basaltic crust on Vesta can be accommodated, together with formation of many exposed metal cores. The lifetimes against destruction are estimated as 3 Gyr at the size of Eros, 10 Gyr at ten times that size, and 40 Gyr at the size of Vesta. Eros as a shattered collisional fragment is not highly unusual. The new picture reveals the new possibility of a transition size in the collisional state, where asteroids below 5 km size would be primarily collisional breakup fragments whereas much larger asteroids are mostly eroded or shattered survivors of collisions. In this case, well-defined families would be found in asteroids larger than about 5 km size, but for smaller asteroids, families may no longer be readily separated from a background population. Moreover, the measured boulder size distribution on Eros is re-interpreted as a sample of impactor size distributions in the asteroid belt. The regolith on Eros may result largely from the last giant impact, and the same may be true of Itokawa, in which case about a meter of regolith would be expected there. Even a small asteroid like Itokawa may be a shattered object with regolith cover.     

An avalanche photodiode photon counting camera for high-resolution astronomy

A system is described which makes best use of the high quantum efficiency and high count rate capability of avalanche photodiodes for high time resolution observations of optical pulsars. The use of three APDs allows simultaneous photometry of the target and a reference star, and the monitoring of the sky background. By minimising the optical components in the light path the optical efficiency of the system is maximised. The TRIFFID (Shearer, A., Stappers, B., O'Connor, P., Golden, A., Strom, R., Redfern, M., Ryan, O.: Science 301, 493–495 (2003)) and OPTIMA (Straubmeier, C., Kanbach, G., Schrey, F.: Exp. Astron. 11, 157–170 (2001)) have shown that fibre-fed APD arrays can produce excellent results. This, new, system was used on the 6m BTA in November 2003 – results on the Crab pulsar are presented.     

Lateral inhomogeneities in the Venus atmosphere: Analysis of thermal infrared maps

The thermal infrared maps of Venus published by Murray, Wildey, and Westphal (1963) and Westphal, Wildey, and Murray (1965) have been analyzed systematically in order to separate the observed intensity into a limb-darkening component and a solar-associated component representing fixed patterns of intensity corotating with the earth and sun, respectively. Interesting new results are obtained for the solar-associated component. Regions near the subsolar point and the poles are not covered in the original maps or in the analysis.The solar-associated pattern of intensity is very nearly symmetric about the equator. In both northern and southern hemispheres, an intensity minimum seems to occur near the morning terminator at middle to high latitudes, slightly beyond the limit of the maps. An intensity maximum occurs on the equator slightly to the east of the antisolar point. Three broad ridges of relatively high intensity radiate away from this point, one pointing to the west along the equator, the others pointing to the northeast and southeast, respectively. The eastward tilt of the latter two ridges may indicate that horizontal exchange is important in maintaining the equatorial maximum of zonal momentum which is associated with the 4-day circulation of the Venus atmosphere.     

An unsteady wind-driven ocean circulation model

This model of a continuously stratified ocean, consisting of surface Ekman and thermal layers and a deep abyssal region, is driven by an unsteady surface wind stress. The model yields a nonlinear planetary wave equation for the surface temperature which is solved by the method of characteristics. Horizontal distributions of the surface temperature, the heat content and the potential energy are computed. For a model zonal wind stress relevant to the North Atlantic, a parameter sensitivity study is made.Long time scale observations of the heat content in the North Atlantic north of 45°N show that periods of heating and cooling of a few decades duration frequently occur. Using a zonal wind stress consisting of the superposition of a mean and two time harmonic components, secular variations in the surface temperature field manifest themselves as a beat period, provided the time harmonic frequencies are close together. Finally, to investigate the effects on the circulation produced by the changing intensity of the westerly winds, numerical results are presented for the case when the wind stress distribution oscillates in the north-south direction with time. Results from the study show that the heating and cooling periods of a few decades duration in the North Atlantic can be reproduced.     

POTENTIOSTATIC STUDY OF IRON METEORITE CORROSION

A potentiostat was used to study the electrolytic corrosion of iron meteorites in a neutral solution. Low current densities were chosen so that the observed potentials would more closely approximate the theoretical Nernst values. Iron, nickel, and cobalt ions, the products of corrosion, were soluble in the electrolyte solution, and were determined after each electrolysis by atomic absorption spectrophotometry. Kamacite and taenite dissolved as individual phases, with kamacite dissolving preferentially. Cobalt dissolved along with iron and nickel from each phase. There is a direct relationship between nickel content and the potential at which a meteorite first starts to dissolve; the higher the nickel content, the more resistant the meteorite is to corrosion. None of the six meteorites observed started to dissolve at a lower potential than pure iron, nor at a higher potential than pure nickel