在EBEX-2000实验资料中湍流耗散率、长度尺度和结构参数特征

采用2000年8月在美国加州棉花地两个高度上应用超声三分量仪、快速响应温度和湿度仪进行的EBEX-2000 (International Energy Balance Experiment, 2000, 简称EBEX-2000) 风速三分量、温度和湿度湍流实验观测数据, 计算分析了在不同稳定度下的湍流能量和热量耗散率和湍流结构参数特征.并与Kansas和长白山原始森林湍流实验得到的结果进行了比较, 得到了一些湍流特征量在不同下垫面情况下的一些有意义的特征.     

Diffuse gas emissions at the Ukinrek Maars,Alaska: Implications for magmatic degassing and volcanic monitoring

Diffuse CO₂ efflux near the Ukinrek Maars, two small volcanic craters that formed in 1977 in a remote part of the Alaska Peninsula, was investigated using accumulation chamber measurements. High CO₂ efflux, in many places exceeding 1000 g m⁻² d⁻¹, was found in conspicuous zones of plant damage or kill that cover 30,000–50,000 m² in area. Total diffuse CO₂ emission was estimated at 21–44 t d⁻¹. Gas vents 3-km away at The Gas Rocks produce 0.5 t d⁻¹ of CO₂ that probably derives from the Ukinrek Maars basalt based on similar δ¹³C values (∼−6‰), ³He/⁴He ratios (5.9–7.2 R_A), and CO₂/³He ratios (1–2 × 10⁹) in the two areas. A lower ³He/⁴He ratio (2.7 R_A) and much higher CO₂/³He ratio (9 × 10¹⁰) in gas from the nearest arc-front volcanic center (Mount Peulik/Ugashik) provide a useful comparison. The large diffuse CO₂ emission at Ukinrek has important implications for magmatic degassing, subsurface gas transport, and local toxicity hazards. Gas–water–rock interactions play a major role in the location, magnitude and chemistry of the emissions.     

Quaternary glaciation of Mount Everest

The Quaternary glacial history of the Rongbuk valley on the northern slopes of Mount Everest is examined using field mapping, geomorphic and sedimentological methods, and optically stimulated luminescence (OSL) and ¹⁰Be terrestrial cosmogenic nuclide (TCN) dating. Six major sets of moraines are present representing significant glacier advances or still-stands. These date to >330 ka (Tingri moraine), >41 ka (Dzakar moraine), 24–27 ka (Jilong moraine), 14–17 ka (Rongbuk moraine), 8–2 ka (Samdupo moraines) and ～1.6 ka (Xarlungnama moraine), and each is assigned to a distinct glacial stage named after the moraine. The Samdupo glacial stage is subdivided into Samdupo I (6.8–7.7 ka) and Samdupo II (～2.4 ka). Comparison with OSL and TCN defined ages on moraines on the southern slopes of Mount Everest in the Khumbu Himal show that glaciations across the Everest massif were broadly synchronous. However, unlike the Khumbu Himal, no early Holocene glacier advance is recognized in the Rongbuk valley. This suggests that the Khumbu Himal may have received increased monsoon precipitation in the early Holocene to help increase positive glacier mass balances, while the Rongbuk valley was too sheltered to receive monsoon moisture during this time and glaciers could not advance. Comparison of equilibrium-line altitude depressions for glacial stages across Mount Everest reveals asymmetric patterns of glacier retreat that likely reflects greater glacier sensitivity to climate change on the northern slopes, possibly due to precipitation starvation.     

Hepburn Spa: cold carbonated mineral waters of Central Victoria,South Eastern Australia

Hepburn Spring is the major cold carbonated mineral spring of the ‘Spa’ country of Central Victoria, in South Eastern Australia. The spring occurs in a small tributary valley of the Loddon River, 15 km away from the crest of the Great Dividing Range. The waters are effervescent, have an alkalinity of around 1,500 mg/L (as HCO₃ ⁻), are mildly acidic and have high iron concentrations. Hepburn Spring is one of nearly 100 small cold low flow carbonated mineral water springs that occur in the region. Hepburn Spring has been protected since 1865 in one of 34 ‘Special Mineral Spring Reserves’. By world standards the spring is small and not highly developed, but it retains much of its charm due to the bushland, forest setting. The bedrock of the region consists of indurated arkosic sandstones interbedded with carbonaceous shales and slates. The rocks are folded and cut by swarms of strongly developed meridional fissure fault systems. Hepburn Spring is situated on the fault and fold axes associated with the “Cornish line” and Gold mines have dewatered the spring on several occasions. After dewatering events the water level and flow recovered first and then the water composition and effervescence. The origin of the effervescent waters has attracted much attention; hypotheses include both a volcanic and a rock water reaction origin. The second hypothesis involves weathering of the carbonaceous and sometimes pyritic rock mass which contains only a few percent carbonate. This process produces high bicarbonate groundwater throughout Central Victoria. The Hepburn waters are a variant of these waters and it is suggested that controls on the carbonate solubility and redox conditions in the fissures flow systems results in effervescent waters as the waters ascend.     

Relict nebkhas (pimple mounds) record prolonged late Holocene drought in the forested region of south-central United States

The origin and significance of pimple mounds (low, elliptical to circular dune-like features found across much of the south-central United States) have been debated for nearly two centuries. We cored pimple mounds at four sites spanning the Ozark Plateau, Arkansas River Valley, and Gulf of Mexico Coastal Plain and found that these mounds have a regionally consistent textural asymmetry such that there is a significant excess of coarse-grained sediment within their northwest flanks. We interpret this asymmetry as evidence of an eolian depositional origin of these mounds and conclude they are relict nebkhas (coppice dunes) deposited during protracted middle to late Holocene droughts. These four mounds yield optically stimulated luminescence ages between 2400 and 700 yr that correlate with well-documented periods of eolian activity and droughts on the southern Great Plains, including the Medieval Climate Anomaly. We conclude vegetation loss during extended droughts led to local eolian deflation and pimple mound deposition. These mounds reflect landscape response to multi-decadal droughts for the south-central U.S. The spatial extent of pimple mounds across this region further underscores the severity and duration of late Holocene droughts, which were significantly greater than historic droughts.     

Silicon isotopic fractionation of CAI-like vacuum evaporation residues

Calcium-, aluminum-rich inclusions (CAIs) are often enriched in the heavy isotopes of magnesium and silicon relative to bulk solar system materials. It is likely that these isotopic enrichments resulted from evaporative mass loss of magnesium and silicon from early solar system condensates while they were molten during one or more high-temperature reheating events. Quantitative interpretation of these enrichments requires laboratory determinations of the evaporation kinetics and associated isotopic fractionation effects for these elements. The experimental data for the kinetics of evaporation of magnesium and silicon and the evaporative isotopic fractionation of magnesium is reasonably complete for Type B CAI liquids (Richter F. M., Davis A. M., Ebel D. S., and Hashimoto A. (2002) Elemental and isotopic fractionation of Type B CAIs: experiments, theoretical considerations, and constraints on their thermal evolution. Geochim. Cosmochim. Acta66, 521-540; Richter F. M., Janney P. E., Mendybaev R. A., Davis A. M., and Wadhwa M. (2007a) Elemental and isotopic fractionation of Type B CAI-like liquids by evaporation. Geochim. Cosmochim. Acta71, 5544-5564.). However, the isotopic fractionation factor for silicon evaporating from such liquids has not been as extensively studied. Here we report new ion microprobe silicon isotopic measurements of residual glass from partial evaporation of Type B CAI liquids into vacuum. The silicon isotopic fractionation is reported as a kinetic fractionation factor, α_Si, corresponding to the ratio of the silicon isotopic composition of the evaporation flux to that of the residual silicate liquid. For CAI-like melts, we find that α_Si = 0.98985 ± 0.00044 (2σ) for ²⁹Si/²⁸Si with no resolvable variation with temperature over the temperature range of the experiments, 1600-1900 °C. This value is different from what has been reported for evaporation of liquid Mg₂SiO₄ (Davis A. M., Hashimoto A., Clayton R. N., and Mayeda T. K. (1990) Isotope mass fractionation during evaporation of Mg₂SiO₄. Nature347, 655-658.) and of a melt with CI chondritic proportions of the major elements (Wang J., Davis A. M., Clayton R. N., Mayeda T. K., and Hashimoto A. (2001) Chemical and isotopic fractionation during the evaporation of the FeO-MgO-SiO₂-CaO-Al₂O₃-TiO₂-REE melt system. Geochim. Cosmochim. Acta65, 479-494.). There appears to be some compositional control on α_Si, whereas no compositional effects have been reported for α_Mg. We use the values of α_Si and α_Mg, to calculate the chemical compositions of the unevaporated precursors of a number of isotopically fractionated CAIs from CV chondrites whose chemical compositions and magnesium and silicon isotopic compositions have been previously measured.     

Proximity and power within investment relationships: The case of the UK private equity industry

The role of power in economic activity has been researched across the social sciences but there has been little engagement with the spatialities of power relations. This paper thus draws on a recent reinvigorated interest in power within economic geography to develop an approach for understanding how the spatiality of power relations in economic practices are constituted through different forms of proximity. It argues that proximity needs to be conceptualised as multi-dimensional including physical, cultural, virtual and organizational proximity between firms and actors. It further contends that the development of different forms of proximity shape the agency of empowered actors in industry clusters and regional economies. This general proposition is explored by presenting research into a case study: the UK-based private equity industry. The research focuses on the nature, role and development of different forms of proximity between private equity firms and the investee firms that are the subject of investments.     

Plesiosaur remains from the Jurassic-Cretaceous Purbeck Limestone Group of southern England

Plesiosaur fossils from the uppermost Tithonian (Upper Jurassic) to lower Valanginian (Lower Cretaceous) Purbeck Limestone Group of Dorset, England are important because they constitute a rare record from around the Jurassic-Cretaceous boundary. Where diagnostic, the remains are referred to indeterminate plesiosauroids (Cryptocleidoidea) and represent relatively small animals including a previously undescribed juvenile individual. This observation accords with the lagoonal-lacustrine (with periodic marine influx) depositional setting of the Purbeck Limestone Group strata, a palaeoenvironment that is often associated with juvenile plesiosaur occurrences.     

Mineralogical control of rare earth elements in acid sulfate soils

Major, trace and rare earth element concentrations were measured in porewater, surface water and sediments at an acid sulfate soil site. The concentrations of La and Ce in porewater are up to 1-3 ppm. There is a strong correlation between REE concentration and acidity, except that the maximum concentrations were consistently found below the horizon of maximum acidity, associated with an increase in pH (to ca. 4) and change in mineralogy from jarosite-dominated to goethite-dominated mottles. Jarosite replacement by goethite is as expected with the rise in pH, which in turn is due to the occurrence of a fossil shell bed just below. The rare earth element patterns in the porewaters are enriched in the MREE with respect to Post-Archaean Australian Shale (PAAS). Measurements and calculations show that this is in accord with experiments on low-degree partial dissolution of jarosite, even when the jarosite itself is highly enriched in LREE. There is a clear fractionation in the patterns between the clay-rich soil matrix, which is slightly depleted in the LREE when normalized to PAAS (La/Yb_PAAS ∼0.5), and the secondary mineral phase jarosite, which is enriched in the LREE (La/Yb_PAAS = 15-50). The REE pattern in the porewater changes with the transition from jarosite- to goethite-rich mottles, becoming relatively more enriched in the LREE compared to the HREE, which is consistent with the incongruent dissolution of jarosite to form goethite and the release of greater amounts of jarosite REE to solution, including proportionately more of the jarosite-compatible LREE.Maximum surface water REE concentrations in acidic water were 100-200 ppb La and Ce. REE patterns in surface water were very similar to the porewater transition zone, enriched in the MREE, but asymmetric, relatively enriched in the LREE compared to the HREE.