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21.
In this article, we document a detailed analytical characterisation of zircon M127, a homogeneous 12.7 carat gemstone from Ratnapura, Sri Lanka. Zircon M127 has TIMS‐determined mean U–Pb radiogenic isotopic ratios of 0.084743 ± 0.000027 for 206Pb/238U and 0.67676 ± 0.00023 for 207Pb/235U (weighted means, 2s uncertainties). Its 206Pb/238U age of 524.36 ± 0.16 Ma (95% confidence uncertainty) is concordant within the uncertainties of decay constants. The δ18O value (determined by laser fluorination) is 8.26 ± 0.06‰ VSMOW (2s), and the mean 176Hf/177Hf ratio (determined by solution ICP‐MS) is 0.282396 ± 0.000004 (2s). The SIMS‐determined δ7Li value is ?0.6 ± 0.9‰ (2s), with a mean mass fraction of 1.0 ± 0.1 μg g?1 Li (2s). Zircon M127 contains ~ 923 μg g?1 U. The moderate degree of radiation damage corresponds well with the time‐integrated self‐irradiation dose of 1.82 × 1018 alpha events per gram. This observation, and the (U–Th)/He age of 426 ± 7 Ma (2s), which is typical of unheated Sri Lankan zircon, enable us to exclude any thermal treatment. Zircon M127 is proposed as a reference material for the determination of zircon U–Pb ages by means of SIMS in combination with hafnium and stable isotope (oxygen and potentially also lithium) determination.  相似文献   
22.
This study addresses whether Raman spectra can be used to estimate the degree of accumulated radiation damage in monazite-(Ce) samples whose chemical composition was previously determined. Our results indicate that the degree of disorder in monazite–(Ce), as observed from increasing Raman band broadening, generally depends on both the structural state (i.e., radiation damage) and the chemical composition (i.e., incorporation of non-formula elements). The chemical effects were studied on synthetic orthophosphates grown using the Li-Mo flux method, and non radiation-damaged analogues of the naturally radiation-damaged monazite–(Ce) samples, produced by dry annealing. We found that the “chemical” Raman-band broadening of natural monazite–(Ce) can be predicted by the empirical formula, $$ {\hbox{FWHM}} {\hbox{[c}}{{\hbox{m}}^{ - {1}}}{]} = {3}{.95} + {26}{.66} \times {\hbox{(Th}} + {\hbox{U}} + {\hbox{Ca}} + {\hbox{Pb)}} {\hbox{[apfu]}} $$ where, FWHM = full width at half maximum of the main Raman band of monazite–(Ce) (i.e., the symmetric PO4 stretching near 970?cm?1), and (Th+U+Ca+Pb) = sum of the four elements in apfu (atoms per formula unit). Provided the chemical composition of a natural monazite–(Ce) is known, this “chemical band broadening” can be used to estimate the degree of structural radiation damage from the observed FWHM of the ν1(PO4) band of that particular sample using Raman spectroscopy. Our annealing studies on a wide range of monazite–(Ce) reference materials and other monazite–(Ce) samples confirmed that this mineral virtually never becomes highly radiation damaged. Potential advantages and the practical use of the proposed method in the Earth sciences are discussed.  相似文献   
23.
The goal of this study is the analysis of heat waves and their impact on humans, using human biometeorological indices, which are based on the energy balance of the human body. The implications for humans are not only described through the intensity of the heat waves, but also through their duration over consecutive days. Both intensity and duration were analyzed for the Greater Athens Area during the period 1955 to 2001. The analysis was carried out using the daily physiologically equivalent temperature and the daily minimum air temperature. Based on these two parameters, the results showed an increase in the average duration of heat waves. Furthermore, the use of the Gaussian filter revealed the intra-annual variation of heat stress conditions and their relevance to humans. The results could be used for the management of the negative consequences of heat waves in cities suffering from environmental pollution and also for climate impact studies.  相似文献   
24.
Although the bulk aerodynamic transfer coefficients for sensible (C H ) and latent (C E ) heat over snow and sea ice surfaces are necessary for accurately modeling the surface energy budget, they have been measured rarely. This paper, therefore, presents a theoretical model that predicts neutral-stability values of C H and C E as functions of the wind speed and a surface roughness parameter. The crux of the model is establishing the interfacial sublayer profiles of the scalars, temperature and water vapor, over aerodynamically smooth and rough surfaces on the basis of a surface-renewal model in which turbulent eddies continually scour the surface, transferring scalar contaminants across the interface by molecular diffusion. Matching these interfacial sublayer profiles with the semi-logarithmic inertial sublayer profiles yields the roughness lengths for temperature and water vapor. When coupled with a model for the drag coefficient over snow and sea ice based on actual measurements, these roughness lengths lead to the transfer coefficients. C E is always a few percent larger than CH. Both decrease monotonically with increasing wind speed for speeds above 1 m s–1, and both increase at all wind speeds as the surface gets rougher. Both, nevertheless, are almost always between 1.0 × 10–3 and 1.5 × 10–3.  相似文献   
25.
Zircon, monazite and xenotime crystallized over a temperature interval of several hundred degrees at the magmatic to hydrothermal transition of the Sn and W mineralized Mole Granite. Magmatic zircon and monazite, thought to have crystallized from hydrous silicate melt, were dated by conventional U–Pb techniques at an age of 247.6 ± 0.4 and 247.7 ± 0.5 Ma, respectively. Xenotime occurring in hydrothermal quartz is found to be significantly younger at 246.2 ± 0.5 Ma and is interpreted to represent hydrothermal growth. From associated fluid inclusions it is concluded that it precipitated from a hydrothermal brine ≤ 600 °C, which is below the accepted closure temperature for U–Pb in this mineral. These data are compatible with a two-stage crystallization process: precipitation of zircon and monazite as magmatic liquidus phases in deep crustal magma followed by complete crystallization and intimately associated Sn–W mineralization after intrusion of the shallow, sill-like body of the Mole Granite. Later hydrothermal formation of monazite in a biotite–fluorite–topaz reaction rim around a mineralized vein was dated at 244.4 ± 1.4 Ma, which distinctly postdates the Mole Granite and is possibly related to a younger hidden intrusion and its hydrothermal fluid system.

Obtaining precise age data for magmatic and hydrothermal minerals of the Mole Granite is hampered by uncertainties introduced by different corrections required for multiple highly radiogenic minerals crystallising from evolved hydrous granites, including 230Th disequilibrium due to Th/U fractionation during monazite and possibly xenotime crystallization, variable Th/U ratios of the fluids from which xenotime was precipitating, elevated contents of common lead, and post-crystallization lead loss in zircon, enhanced by the fluid-saturated environment. The data imply that monazite can also survive as a liquidus phase in protracted magmatic systems over periods of 106 years. The outlined model is in agreement with prominent chemical core-rim variation of the zircon.  相似文献   

26.
Photoelectric detectors for the measurement of photolysis frequencies of different trace gases in the atmosphere are described. They exhibit uniform response characteristics over one hemisphere (2 sr) and wavelength characteristics closely matched to those of the photolysis frequencies J O1D, J NO2, and J NO3, respectively. Absolute calibration of the J O1D detector was performed by chemical actinometry with an accuracy of ±16 percent. Simultaneous measurements of J NO2 and J O1D are presented.  相似文献   
27.
Free tropospheric measurements of ozone, peroxyacetylnitrate andprecursors (CO, NMHC) that were made within the framework of the EUROTRACsub-project TOR (Tropospheric Ozone Research) between 1990 and 1995 at theGAW station Izana, Tenerife (28°18N, 16°30W) arediscussed. The average annual cycles reveal the importance of transport fromnorthern mid-latitudes and the role of photo-chemistry. According toair-mass trajectories, which were supplied to us from AEROCE(Atmosphere/Ocean Chemistry Experiment), transport from northernmid-latitudes is associated with high precursor concentrations in winter,whereas ozone concentrations in winter are not much influenced by transportpatterns, suggesting a rather uniform distribution over the northern part ofthe Northern Hemisphere around mean value of 43 ± 5 ppb. In summer,high ozone concentrations of up to 90 ppb are often encountered duringtransport from north, while the levels of precursors are much lower than inwinter, because of photochemical destruction. Trajectories from southerlylatitudes and the Sahara usually have the lowest ozone concentrationsassociated with them.  相似文献   
28.
This study aims at sharpening the existing knowledge of expected seasonal mean climate change and its uncertainty over Europe for the two key climate variables air temperature and precipitation amount until the mid-twentyfirst century. For this purpose, we assess and compensate the global climate model (GCM) sampling bias of the ENSEMBLES regional climate model (RCM) projections by combining them with the full set of the CMIP3 GCM ensemble. We first apply a cross-validation in order to assess the skill of different statistical data reconstruction methods in reproducing ensemble mean and standard deviation. We then select the most appropriate reconstruction method in order to fill the missing values of the ENSEMBLES simulation matrix and further extend the matrix by all available CMIP3 GCM simulations forced by the A1B emission scenario. Cross-validation identifies a randomized scaling approach as superior in reconstructing the ensemble spread. Errors in ensemble mean and standard deviation are mostly less than 0.1 K and 1.0 % for air temperature and precipitation amount, respectively. Reconstruction of the missing values reveals that expected seasonal mean climate change of the ENSEMBLES RCM projections is not significantly biased and that the associated uncertainty is not underestimated due to sampling of only a few driving GCMs. In contrast, the spread of the extended simulation matrix is partly significantly lower, sharpening our knowledge about future climate change over Europe by reducing uncertainty in some regions. Furthermore, this study gives substantial weight to recent climate change impact studies based on the ENSEMBLES projections, since it confirms the robustness of the climate forcing of these studies concerning GCM sampling.  相似文献   
29.
Previous work has shown that streamflow response during baseflow conditions is a function of storage, but also that this functional relationship varies among seasons and catchments. Traditionally, hydrological models incorporate conceptual groundwater models consisting of linear or non‐linear storage–outflow functions. Identification of the right model structure and model parameterization however is challenging. The aim of this paper is to systematically test different model structures in a set of catchments where different aquifer types govern baseflow generation processes. Nine different two‐parameter conceptual groundwater models are applied with multi‐objective calibration to transform two different groundwater recharge series derived from a soil‐atmosphere‐vegetation transfer model into baseflow separated from streamflow data. The relative performance differences of the model structures allow to systematically improve the understanding of baseflow generation processes and to identify most appropriate model structures for different aquifer types. We found more versatile and more aquifer‐specific optimal model structures and elucidate the role of interflow, flow paths, recharge regimes and partially contributing storages. Aquifer‐specific recommendations of storage models were found for fractured and karstic aquifers, whereas large storage capacities blur the identification of superior model structures for complex and porous aquifers. A model performance matrix is presented, which highlights the joint effects of different recharge inputs, calibration criteria, model structures and aquifer types. The matrix is a guidance to improve groundwater model structures towards their representation of the dominant baseflow generation processes of specific aquifer types. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   
30.
The synthesis of experimental understanding of catchment behaviour and its translation into qualitative perceptual models is an important objective of hydrological sciences. We explore this challenge by examining the cumulative understanding of the hydrology of three experimental catchments and how it evolves through the application of different investigation techniques. The case study considers the Huewelerbach, Weierbach and Wollefsbach headwater catchments of the Attert basin in Luxembourg. Subsurface investigations including bore holes and pits, analysis of soil samples and Electrical Resistivity Tomography measurements are presented and discussed. Streamflow and tracer data are used to gain further insights into the streamflow dynamics of the catchments, using end‐member mixing analysis and hydrograph separation based on dissolved silica and electrical conductivity. We show that the streamflow generating processes in all three catchments are controlled primarily by the subsolum and underlying bedrock. In the Huewelerbach, the permeable sandstone formation supports a stable groundwater component with little seasonality, which reaches the stream through a series of sources at the contact zone with the impermeable marls formation. In the Weierbach, the schist formation is relatively impermeable and supports a ‘fill and spill’‐type of flow mechanism; during wet conditions, it produces a delayed response dominated by pre‐event water. In the Wollefsbach, the impermeable marls formation is responsible for a saturation‐excess runoff generating process, producing a fast and highly seasonal response dominated by event water. The distinct streamflow generating processes of the three catchments are represented qualitatively using perceptual models. The perceptual models are in turn translated into quantitative conceptual models, which simulate the hydrological processes using networks of connected reservoirs and transfer functions. More generally, the paper illustrates the evolution of perceptual models based on experimental fieldwork data, the translation of perceptual models into conceptual models and the value of different types of data for processes understanding and model representation. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   
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