Pre-1991 sulfur transfer between mafic injections and dacite magma in the Mt. Pinatubo reservoir

Before the 1991–1992 activity, a large andesite lava dome belonging to the penultimate Pinatubo eruptive period (Buag ∼ 500 BP) formed the volcano summit. Buag porphyritic andesite contains abundant amphibole-bearing microgranular enclaves of basaltic–andesite composition. Buag enclaves have lower K₂O and incompatible trace element (LREE, U, Th) contents than mafic pulses injected in the Pinatubo reservoir during the 1991–1992 eruptive cycle. This study shows that Buag andesite formed by mingling of a hot, water-poor and reduced mafic magma with cold, hydrous and oxidized dacite. Depending on their size, enclaves experienced variable re-equilibration during mixing/mingling. Re-equilibration resulted in hydration, oxidation and transfer of mobile elements (LILE, Cu) from the dacite to the mafic melts and prompted massive amphibole crystallization. In Buag enclaves, S-bearing phases (sulfides, apatite) and melt inclusions in amphibole and plagioclase record the evolution of sulfur partition among melt, crystal and fluid phases during magma cooling and oxidation. At high temperature, sulfur is partitioned between andesitic melt and sulfides (Ni-pyrrhotite). Magma cooling, oxidation and hydration resulted in exsolution of a S–Cl–H₂O vapor phase at the S-solubility minimum near the sulfide–sulfate redox boundary. Primary magmatic sulfide (pyrrhotite) and xenocrystic sulfide grains (pyrite), recycled together with olivines and pyroxenes from old mafic intrusives, were replaced by Cu-rich phases (chalcopyrite, cubanite) and, partially, by Ba–Sr sulfate. Sulfides degassed and transformed into residual spongy magnetite in response to fS₂ drop during final magma ascent and decompression. Our research suggests that a complete evaluation of the sulfur budget at Pinatubo must take into account the en route S assimilation from the country rocks. Moreover, this study shows that the efficiency of sulfur transfer between mafic recharges and injected magmas is controlled by the extent and rate of mingling, hydrous flushing and melt oxidation. Vigorous mixing/mingling and transformation of the magmatic recharge into a spray of small enclaves is required in order to efficiently strip their primary S-content that otherwise remains locked in the sulfides. Hydrous flushing increases the magma oxidation state of the recharges and modifies their primary volatile concentrations that cannot be recovered by the study of late-formed mineral phases and melt inclusions. Conversely, S stored in both late-formed Cu-rich sulfides and interstitial rhyolitic melt represents the pre-eruptive sulfur budget immediately available for release from mafic enclaves during their decompression.     

Hazards and landscape changes (degradations) on Hungarian karst mountains due to natural and human effects

In order to study the karstological processes within the karst ecological system,the geohazards and degradation of karst landscapes on the karst areas of the Bakony mountains(Hungary),we investigated the abiotic elements of the environment,soil and cover deposits,erosion soil decay;the changes in the quantity and quality of karst waters:contamination at swallow holes,contamination of karst springs;and the biogenic factors:surface vegetation coverage by the corine land cover method,plant-ecological examinations,qualification of surface waters with the help of biological water labeling.We recognized that the increasing human activities during the past few centuries have had significant impact on the investigated landscapes of karst areas because of their spatial sensitivity.In the scope of our research we concluded that the landscape changes due to natural and human effects can vary strongly on the different karst areas.These differences can arise from the climatic and geomorphologic situation,the coverlayer’s qualities,etc.,but primarily from the different utilization of the investigated karst areas(e.g.the intensity,characteristics and territorial extension of utilization).On the spot investigation we detected traces of new and fast geomorphological processes(gully formation,landslides,collapses,new sinkhole development) and landforms(sinkholes,gullies,swallow holes),which are clear evidences of the effect of climatic changes.     

Delayed delivery from the sediment factory: modeling the impact of catchment response time to tectonics on sediment flux and fluvio‐deltaic stratigraphy

The sediment flux from a catchment is driven by tectonics and climate but is moderated by the geomorphic response of the landscape system to changes in these two boundary conditions. Consequently, catchment response time and the non‐linear behavior of landscapes in response to boundary condition change control the downstream propagation of climatic or tectonic perturbations from catchments to neighboring basins. In order to investigate the impact of catchment response time on sediment flux, we integrated a spatially‐lumped numerical model PaCMod, with new routines simulating the evolution of landscape morphology and erosion rates under tectonic and climatic forcing. We subsequently applied the model to reconstruct the sediment flux from a tectonically perturbed catchment in central Italy. Finally, we coupled our model to DeltaSim, a process‐response model simulating fluvio‐deltaic stratigraphy, and investigated the impact of catchment response time on stratigraphy, using both synthetic scenarios and a real world system (Fucino Basin, central Italy). Our results demonstrate that the differential response of geomorphic elements to tectonic and climatic changes induces a complex sediment flux signal, and produces characteristic stratigraphic architectures and shoreline trajectories. Copyright © 2014 John Wiley & Sons, Ltd.     

Improved salt imaging in a basin context by high resolution potential field data: Nordkapp Basin,Barents Sea

The seismic imaging of salt diapirs in the Nordkapp Basin gave rise to considerable problems in defining their shape and volume. Independent information was added by integrating the interpretation with high resolution gravity and magnetic data. We developed a novel, iterative workflow, separated into sub‐categories: sediments, salt structures, basement and Moho. Distinctions between the sources of the anomalies from different depths was achieved by utilizing the different decay characteristics of gravity, gravity gradiometry and high resolution magnetic anomalies. The workflow was applied to the southern part of the Nordkapp Basin. It started with the sedimentary model derived from seismics, populated with measured densities and magnetic susceptibilities and a starting model for the base salt. The residual after the removal of this model was interpreted in terms of a crustal model, including flexural isostatic calculations for the Moho with the sedimentary load. The residual after the removal of crustal and early sedimentary model was used to tune the salt model. As these major and minor modelling steps depend on each other, an iterative process was applied to stepwise improve the density and magnetic susceptibility model. The first vertical gradient of gravity and the magnetic field were found to give most information about the cap rock of the diapirs. The improvement in salt imaging, integrated with results from controlled‐source electromagnetic and magneto‐telluric modelling is shown for the salt diapir Uranus, where a well, terminated in the salt, constrains the minimum of the depth to base salt.     

Linking the Recurrence Time of Earthquakes to Source Parameters: A Dream or a Real Possibility?

By using a single-degree-of-freedom spring-slider analog fault model, we generate a synthetic catalog of nearly 500 different seismic sequences. We explore the parameter space by assuming different values of constitutive parameters and tectonic environment. We also consider three different versions of the rate-dependent and state-dependent friction laws [the Dieterich-Ruina (DR), the Ruina-Dieterich (RD) and the Chester-Higgs (CH) models], and different approximations of the behavior of the friction at high sliding speeds, as well as the radiation damping effects. Our results indicate that for all the considered models, the recurrence time (T _cycle) exhibits an inverse proportionality on the loading rate; a linear, positive dependence on the effective normal stress; and a linear, negative dependence on the characteristic distance controlling the state variable evolution. These results confirm and generalize previous studies. Remarkably, we found here that the coefficients of proportionality strongly depend on the adopted friction model, on the high speed behavior and on the reference set of parameters. Notably, we also found that the positive proportionality between T _cycle and the difference b – a, confirmed for DR and RD laws, does not hold in general for the CH law. Overall, we conclude that even in the simplest (and idealized) case of characteristic earthquakes considered here, in which the limiting cycle is reached by the system, and even in the framework of a very simplified fault model, the possibility to a priori predict, through an universal analytical relation, the inter-event time of an impending earthquake still remains only a dream. On the other hand, a numerical prediction of T _cycle would require the exact knowledge of the rheological model (and its parameters at all times over the entire life of the fault) and the actual state of the fault, which indeed are often unknown.     

Damage assessment through structural identification of a three‐story large‐scale precast concrete structure

This paper investigates the damage assessment of a three‐story half‐scale precast concrete building resembling a parking garage through structural identification. The structure was tested under earthquake‐type loading on the NEES large high‐performance outdoor shake table at the University of California San Diego in 2008. The tests provide a unique opportunity to capture the dynamic performance of precast concrete structures built under realistic boundary conditions. The effective modal parameters of the structure at different damage states have been identified from white‐noise and scaled earthquake test data with the assumption that the structure responded in a quasi‐linear manner. Modal identification has been performed using the deterministic‐stochastic subspace identification method based on the measured input–output data. The changes in the identified modal parameters are correlated to the observed damage. In general, the natural frequencies decrease, and the damping ratios increase as the structure is exposed to larger base excitations, indicating loss of stiffness, development/propagation of cracks, and failure in joint connections. The analysis of the modal rotations and curvatures allowed the localization of shear and flexural damages respectively and the checking of the effectiveness of repair actions. Copyright © 2013 John Wiley & Sons, Ltd.     

Mixing metals in the early Universe

We investigate the evolution of the metallicity of the intergalactic medium (IGM) with particular emphasis on its spatial distribution. We propose that metal enrichment occurs as a two-step process. First, supernova (SN) explosions eject metals into relatively small regions confined to the surroundings of star-forming galaxies. From a comprehensive treatment of blowout we show that SN by themselves fail by more than one order of magnitude to distribute the products of stellar nucleosynthesis over volumes large enough to pollute the whole IGM to the metallicity levels observed. Thus, an additional (but as yet unknown) physical mechanism must be invoked to mix the metals on scales comparable to the mean distance between the galaxies that are most efficient pollutants. From this simple hypothesis we derive a number of testable predictions for the evolution of the IGM metallicity. Specifically, we find that: (i) the fraction of metals ejected over the star-formation history of the Universe is about 50 per cent at     that is, approximately half of the metals today are found in the IGM; (ii) if the ejected metals were homogeneously mixed with the baryons in the Universe, the average IGM metallicity would be     at     However, due to spatial inhomogeneities, the mean of the distribution of metallicities in the diffusive zones has a wide (more than 2 orders of magnitude) spread around this value; (iii) if metals become more uniformly distributed at     as assumed, at     the metallicity of the IGM is narrowly confined within the range     Finally, we point out that our results can account for the observed metal content of the intracluster medium.     

Evidence for short-lived oscillations in the biological records from the sediments of Lago Albano (Central Italy) spanning the period ca. 28 to 17 k yr BP

We report the results of analyses of pigments (derived from algae and photosynthetic bacteria), diatoms and invertebrate fossil remains (ostracods, cladocerans, chironomids) in two late Pleistocene sediment cores from Lago Albano, a crater lake in Central Italy. The record contains evidence for oscillations in lake biota throughout the period ca. 28 to 17 k yr BP. The earliest of these are contained in the basal 3.5 m of light olive-gray and yellowish-gray spotted muds sampled in core PALB 94-1E from 70 m water depth. The later oscillations are best represented in the more extended sediment sequence recovered from a second core site, PALB 94-6B, in 30 m water depth. The sediments at site 1E, containing the earlier oscillations (ca. 28-24 k yr BP), predate any sedimentation at the shallower site, from which we infer an initially low lake level rising to permit sediment accumulation at site 6B from ca. 24 k yr onwards. At site 6B, massive silts rich in moss remains are interbedded with laminated silts and carbonates. These sediments span the period ca. 24 to 17 k yr and are interpreted as representing, respectively, times of shallow water alternating with higher lake stands, when the lake was stratified and bottom water was stagnant. A range of mutually independent chronological constraints on the frequency and duration of the oscillations recorded in the lake biota indicate that they were aperiodic and occurred on millennial to century timescales. We interpret them as responses to climate forcing through its impact on lake levels and changing aquatic productivity. The time span they occupy, their frequency and their duration suggest that at least some of these changes may parallel both the Dansgaard-Oeschger events recorded in Greenland Ice Cores and the contemporary oscillations in North Atlantic circulation documented in marine sediment cores.     

On the seismic performance of straight integral abutment bridges: From advanced numerical modelling to a practice-oriented analysis method

The seismic performance of integral abutment bridges (IABs) is affected by the interaction with the surrounding soil, and specifically by the development of interaction forces in the embankment-abutment and soil-piles systems. In principle, these effects could be evaluated by means of highly demanding numerical computations that, however, can be carried out only for detailed studies of specific cases. By contrast, a low-demanding analysis method is needed for a design-oriented assessment of the longitudinal seismic performance of IABs. To this purpose, the present paper describes a design technique in which the frequency- and amplitude-dependency of the soil-structure interaction is modelled in a simplified manner. Specifically, the method consists of a time-domain analysis of a simplified soil-bridge model, in which soil-structure interaction is simulated by means of distributed nonlinear springs connecting a free-field ground response analysis model to the structural system. The results of this simplified method are validated against the results of advanced numerical analyses, considering different seismic scenarios. In its present state of development, the proposed simplified nonlinear model can be used for an efficient evaluation of the longitudinal response of straight IABs and can constitute a starting point for a prospective generalisation to three-dimensional response.     

Watershed and ocean controls of salt marsh extent and resilience

The formation and evolution of tidal platforms are controlled by the feedbacks between hydrodynamics, geomorphology, vegetation, and sediment transport. Previous work mainly addresses dynamics at the scale of individual marsh platforms. Here, we develop a process-based model to investigate salt marsh depositional/erosional dynamics and resilience to environmental change at the scale of tidal basins. We evaluate how inputs of water and sediment from river and ocean sources interact, how losses of sediment to the ocean depend on this interaction, and how erosional/depositional dynamics are coupled to these exchanges. Model experiments consider a wide range of watershed, basin, and oceanic characteristics, represented by river discharge and suspended sediment concentration, basin dimensions, tidal range, and ocean sediment concentration. In some scenarios, the vertical accretion of a tidal flat can be greater than the rate of sea level rise. Under these conditions, vertical depositional dynamics can lead to transitions between tidal flat and salt marsh equilibrium states. This type of transition occurs much more rapidly than transitions occurring through horizontal marsh expansion or retreat. In addition, our analyses reveal that river inputs can affect the existence and extent of marsh/tidal flat equilibria by both directly providing suspended sediment (favoring marshes) and by modulating water exchanges with the ocean, thereby indirectly affecting the ocean sediment input to the system (favoring either marshes or tidal flats depending on the ratio of the river and ocean water inputs and their sediment concentrations). The model proposed has the goal of clarifying the roles of the main dynamic processes at play, rather than of predicting the evolution of a particular tidal system. Our model results most directly reflect micro- and meso-tidal environments but also have implications for macro-tidal settings. The model-based analyses presented extend our theoretical understanding of marsh dynamics to a greater range of intertidal environments. © 2020 John Wiley & Sons, Ltd.