Geochemical Assessment of a Subtropical Reservoir: A Case Study in Curitiba,Southern Brazil

Suspended particles and dissolved substances in water provide reactive surfaces, influence metabolic activity and contribute to the net sediment deposition. It therefore plays an important part in the ecology and quality of the water mass. The water quality in reservoirs is crucial and it is naturally maintained by flushing and sedimentation, which continuously remove phosphorus from the water. In some reservoirs, however, these removal processes are countered by recycling of ions which could play a key role to start and/or maintain the eutrophic state. The combination of macro‐, trace‐ and microanalysis techniques can be useful to trace pollution sources through a chemical fingerprint, whether be during an acute environmental disaster or a long‐term release of pollutants. The water quality and total metal content of reservoir sediments were assessed in a reservoir, situated in the capital of the Paraná State, in the South‐Eastern part of Brazil. The goal of this paper was to determine the metal presence in the sediment and metal and ionic speciation in the Green River reservoir water. Water and bed sediment samples, collected from various sites during 2008 and 2009, were investigated using XRF, ICP‐OES, ICP‐MS, XRD and zeta potential measurements. Based on the results, the heavy metal concentration and chemical composition of the suspended matter in the water samples, as well as the sediment's chemical composition will be discussed.     

A strategy for frequency spectra of quaternary climate records

The paleoclimatic variability at frequencies ranging from 10^–4 cycle per year (cpy) to 10^–5 cpy is investigated using a set of four deep-sea cores from the Atlantic, Pacific and Indian Oceans. Dominant features are the presence of orbital frequencies corresponding to mean periods of 117.7, 43.6, 24.9 and 19.3 kyr. These are statistically significant according to such advanced spectral tools as Blackman-Tukey, maximum entropy and the highly efficient Thomson technique. However, the main purpose of this paper is methodological, describing the statistical analyses of time series with modern methods in order to stress their relative power, advantages and disadvantages. The more advanced statistical methods confirm the coincidence of the dominant periods in the deep sea cores and those in the astronomical elements, including combination tones. Three frequency bands of high paleoclimatic variability centred at 15.4, 13 and 10.8 kyr are indeed also detected. These two last periods are very close to those predicted by the climatic non-linear model of Ghil and Le Treut and found by Pestiaux et al. and Yiou et al.     

Scattered PKKP: Further evidence for scattering at a rough core-mantle boundary

PKKP signals from Novaya Zemlya recorded at LASA at distances around 60° show consistent anomalies in both slowness and azimuth. The observed anomaly suggests that the signal is a BC branch arrival, although the arrival time corresponds to the DF branch. The BC branch, however, does not extend back to this distance. The azimuth of approach is in the range 229–245°, instead of the expected 186°. These anomalies are associated only with PKKP; analysis of the core phases PKiKP and P′P′ (BC) from the same events show that they arrived at LASA with the appropriate slownesses and azimuths.The PKKP signals can be interpreted as “scattered” PKKP; the scattering occurs on underside reflection at the core-mantle boundary and is probably caused by topographic irregularities on the boundary itself. The calculated scattering region has a surface projection at about 60°S, 134°E, which is outside the diametral plane through source and receiver, and about 21° from the expected PKKP reflection point at 76°S, 95°E.Both the “direct” and “scattered” arms of the PKKP signal have a PK path close to that of the “C” end of the BC branch. The unexpectedly large amplitude of the arrival suggests that there may be a focusing of energy at C, which would indicate a change in velocity gradient just above the inner core boundary. The observations nevertheless require, on the scattering interpretation, lateral variations in the topography of the core-mantle boundary and a region of relatively large topography responsible for the anomalous PKKP observations.     

Similarity studies of entrainment in convective mixed layers

A similarity study of entrainment at the top of convectively driven mixed layer is presented. The similarity framework is used for a comparison between various parameterized models of mixed-layer growth rate and between closely related models for the ratio of heat fluxes at ground and inversion levels. These various models are also tested, in dimensionless form, against data from laboratory, field experiments and numerical higher-order-modeling of the convective layer. It is concluded that a rather accurate prediction of mixed-layer growth can be achieved with the simple constant flux ratio model, but that more refined studies of entrainment are required to account for the decrease of the heat flux ratio with increasing convective intensity.List of acronyms CRPE Centre de Recherches en Physique de l'Environnement, Issy-les-Moulineaux, France - EERM Etablissement d'Etudes et de Recherches Météorologiques, Boulogne, France - INRA Institut National de la Recherche Agronomique, Versailles, France - LAMP Laboratoire Associé de Météorologie Physique, Clermont-Ferrand, France - NCAR National Center for Atmospheric Research, Boulder, U.S.A. - NOAA National Oceanic and Atmospheric Administration, Environmental Research Laboratories, Boulder, U.S.A.     

Filter-Based Classification of Training Image Patterns for Spatial Simulation

Multiple-point simulation, as opposed to simulation one point at a time, operates at the pattern level using a priori structural information. To reduce the dimensionality of the space of patterns we propose a multi-point filtersim algorithm that classifies structural patterns using selected filter statistics. The pattern filter statistics are specific linear combinations of pattern pixel values that represent directional mean, gradient, and curvature properties. Simulation proceeds by sampling from pattern classes selected by conditioning data.     

The Necessity of a Multiple-Point Prior Model

Any interpolation, any hand contouring or digital drawing of a map or a numerical model necessarily calls for a prior model of the multiple-point statistics that link together the data to the unsampled nodes, then these unsampled nodes together. That prior model can be implicit, poorly defined as in hand contouring; it can be explicit through an algorithm as in digital mapping. The multiple-point statistics involved go well beyond single-point histogram and two-point covariance models; the challenge is to define algorithms that can control more of such statistics, particularly those that impact most the utilization of the resulting maps beyond their visual appearance. The newly introduced multiple-point simulation (mps) algorithms borrow the high order statistics from a visually and statistically explicit model, a training image. It is shown that mps can simulate realizations with high entropy character as well as traditional Gaussian-based algorithms, while offering the flexibility of considering alternative training images with various levels of low entropy (organized) structures. The impact on flow performance (spatial connectivity) of choosing a wrong training image among many sharing the same histogram and variogram is demonstrated.     

ESR dating of sedimentary quartz: Possibilities and limitations of the single-grain approach

Usually, multiple-grain aliquots are used for electron spin resonance (ESR) dating of sediments. However, this approach excludes the ability of detecting insufficient bleaching, as would be the case when measuring several single aliquots or single grains. In this paper, we present preliminary results of single-grain ESR dating experiments on three different sedimentary deposits (fluvial, fluvio-aeolian and desert aeolian), ranging in age between 100 ka and 2 Ma. Titanium-related impurity centres (Ti–Li and Ti–H) were measured in a Q-band ESR spectrometer for estimating equivalent doses (D_e) of individual quartz grains (0.5–1 mm). Both additive and regenerative dose methods were used. The resulting D_e plots show a large scatter in D_e—from 100 Gy to more than 600 Gy—for the fluvial sample, probably reflecting different bleaching histories of the grains. On the contrary, a clear plateau can be observed in D_e for sands with a strong aeolian component. Preliminary single-grain ESR ages are in relatively good agreement with independent estimates, the best results being obtained for the desert aeolian sample (200 ka). It is concluded that ESR has a promising potential for estimating large naturally accumulated doses of well-bleached sediments. Nevertheless, the method is challenged by several experimental difficulties, such as long measurement times, excessive errors, and presumably a complex interrelationship between Ti–Li and Ti–H components.     

A novel experimental procedure to investigate the biodegradation of NAPL under unsaturated conditions

Soils need to be thoroughly investigated regarding their potential for the natural attenuation of non-aqueous phase liquids (NAPL). Laboratory investigations truly representative of degradation processes in field conditions are difficult to implement for porous media partially saturated with water, NAPL and air. We propose an innovative protocol to investigate degradation processes under steady-state vadose zone conditions. Experiments are carried out in glass columns filled with a sand and, as bacteria source, a soil from a diesel-fuel-polluted site. Water and NAPL (n-hexadecane diluted in heptamethylnonane (HMN)) are added to the porous medium in a two-step procedure using ceramic membranes placed at the bottom of the column. This procedure results, for appropriate experimental conditions, in a uniform distribution of the two fluids (water and NAPL) throughout the column. In a biodegradation experiment non-biodegradable HMN is used to provide NAPL mass, while keeping biodegradable n-hexadecane small enough to monitor its rapid degradation. Biodegradation is followed as a function of time by measuring oxygen consumption, using a respirometer. Degradative activity is controlled by diffusive transfers in the porous network, of oxygen from the gas phase to the water phase and of n-hexadecane from the NAPL phase to the water phase.