Methane-derived carbonate cements in barrier and beach sands of a subtropical delta complex

Highly negative δC¹³ values, ?18 to ? 40%., for carbonate cements found in Recent barrier and beach sands of the Mississippi River Delta complex strongly suggest that considerable carbon is furnished to the CaCO₃ cements by either chemical or biological oxidation of CH₄. These cemented sands are commonly found on beaches of the Chandeleur barrier island chain and other sites along the Louisiana coast where Holocene sands are rapidly transgressing over highly organic marsh deposits. Generation of CH₄ from underlying anoxic marsh sediments, followed by vertical migration and oxidation to CO₂ in the porous overlying sand, appears to be the unique set of conditions regulating this process of carbonate cementation.     

The formation of pyrite from hydrated iron oxide in aqueous solution at 20°C

Experiments are described in which pyrite is synthesized at room temperature and atmospheric pressure from hydrated iron oxides and hydrogen sulphide under conditions similar to those expected in the natural environment. This synthesis differs from earlier work in that oxygen was rigorously excluded from the system and the pH was 5.6. During a later ageing period a reaction appears to take place in which iron monosulphide is converted to pyrite at pH 5.85.

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Zusammenfassung Versuche zur Synthese von Pyrit bei Raumtemperatur unter atmosphärischem Druck, ausgehend von Eisenhydroxiden und Schwefelwasserstoff und somit unter gleichen Verhältnissen, wie in natürlicher Umgebung, werden beschrieben.Die Synthese unterscheidet sich von früheren Arbeiten durch den strengen Ausschluß von Sauerstoff und den pH-Wert von 5.6. In einer darauffolgenden Alterungsperiode scheint eine Reaktion einzusetzen, in der Eisenmonosulfid bei pH 5.85 zu Pyrit umgewandelt wird.

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Published with the approval of the Director; Bureau of Mineral Resources, Geology and Geophysics.     

Tertiary geodynamics of Sakhalin (NW Pacific) from anisotropy of magnetic susceptibility fabrics and paleomagnetic data

Sakhalin has been affected by several phases of Cretaceous and Tertiary deformation due to the complex interaction of plates in the northwest Pacific region. A detailed understanding of the strain is important because it will provide constraints on plate-scale processes that control the formation and deformation of marginal sedimentary basins. Anisotropy of magnetic susceptibility (AMS) data were obtained from fine-grained mudstones and siltstones from 22 localities in Sakhalin in order to provide information concerning tectonic strain. AMS data reliably record ancient strain tensor orientations before significant deformation of the sediments occurred. Paleomagnetically determined vertical-axis rotations of crustal rocks allow rotation of the fabrics back to their original orientation. Results from southwest Sakhalin indicate a N035°E-directed net tectonic transport from the mid-Paleocene to the early Miocene, which is consistent with the present-day relative motion between the Okhotsk Sea and Eurasian plates. Reconstruction of early–late Miocene AMS fabrics in east Sakhalin indicates a tectonic transport direction of N040°E. In west Sakhalin, the transport direction appears to have remained relatively consistent from the Oligocene to the late Miocene, but it has a different attitude of N080°E. This suggests local deflection of the stress and strain fields, which was probably associated with opening of the northern Tatar Strait. A northward-directed tectonic transport is observed in Miocene sediments in southeast Sakhalin, mid-Eocene sediments in east Sakhalin, and in Late Cretaceous rocks of west and northern Sakhalin, which may be associated with northwestward motion and subduction of the Pacific Plate in the Tertiary period. The boundaries of the separate regions defined by the AMS data are consistent with present-day plate models and, therefore, provide meaningful constraints on the tectonic evolution of Sakhalin.     

Limnology of Two Antarctic Epishelf Lakes and their Potential to Record Periods of Ice Shelf Loss

George VI Ice Shelf is the largest ice shelf on the western side of the Antarctic Peninsula and its northern margin marks the southern most latitudinal limit of recent ice shelf retreat. As part of a project to reconstruct the long-term (Holocene) history of George VI Ice Shelf we studied two epishelf lakes impounded by the ice shelf at Ablation Point, on the east coast of Alexander Island. These lakes, Moutonnée and Ablation, are stratified water bodies with a lower marine layer and an upper freshwater layer. To determine if their sediment records could be used to detect past changes in the presence or absence of the ice shelf it was necessary to describe their present-day limnology and sedimentology. We measured water column chemistry and sampled the water column and sediments of the lakes along vertical and horizontal transects. We analysed these samples for diatoms, stable isotopes (δ¹⁸O, δ²H, δ¹³C_DIC, δ¹³C_org), geochemistry (TOC, TN, C/N ratios) and physical sedimentology (grain-size). This was supplemented by chemical and biological reference data from the catchments. Results showed that the water columns of both lakes are nutrient limited and deficient in phytoplankton. Benthic productivity is low and decreases with depth. Comparison of water column chemistry with an earlier survey shows a net increase in the thickness of the freshwater layer in Moutonnée Lake between 1973 and 2001, which could indicate that George VI Ice Shelf has thinned during this period. However, a similar trend was not observed in Ablation Lake (5 km to the north) and an alternative explanation is that the changes are a seasonal phenomena. Data from the surface sediment transects identified a number of proxies that respond to the present day stratification of the water column including diatom species composition, stable isotopes and geochemistry, particularly in Moutonnée Lake. Collectively these data have been used to develop a conceptual model for determining past ice shelf configuration in epishelf lakes. Specifically, periods of past ice shelf loss, and the removal of the ice dam, would see the present stratified epishelf lake replaced by a marine embayment. It is suggested that this change would leave a clear signature in the lake sediment record, notably the deposition of an exclusively marine biological assemblage, increased ice rafted debris and δ¹³C_org values that are indicative of marine derived organic matter. These authors contributed equally to this work     

Application of the Spatially Smoothed Seismicity and Monte Carlo Methods to Estimate the Seismic Hazard of Eritrea and the Surrounding Region

The region of interest is characterized by incomplete data sets and little information about the tectonic features. Therefore, two methodologies for estimating seismic hazard were used in order to elucidate the robustness of the results: the method of spatially smoothed seismicity introduced by Frankel (1995) and later extended by Lapajne et al. (1997) and a Monte Carlo approach presented by Ebel and Kafka (1999). In the first method, fault-rupture oriented elliptical Gaussian smoothing was performed to estimate future activity rates along the causative structures. Peak ground accelerations were computed for a grid size of 15 km × 415 km assuming the centre of the grids as epicentres, from which the seismic hazard map was produced. The attenuation relationship by Ambraseys et al. (1996) was found suitable for the region under study. PGA values for 10% probability of exceedence in 50 years (return period of 475 years) were computed for each model and a combined seismic hazard map was produced by subjectively assigning weights to each of these models. A worst-case map is also obtained by picking the highest value at each grid point from values of the four hazard maps. The Monte Carlo method is used to estimate seismic hazard, for comparison to the results from our previous approach. Results obtained from both methods are comparable except values in the first set of maps estimate greater hazard in areas of low seismicity. Both maps indicate a higher hazard along the main tectonic features of the east African and Red Sea rift systems. Within Eritrea, the highest PGA exceeded a value 25% of g, located north of Red Sea port of Massawa. In areas around the capital, Asmara, PGA values exceed 10% of g.     

Lithospheric structure of the Tornquist Zone resolved by nonlinear P and S teleseismic tomography along the TOR array

The main aim of the TOR project is to study the lithospheric–asthenospheric boundary structure under the Sorgenfrei–Tornquist Zone, across northern Germany, Denmark and southern Sweden. Relative arrival-time residuals of teleseismic P and S phases from 51 earthquakes, recorded by 150 seismic stations along the TOR array, were used to delineate the transition zone in the studied area. The effects of crustal structures were investigated by correcting the teleseismic residuals for travel-time variations in the crust based on a 3D crustal model derived from other data. The inversion was carried out for S phases. The results were then compared with the corresponding P-wave models. As expected, the derived models show that the relatively old and cold Baltic Shield has higher velocity at depth than the younger lithosphere farther South. The models show two sharp and distinct increases in depth to velocities which are low compared to our reference model, as we move from South to North. The location and sharpness of these boundaries suggests that the features resolved are, at least partially, compositional in origin, presumably related to mantle depletion. A sharp and steep subcrustal boundary is found roughly coincident with the southern edge of Sweden. This is below where the edge of the Baltic Shield is usually placed, based on surface geological evidence (the Sorgenfrei–Tornquist Zone). Another less significant transition is recognised more or less beneath the Elbe-lineament. Relatively high d(V_p / V_s) ratios under the central part of the profile (Denmark) indicate relatively low S-velocity in an area where a gravity high supports the hypothesis of extensive mafic intrusions.     

Physics of the Omori law: Inferences from interevent time distributions and pore pressure diffusion modeling

Empirical laws and statistics of earthquakes are valuable as a basis for a better understanding of the earthquake cycle. In this paper we focus on the postseismic phase and the physics of aftershock sequences. Using interevent time distributions for a catalogue of Icelandic seismicity, we infer that the parameter C₂ in the Omori law, often considered to represent incomplete detection of aftershocks, is at least in part related to the physics of the earthquake process. We investigate the role of postseismic pore pressure diffusion after two Icelandic earthquakes on the rate of aftershocks and what we can infer about the physical meaning of C₂ from the diffusion process. Using the Mohr–Coulomb failure criterion we obtain a rate of triggered points in our diffusion model that agrees with the modified Omori law, with a value of C₂ that is consistent with data. Our pore pressure diffusion model suggests that C₂ is related to the process of reducing high pore pressure gradients existing across a fault zone at short times after a main shock.