Characterization of dissolved organic matter fluorescence in the South Atlantic Bight with use of PARAFAC model: Interannual variability

Systematic water sampling for characterization of chromophoric dissolved organic matter (CDOM) in the coastal South Atlantic Bight, was conducted as part of the long term Coastal Ocean Research and Monitoring Program (CORMP). Water samples were collected during a 3.5 year period, from October 2001 until March 2005, in the vicinity of the Cape Fear River (CFR) outlet and in adjacent Onslow Bay (OB). During this study there were two divergent hydrological and meteorological conditions in the CFR drainage area: a severe drought in 2002, followed by the very wet year of 2003. CDOM was characterized optically by the absorption coefficient at 350 nm, the spectral slope coefficient (S), and by Excitation Emission Matrix (EEM) fluorescence. Parallel Factor Analysis (PARAFAC) was used to assess CDOM composition from EEM spectra and six components were identified: three terrestrial humic-like components, one marine humic-like component and two protein-like components. Terrestrial humic-like components contributed most to dissolved organic matter (DOM) fluorescence in the low salinity plume of the CFR. The contribution of terrestrial humic-like components to DOM fluorescence in OB was much smaller than in the CFR plume area. Protein-like components contributed significantly to DOM fluorescence in the coastal ocean of OB and they dominated DOM fluorescence in the Gulf Stream waters. Hydrological conditions during the observation period significantly impacted both concentration and composition of CDOM found in the estuary and coastal ocean. In the CFR plume, there was an order of magnitude difference in CDOM absorption and fluorescence intensity between samples collected during the drought compared to the wet period. During the drought, CDOM in the CFR plume was composed of equal proportions of terrestrial humic-like components (ca. 60% of the total fluorescence intensity) with a significant contribution of proteinaceous substances (ca. 20% of the total fluorescence). During high river flow, CDOM was composed mostly of humic substances (nearly 75% of total fluorescence) with minor contributions by proteinaceous substances. The impact of changes in fresh water discharge patterns on CDOM concentration and composition was also observed in OB, though to a lesser degree.     

Biogeochemical characterization of particulate organic matter from a coastal hydrothermal vent zone in the Aegean Sea

Three particle interceptor traps were moored from June to September 1996 along the SE coast of Milos Island (Aegean Sea), in an area known for its extensive seabed geothermal activity. The settling particles collected differed between sites not only in quantity but also in their geochemical composition. In the area directly influenced by warm water vents, the vertical flux of particulate material was almost one order of magnitude higher than that observed at the reference sites 6.5 km away from the vents, with a higher contribution of biogenic material in the former. The neutral lipid fractions exhibited a significant zooplankton biomarker signature (e.g. cholesterol and wax esters), followed by those of microalgal and terrigenous remains. The biogeochemical cycle of sterols included the formation of steroidal ketones, thiols and stanols, the latter two particularly associated with the venting activity. Moreover, the aliphatic and aromatic hydrocarbons in the particles from the venting area reflected a locally enhanced maturity of the organic matter. Although part of the material collected in the traps may have been exported in the vent waters, the higher fluxes observed in the vicinity of the hydrothermal plumes are mainly the result of an assemblage of zooplankton which, in turn, may contribute significantly to the sedimentation, through fast sinking faecal pellets, of the petrogenic hydrocarbons possibly generated in the vents.     

The impact of discharges from seafood processing on southeastern estuaries

A study to determine the impact of seafood packing and processing effluents discharged to southeastern estuarine waters was conducted in July and August of 1979. The environmental impact of current seafood processing wastes on Georgia’s estuaries appears to be minimal when compared with the natural organic load. One large estuary demonstrated a high residual capacity to receive processing effluents without significant change. The BOD load from shrimp thawing, peeling, sorting, and cleaning operations at a large seafood processing plant was shown to be equivalent to the organic material generated by a 302 m² plot (57 ft×57 ft) of salt marsh. NH₄?N levels were greater than, but the same order of magnitude as, natural runoff from marsh land.     

Comparison of linear and nonlinear dimension reduction techniques for automated process monitoring of a decentralized wastewater treatment facility

Multivariate statistical methods for online process monitoring have been widely applied to chemical, biological, and engineered systems. While methods based on principal component analysis (PCA) are popular, more recently kernel PCA (KPCA) and locally linear embedding (LLE) have been utilized to better model nonlinear process data. Additionally, various forms of dynamic and adaptive monitoring schemes have been proposed to address time-varying features in these processes. In this analysis, we extend a common simulation study in order to account for autocorrelation and nonstationarity in process data and comprehensively compare the monitoring performances of static, dynamic, adaptive, and adaptive–dynamic versions of PCA, KPCA, and LLE. Furthermore, we evaluate a nonparametric method to set thresholds for monitoring statistics and compare results with the standard parametric approaches. We then apply these methods to real-world data collected from a decentralized wastewater treatment system during normal and abnormal operations. From the simulation study, adaptive–dynamic versions of all three methods generally improve results when the process is autocorrelated and nonstationary. In the case study, adaptive–dynamic versions of PCA, KPCA, and LLE all flag a strong system fault, but nonparametric thresholds considerably reduce the number of false alarms for all three methods under normal operating conditions.     

Basin‐scale predictive models of alluvial architecture: Constraints from the Palaeocene–Eocene,Bighorn Basin,Wyoming, USA

Basin‐scale models are required to interpret ancient continental sedimentary successions, and reduce uncertainty in assessing geological resources in basins. Recently, modern studies show distributive fluvial systems to comprise a substantial proportion of modern sedimentary basins, but their role in ancient basin fills has yet to be quantitatively documented at the basin scale. This study analysed key fluvial characteristics to construct a detailed basin‐wide model of the Palaeogene Fort Union and Willwood formations (Bighorn Basin, Wyoming), using observations from modern studies, and ancient system scale studies of distributive fluvial systems, to guide interpretations. Mapping showed these formations to be highly heterogeneous with channel‐body proportion (from 12 to 81%) and geometry types (large amalgamated bodies to isolated channels), grain size (silt to conglomerate), average channel‐body thickness (4 to 20 m) and average storey thickness (3 to 10 m) varying significantly across the basin. Distributive fluvial systems in the form of alluvial and fluvial fans in transverse configurations were recognized as well as a wide axial system, with heterogeneity in the formations being closely aligned to these interpretations. Furthermore, numerous individual depositional systems were identified within the formations (Beartooth Absaroka, Washakie, Owl Creek and axial). Predicted downstream distributive fluvial system trends (i.e. downstream decrease in channel proportion, size and grain size) were identified in the Beartooth, Absaroka and Owl Creek systems. However, predicted trends were not identified in the Washakie system where intrabasinal thrusting disturbed the sequence. Importantly, a wide axial fluvial system was identified, where reverse downstream distributive fluvial system trends were present, interpreted to be the result of the input of transverse systems of variable size. This study provides a new level of detail in the application of basin‐scale models, demonstrating their usefulness in trying to understand and predict alluvial architecture distribution and heterogeneity, with important implications for economic resources and palaeogeographic reconstructions.     

Multi‐proxy constraints on the significance of covariant δ13C values in carbonate and organic carbon during the early Mississippian

This study investigates the covariation between carbonate and organic δ¹³C values in a proximal to distal transect of four outcrops in the Madison Limestone in the Western United States Rockies, combined with δ³⁴S values of carbonate associated sulphate, the concentration of acid‐insoluble material and measurements of total organic carbon. These new geochemical datasets not only allow for an evaluation of carbon isotope covariance during one of the largest perturbations to the global carbon cycle over the past 550 Myr, but also constrain the cause of the excursion in carbonate δ¹³C values. The results support the hypothesis that a period of anoxia did not play a role in generating the positive carbonate δ¹³C values, but rather favour interpretations by previous workers that the proliferation of land plants destabilized the Carboniferous carbon cycle, setting the stage for a significant change in the carbonate δ¹³C values of contemporaneous marine carbonates. These results also demonstrate that one of the largest perturbations to the global carbon cycle did not produce synchronous variations in carbonate and organic δ¹³C values, emphasizing the importance of local depositional controls on carbon isotope covariance in the geological record in both modern and ancient environments.     

Regional and local controls on the spatial distribution of bedrock reaches in the Upper Guadalupe River, Texas

While studies on gravel mantled and mixed alluvial bedrock rivers have increased in recent decades, few field studies have focused on spatial distributions of bedrock and alluvial reaches and differences between reach types. The objective of this work is to identify the spatial distribution of alluvial and bedrock reaches in the Upper Guadalupe River. We compare reach length, channel and floodplain width, sinuosity, bar length and spacing, bar surface grain size, and slope in alluvial and bedrock reaches to identify whether major differences exist between channel reach types. We find that local disturbances, interaction of the channel and valley sides, variation in lithology, and regional structural control contribute to the distribution of bedrock reaches in the largely alluvial channel. Alluvial and bedrock channel reaches in the Upper Guadalupe River are similar, particularly with respect to the distribution of gravel bars, surface grain size distributions of bars, and channel slope and width. Our observations suggest that the fluvial system has adjusted to changes in base level associated with the Balcones Escarpment Fault Zone by phased incision into alluvial sediment and the underlying bedrock, essentially shifting from a fully alluvial river to a mixed alluvial bedrock river.