Activity-composition relations in the system CaCO3-MgCO3 predicted from static structure energy calculations and Monte Carlo simulations

Thermodynamic mixing properties and subsolidus phase relations of the rhombohedral carbonate system, (1 − x) · CaCO₃ − x · MgCO₃, were modelled in the temperature range of 623-2023 K with static structure energy calculations based on well-parameterised empirical interatomic potentials. Relaxed static structure energies of a large set of randomly varied structures in a 4 × 4 × 1 supercell of calcite (a = 19.952 Å, c = 17.061 Å) were calculated with the General Utility Lattice Program (GULP). These energies were cluster expanded in a basis set of 12 pair-wise effective interactions. Temperature-dependent enthalpies of mixing were calculated by the Monte Carlo method. Free energies of mixing were obtained by thermodynamic integration of the Monte Carlo results. The calculated phase diagram is in good agreement with experimental phase boundaries.     

Trends and low frequency variability of extra-tropical cyclone activity in the ensemble of twentieth century reanalysis

An objective cyclone tracking algorithm is applied to twentieth century reanalysis (20CR) 6-hourly mean sea level pressure fields for the period 1871–2010 to infer historical trends and variability in extra-tropical cyclone activity. The tracking algorithm is applied both to the ensemble-mean analyses and to each of the 56 ensemble members individually. The ensemble-mean analyses are found to be unsuitable for accurately determining cyclone statistics. However, pooled cyclone statistics obtained by averaging statistics from individual members generally agree well with statistics from the NCEP-NCAR reanalyses for 1951–2010, although 20CR shows somewhat weaker cyclone activity over land and stronger activity over oceans. Both reanalyses show similar cyclone trend patterns in the northern hemisphere (NH) over 1951–2010. Homogenized pooled cyclone statistics are analyzed for trends and variability. Conclusions account for identified inhomogeneities, which occurred before 1949 in the NH and between 1951 and 1985 in the southern hemisphere (SH). Cyclone activity is estimated to have increased slightly over the period 1871–2010 in the NH. More substantial increases are seen in the SH. Notable regional and seasonal variations in trends are evident, as is profound decadal or longer scale variability. For example, the NH increases occur mainly in the mid-latitude Pacific and high-latitude Atlantic regions. For the North Atlantic-European region and southeast Australia, the 20CR cyclone trends are in agreement with trends in geostrophic wind extremes derived from in-situ surface pressure observations. European trends are also consistent with trends in the mean duration of wet spells derived from rain gauge data in Europe.     

Hot springs,thermal springs and warm springs. What's the difference?

Springs rising with water temperatures well above ambient have a fascination borne out of curiosity, spectacle and sometimes a need to understand the origins of the groundwater and its composition. While hot springs bring to mind boiling waters, explosive emissions of steam and volcanism, many exit temperatures are far lower than the boiling point of water, yet remain elevated above the mean air temperature or those of other springs in the surrounding country. This has led to some confusion in naming these springs. When does a hot spring cease to be hot?     

Wolf-Rayet stars

This paper reviews the current status of knowledge regarding the basic physical and chemical properties of Wolf-Rayet stars; their overall mass loss and stellar wind characteristics and current ideas about their evolutionary status. WR stars are believed to be the evolved descendents of massive O-type stars, in which extensive mass loss reveals successive stages of nuclear processed material: WN stars the products of interior CNO-cycle hydrogen burning, and WC and WO stars the products of interior helium burning. Recent stellar evolution models, particularly those incorporating internal mixing, predict results which are in good accord with the different chemical compositions observationally inferred for WN, WC and WO stars. WR stars exhibit the highest levels of mass loss amongst earlytype stars: mass loss rates, typically, lie in the range [1–10]×10⁻⁵ M _⊙yr⁻¹. Radiation pressure-driven winds incorporating multi-scattering in high ionisation-stratified winds may cause these levels, but additional mechanisms may also be needed.     

Fall days of the SNC meteorites: Evidence for an SNC meteoroid stream,and a common site of origin

Abstract— Four of the SNC meteorites of putative Martian origin are falls. Two of these fell on October 3: Chassigny in 1815 and Zagami in 1962. The probability of this coincidence arising from random fall days is approximately 1 in 60. If this coincidence is not the result of chance, it suggests that some of the SNC meteorites are derived from a meteoroid stream. In that Chassigny and Zagami span nearly the full range of SNC lithologies and histories, the coincidence of fall days is consistent with suggestions that all of the SNCs came from a single site (impact crater) on their parent planet.     

The Balderton Sand and Gravel: Pre-Ipswichian cold stage fluvial deposits near Lincoln,England

The Balderton Terrace marks a former course of the River Trent between Newark and the Lincoln Gap. The principal deposit, the Balderton Sand and Gravel, is interpreted as a braided river sediment. Ice wedge casts truncated by intraformational erosion surfaces at many levels indicate syndepositional permafrost. Remnant cover deposits overlying the Balderton Sand and Gravel include the partly aeolian Whisby Sand. Locally, both the upper part of the Balderton Sand and Gravel and the cover deposits exhibit features indicative of temperate climate pedogenesis. All these deposits are affected by subsequent cryoturbation. On the basis of these features and the geomorphological and topographical relationship to other terrace deposits of the area, the Balderton Sand and Gravel and Whisby Sand are regarded as post-Hoxnian and pre-lpswichian, i.e. Wolstonian. Electron spin resonance age determinations for fossil elephant teeth and amino acid analyses on molluscs from the Balderton Sand and Gravel suggest correlation with Oxygen Isotope Stage 6. The Balderton Sand and Gravel has yielded a cold-climate mammalian fauna dominated by woolly mammoth and woolly rhinoceros, though rarer species suggest periods of milder climate. Silts from channels near the base of the deposit have produced pollen, mollusc, ostracod and beetle assemblages also indicating a cold climate.     

Lunar properties from transient and steady magnetic field measurements

The electrical conductivity of the lunar interior has been determined from magnetic field step transients measured on the lunar dark side. The simplest model which best fits the data is a spherically symmetric three layer model having a nonconducting outer crust of radial thickness 0.03R _moon; an intermediate layer of thicknessR0.37R _moon, with electrical conductivity ₁ 3.5 × 10^–4 mhos/m; and an inner core of radiusR ₂ 0.6R _m with conductivity ₂ 10^–2 mhos/m. Temperatures calculated from these conductivities in the three regions for an example of an olivine Moon are as follows: crust, < 440 K; intermediate layer, 890 K; and core, 1240 K. The whole-moon relative permeability has been calculated from the measurements to be/ ₀ = 1.03 ± 0.13. Remanent magnetic fields at the landing sites are 38 ± 3 at Apollo 12, 43 ± 6 and 103 ± 5 at two Apollo 14 sites separated by 1.1 km, and 6 ± 4 at the Apollo 15 site. Measurements show that the 38 remanent field at the Apollo 12 site is compressed to 54 by a solar wind pressure increase of 7 × 10^–8 dynes/cm².National Research Council Postdoctoral Associate.     

A simple method for calculating growth rates of petroleum hydrocarbon plumes

Consumption of aquifer Fe(III) during biodegradation of ground water contaminants may result in expansion of a contaminant plume, changing the outlook for monitored natural attenuation. Data from two research sites contaminated with petroleum hydrocarbons show that toluene and xylenes degrade under methanogenic conditions, but the benzene and ethylbenzene plumes grow as aquifer Fe(III) supplies are depleted. By considering a one-dimensional reaction front in a constant unidirectional flow field, it is possible to derive a simple expression for the growth rate of a benzene plume. The method balances the mass flux of benzene with the Fe(III) content of the aquifer, assuming that the biodegradation reaction is instantaneous. The resulting expression shows that the benzene front migration is retarded relative to the ground water velocity by a factor that depends on the concentrations of hydrocarbon and bioavailable Fe(III). The method provides good agreement with benzene plumes at a crude oil study site in Minnesota and a gasoline site in South Carolina. Compared to the South Carolina site, the Minnesota site has 25% higher benzene flux but eight times the Fe(III), leading to about one-sixth the expansion rate. Although it was developed for benzene, toluene, ethylbenzene, and xylenes, the growth-rate estimation method may have applications to contaminant plumes from other persistent contaminant sources.