Geospatial Analysis of Space–Time Patterning of ENSO Forced Daily Precipitation Distributions in the Gulf of Mexico

The Gulf of Mexico experiences significant changes in the distribution of daily precipitation totals that are linked to the El Niño–Southern Oscillation (ENSO). This research uses geospatial techniques to examine distribution patterns of ENSO-related precipitation. Kolmogorov–Smirnov test results comparing daily rainfall distributions for El Niño and La Niña are mapped at a 1° × 1° latitude/longitude resolution, and hotspot analysis using local Moran's I is performed to identify spatial clustering. Results indicate that ENSO-forced spatial and temporal variation in daily precipitation distributions influence large areas of the Gulf of Mexico region from August through January.     

Global music city: knowledge and geographical proximity in London's recorded music industry

Drawing from debates in economic geography on relational and organisational proximity as a substitute for geographical proximity, the paper explores characteristics of knowledge transfer in London's recorded music industry through an examination of organisational connections on local and global scales. The paper demonstrates that knowledge transfer within the industry occurs simultaneously across multiple geographical scales, with certain organisational connections facilitating the transfer of tacit knowledge across organisational boundaries. However, the paper argues that these connections do not offer the same scope for trust as is afforded by frequent face-to-face contact and therefore offer only a partial substitute for geographical proximity.     

Petrology of Martian meteorite Northwest Africa 998

Abstract— Nakhlite Northwest Africa (NWA) 998 is an augite-rich cumulate igneous rock with mineral compositions and oxygen isotopic composition consistent with an origin on Mars. This 456-gram, partially fusion-crusted meteorite consists of (by volume) ∼75% augite (core composition Wo₃₉En₃₉Fs₂₂), ∼9% olivine (Fo₃₅), ∼7% plagioclase (Ab₆₁An₃₅) as anhedra among augite and olivine, ∼3.5% low-calcium pyroxenes (pigeonite and orthopyroxene) replacing or forming overgrowths on olivine and augite, ∼1% titanomagnetite, and other phases including potassium feldspar, apatite, pyrrhotite, chalcopyrite, ilmenite, and fine-grained mesostasis material. Minor secondary alteration materials include “iddingsite” associated with olivine (probably Martian), calcite crack fillings, and iron oxide/hydroxide staining (both probably terrestrial). Shock effects are limited to minor cataclasis and twinning in augite. In comparison to other nakhlites, NWA 998 contains more low-calcium pyroxenes and its plagioclase crystals are blockier. The large size of the intercumulus feldspars and the chemical homogeneity of the olivine imply relatively slow cooling and chemical equilibration in the late- and post-igneous history of this specimen, and mineral thermometers give subsolidus temperatures near 730 °C. Oxidation state was near that of the QFM buffer, from about QFM-2 in earliest crystallization to near QFM in late crystallization, and to about QFM + 1.5 in some magmatic inclusions. The replacement or overgrowth of olivine by pigeonite and orthopyroxene (with or without titanomagnetite), and the marginal replacement of augite by pigeonite, are interpreted to result from late-stage reactions with residual melts (consistent with experimental phase equilibrium relationships). Apatite is concentrated in planar zones separating apatite-free domains, which suggests that residual magma (rich in P and REE) was concentrated in planar (fracture?) zones and possibly migrated through them. Loss of late magma through these zones is consistent with the low bulk REE content of NWA 998 compared with the calculated REE content of its parent magma.     

Criteria for aging and sexing New Zealand oystercatchers

Criteria based on external characters are presented for aging and sexing the three New Zealand species of oystercatcher, Haematopus ostralegus finschi Martens, 1897, H. unicolor Forster, 1844, and H. chathamensis Hartert, 1927. Four classes are discerned: juveniles have brown dorsal plumage, a brown iris and grey legs; second‐year birds have an orange‐red iris and pale pink legs; sub‐adults have a dull red iris and pink legs; adults have a scarlet iris and bright coral pink legs. The three species can be sexed by discriminant analysis of the sexually dimorphic characters bill length (x ₁), bill length:bill depth (x ₂) and bill length:bill width (x ₃). Linear functions and discriminating values for predicting sex are :

H. ostralegus finschi 0.46x ₁+3.15x ₂+2.94x ₃, 77.41;

H. unicolor 0.12x₁+6.52x₂+2.85x₃ , 58.05; and

H. chathamemis ‐0.93x ₁+1.50x ₂+7.48x ₃, ‐20.86.

Similarly, the sexes of immature H. ostralegus finschi can be predicted :

juveniles 0.73x₁+ 5.76x ₂ + 3.10 _x3 116.57;

second‐year birds 0.57x ₁+5.12x ₂+ 0.98x ₈, 84.84; and

sub‐adults 0.55x ₁+1.88x ₂+ 1.08x ₃, 65.90.’     

Water demand management in Yemen and Jordan: addressing power and interests

This paper investigates the extent to which entrenched interests of stakeholder groups both maintain water use practice, and may be confronted. The focus is on the agricultural sectors of Yemen and Jordan, where water resource policymakers face resistance in their attempts to reduce water use to environmentally sustainable levels through implementation of water demand management (WDM) activities. Some farmers in both countries that have invested in irrigated production of high-value crops (such as qat and bananas) benefit from a political economy that encourages increased rather than reduced water consumption. The resultant over-exploitation of water resources affects groups in unequal measures. Stakeholder analysis demonstrates that the more ‘powerful’ groups (chiefly the large landowners and the political elites, as well as the ministries of irrigation over which they exert influence) are generally opposed to reform in water use, while the proponents of WDM (e.g. water resource managers, environmental ministries and NGOs, and the international donor community) are found to have minimal influence over water use policy and decisionmaking. Efforts and ideas attempted by this latter group to challenge the status quo are classified here as either (a) influencing or (b) challenging the power asymmetry, and the merits and limits of both approaches are discussed. The interpretation of evidence suggests current practice is likely to endure, but may be more effectively challenged if a long-term approach is taken with an awareness of opportunities generated by windows of opportunity and the participation of ‘overlap groups’.     

Mechanism and kinetics of pseudomorphic mineral replacement reactions: A case study of the replacement of pentlandite by violarite

Although pseudomorphic mineral replacement reactions are common in all geological environments, and have long been considered important to many geological processes such as metamorphism, metasomatism, diagenesis, and chemical weathering, their mechanisms are still not well known. We present a combined textural and kinetic study of the replacement of pentlandite, (Fe,Ni)₉S₈, by violarite (NiFe)₃S₄, and describe the mechanisms and kinetic behavior of this reaction by considering the role of the fluid phase, the causes of coupling between pentlandite dissolution and violarite precipitation, the rate-limiting steps controlling the kinetic behavior, and the origin of the length scale of the features preserved during pseudomorphism.The experiments were conducted under mild hydrothermal conditions (80-210 °C, vapor saturated pressures). Reaction kinetics shows a complex behavior depending on various physical and chemical parameters including temperature, pH, concentrations of various reaction species, solid-weight-to-fluid-volume-ratio and specific surface area. The rate of replacement (i) increases with temperature from 80 to 125 °C, then decreases as temperature further increases to 210 °C, (ii) first increases then decreases with decreasing pH from pH 6 to 1, (iii) increases with increasing concentration of oxidants such as O_2(aq), H₂O₂, and KMnO₄, but decreases with increasing concentration of Ni²⁺ and Fe³⁺, and with increasing solid-weight-to-fluid-volume ratio, (iv) increases linearly with the specific surface area. This kinetic behavior as well as the resulting textures revealed a coupled dissolution-reprecipitation reaction mechanism.Nanometer-scale pseudomorphic replacement, through which the crystallographic orientation of pentlandite is inherited by violarite, occurs only between 1 < pH < 6, and spatial coupling between dissolution and reprecipitation is controlled by the local solution chemistry as well as by epitaxial nucleation mediated by the pentlandite substrate. The kinetic results show that pentlandite dissolution is rate-limiting under mild acidic to neutral conditions (1 < pH < 6), while violarite precipitation is rate-limiting under strong acidic conditions (pH 1). The difference in rate-limiting steps influences the coupling mechanism and causes the different degrees of preservation (length scale of pseudomorphism) and different morphologies observed at high and low pHs: pentlandite dissolution being rate-limiting results in nanoscale coupling between dissolution and precipitation and thus nanoscale pseudomorphism (length scale <20 nm), in which the replacement precisely preserves the morphology and internal details, resembling remarkably the natural pentlandite/violarite assemblages. In contrast, violarite precipitation being rate-limiting results in microscale pseudomorphism (length scale ∼10 μm): the morphology of the pentlandite grains is only roughly preserved and internal details are not preserved.This case study illustrates some general principles of replacement reactions proceeding via the coupled dissolution-reprecipitation mechanism: (i) primary mineral dissolution needs to be rate-limiting compared to the secondary mineral precipitation in order to achieve a high degree pseudomorphic replacement; (ii) the effects of solution composition on reaction kinetics can be qualitatively rationalized by considering the rate-limiting step reaction.     

Runoff generation in zero-order precambrian shield catchments: The stormflow response of a heterogeneous landscape

Hydrometric and isotopic (oxygen-18) observations were used to delineate the runoff processes operating in several headwater catchments on the Precambrian Shield of Canada. The catchments comprise patches of conifer forest situated on thin soils among areas of lichen-covered granitic bedrock. Horton overland flow occurred from the lichen-bedrock areas in all precipitation events that exceeded 4–6 mm. Runoff from the forest stands occurred mainly as subsurface stormflow, but in some instances saturation overland flow was observed. The occurrence of saturation overland flow was controlled by the topography of the bedrock beneath the forest soils. The area contributing runoff and the pathway by which water was conveyed to the catchment outflow switched from the open lichen-bedrock areas producing overland flow on the rising limb of the storm hydrograph to the forest stands contributing subsurface stormflow on the recession limb of the hydrograph. The areal extent and position of the landscape units in the basin were important to the rate and magnitude of stormflow production. Runoff was generated from the catchments only during and immediately after snowmelt and/or rainfall events. The catchments were dry and/or frozen for about 70% of the year.