Arctic rockwall retreat rates estimated using laboratory‐calibrated ERT measurements of talus cones in Longyeardalen,Svalbard

Holocene rockwall retreat rates quantify integral values of rock slope erosion and talus cone evolution. Here we investigate Holocene rockwall retreat of exposed arctic sandstone cliffs in Longyeardalen, central Svalbard and apply laboratory‐calibrated electrical resistivity tomography (ERT) to determine talus sediment thickness. Temperature–resistivity functions of two sandstone samples are measured in the laboratory and compared with borehole temperatures from the talus slope. The resistivity of the higher and lower‐porosity sandstone at relevant borehole permafrost temperatures defines a threshold range that accounts for the lithological variability of the dominant bedrock and debris material. This helps to estimate the depth of the transition from higher resistivities of ice‐rich debris to lower resistivities of frozen bedrock in the six ERT transects. The depth of the debris–bedrock transition in ERT profiles is confirmed by a pronounced apparent resistivity gradient in the raw data plotted versus depth of investigation. High‐resolution LiDAR‐scanning and ERT subsurface information were collated in a GIS to interpolate the bedrock surface and to calculate the sediment volume of the talus cones. The resulting volumes were referenced to source areas to calculate rockwall retreat rates. The rock mass strength was estimated for the source areas. The integral rockwall retreat rates range from 0.33 to 1.96 mm yr^–1, and are among the highest rockwall retreat rates measured in arctic environments, presumably modulated by harsh environmental forcing on a porous sandstone rock cliff with a comparatively low rock mass strength. Here, we show the potential of laboratory‐calibrated ERT to provide accurate estimates of rockwall retreat rates even in ice‐rich permafrost talus slopes. Copyright © 2012 John Wiley & Sons, Ltd.     

Field-aligned currents in the winter and summer hemispheres caused by IMF <Emphasis Type="Italic">By</Emphasis>

Structures controlled by the IMF By sign and season of the year have been detected based on the decomposition of field-aligned current maps constructed using magnetic field measurements on polar low-orbiting satellites. It has been indicated that field-aligned currents have identical structures, composed of the main polar circular current and the return current at the polar cap dayside boundary, at any By sign in the summer hemisphere. Two different types of structures are implemented under winter conditions depending on the By sign. For the northern winter, it is the polar circular current and the return current at the polar cap nightside boundary at By < 0; current sheets are strongly stretched along latitudes below 80° MLat, and only small part of the current is in the noon sector of the polar cap. For the summer winter, the corresponding structures are implemented at opposite By signs. The intensities of the field-aligned currents, originating as a result of the interhemispheric asymmetry and flowing along closed geomagnetic field lines near the polar cap boundary, have been estimated. The maximum of the interhemispheric current density is 0.25 μA m⁻² in the summer and 0.1 μA m⁻² in the winter; the total current is 5 × 10⁵ and 5 × 10⁴ A, respectively.     

Expression of the Toarcian Oceanic Anoxic Event: New insights from a Swiss transect

A sedimentological, biostratigraphical and geochemical (stable isotopes and Rock‐Eval parameters) analysis was performed on four Swiss successions, in order to examine the expression of the Toarcian Oceanic Anoxic Event along a north–south transect, from the Jura through the Alpine Tethys (Sub‐Briançonnais and Lombardian basins). The locations were selected to represent a range of palaeoceanographic positions from an epicontinental sea to a more open marine setting. The Toarcian Oceanic Anoxic Event was recognized by the presence of the characteristic negative carbon‐isotope excursion in carbonate (ca 2 to 4‰) and organic matter (ca 4 to 5‰) at the base of the falciferum ammonite Zone (NJT6 nannofossil Zone). The sedimentary expression of the Toarcian Oceanic Anoxic Event varies along the transect from laminated mudstone rich in total organic carbon (≤11 wt.%) in the Jura, to thin‐bedded marl (≤5 wt.% total organic carbon) in the Sub‐Briançonnais Basin and to hemipelagic reddish marly limestone (total organic carbon <0·05 wt.%) in equivalent levels from the Lombardian Basin. The carbon‐isotope excursion is thus independent of facies and palaeoceanographic position. The low nannofossil abundance and the peak in Calyculaceae in the Jura and the Sub‐Briançonnais Basin indicate low salinity surface waters and stratified water masses in general. Sedimentological observations (for example, obliquely‐bedded laminae and homogeneous mud layers containing rip‐up clasts) indicate the presence of dynamic conditions, suggesting that water mass stratification was episodically disrupted during the Toarcian Oceanic Anoxic Event. The proposed correlation highlights a stratigraphic gap and/or condensed interval between the Pliensbachian–Toarcian boundary and the Toarcian Oceanic Anoxic Event interval (most of the tenuicostatum ammonite Zone is missing), which is also observed in coeval European sections and points to the influence of sea‐level change and current dynamics. This transect shows that the sedimentary expression of the Toarcian Oceanic Anoxic Event is not uniform across the Alpine Tethys, supporting the importance of local conditions in determining how this event is recorded across different palaeoceanographic settings.     

A mechanism for the production of hydroxyl radical at surface defect sites on pyrite

A previous contribution from our laboratory reported the formation of hydrogen peroxide (H₂O₂) upon addition of pyrite (FeS₂) to O₂-free water. It was hypothesized that a reaction between adsorbed H₂O and Fe(III), at a sulfur-deficient defect site, on the pyrite surface generates an adsorbed hydroxyl radical (OH^•).

     

Characterization of the structure and the surface reactivity of a marcasite thin film

A thin film of marcasite, FeS₂, was synthesized under vacuum and its structure and reactivity under oxidizing conditions was investigated by means of diffraction and surface analytical techniques, respectively. Synthesis of the film was carried out by codepositing Fe and S₂ onto a Ta support. The thickness of the film could be varied from approximately 10 Å to 1 μm. High-resolution S 2p synchrotron-based photoemission showed S22−, with undetectable amounts of S²⁻ impurity that is typically present on natural sample surfaces. X-ray diffraction of the micron-thick films showed that the film crystallized in the marcasite phase of FeS₂. Atomic force microscopy indicated that the thin film had a nanometer-scale roughness suggesting the film contained defects such as steps and kinks. X-ray photoelectron spectroscopy studies found the thin marcasite film to be more reactive than natural pyrite (the most ubiquitous FeS₂ dimorph) after exposure to a gaseous O₂/H₂O environment on the basis of the amount of sulfate formation. Likely the oxidation of marcasite was dominated by its short-range order (e.g., presence of steps), because the density of nonstoichiometric defect sites (e.g., S²⁻) was low as assessed by photoelectron spectroscopy.     

Chemical fractionations in meteorites—XI. C2 chondrites

Six C2M chondrites (Boriskino, Cold Bokkeveld, Erakot, Essebi, Haripura and Santa Cruz) and the C2R chondrite Al Rais were analyzed by radiochemical neutron activation analysis for Ag, Au, Bi, Cd, Cs, Ge, In, Ir, Ni, Os, Pd, Rb, Re, Sb, Se, Sn, Te, Tl, U, and Zn. Abundances (relative to Cl chondrites) show a systematic dependence on volatility, apparently reflecting volatile loss during formation of chondrules and other high-T components. Elements of nebular condensation temperature (T_c) > 1200 K are undepleted, those of T_c < 700 K are depleted by a constant factor (0.482 ± 0.049 for C2M's) and elements of intermediate volatility are depleted by intermediate factors. The abundances do not “tend to fall monotonically as a function of [T_c],” as previously claimed by Wai and Wasson (1977) for a more restricted temperature range. For meteorites that have suffered little aqueous alteration (Mighei, Murchison, Murray), the mean abundance of volatiles agrees with the matrix content, but for the more altered meteorites, matrix contents are 20–30% higher. Only a few meteorites deviate appreciably from the mean abundance pattern. Al Rais, a C2R chondrite with a significant metal content, is systematically lower in 12 volatiles, but is enriched in Ni and Pd. Haripura and Erakot are enriched in Bi and Tl, possibly from the late condensate, mysterite.     

Storage, migration, and eruption of magma at Kilauea volcano, Hawaii, 1971–1972

The magmatic plumbing system of Kilauea Volcano consists of a broad region of magma generation in the upper mantle, a steeply inclined zone through which magma rises to an intravolcano reservoir located about 2 to 6 km beneath the summit of the volcano, and a network of conduits that carry magma from this reservoir to sites of eruption within the caldera and along east and southwest rift zones. The functioning of most parts of this system was illustrated by activity during 1971 and 1972. When a 29-month-long eruption at Mauna Ulu on the east rift zone began to wane in 1971, the summit region of the volcano began to inflate rapidly; apparently, blockage of the feeder conduit to Mauna Ulu diverted a continuing supply of mantle-derived magma to prolonged storage in the summit reservoir. Rapid inflation of the summit area persisted at a nearly constant rate from June 1971 to February 1972, when a conduit to Mauna Ulu was reopened. The cadence of inflation was twice interrupted briefly, first by a 10-hour eruption in Kilauea Caldera on 14 August, and later by an eruption that began in the caldera and migrated 12 km down the southwest rift zone between 24 and 29 September. The 14 August and 24–29 September eruptions added about 10⁷ m³ and 8 × 10⁶ m³, respectively, of new lava to the surface of Kilauea. These volumes, combined with the volume increase represented by inflation of the volcanic edifice itself, account for an approximately 6 × 10⁶ m³/month rate of growth between June 1971 and January 1972, essentially the same rate at which mantle-derived magma was supplied to Kilauea between 1952 and the end of the Mauna Ulu eruption in 1971.The August and September 1971 lavas are tholeiitic basalts of similar major-element chemical composition. The compositions can be reproduced by mixing various proportions of chemically distinct variants of lava that erupted during the preceding activity at Mauna Ulu. Thus, part of the magma rising from the mantle to feed the Mauna Ulu eruption may have been stored within the summit reservoir from 4 to 20 months before it was erupted in the summit caldera and along the southwest rift zone in August and September.The September 1971 activity was only the fourth eruption on the southwest rift zone during Kilauea's 200 years of recorded history, in contrast to more than 20 eruptions on the east rift zone. Order-of-magnitude differences in topographic and geophysical expression indicate greatly disparate eruption rates for far more than historic time and thus suggest a considerably larger dike swarm within the east rift zone than within the southwest rift zone. Characteristics of the historic eruptions on the southwest rift zone suggest that magma may be fed directly from active lava lakes in Kilauea Caldera or from shallow cupolas at the top of the summit magma reservoir, through fissures that propagate down rift from the caldera itself at the onset of eruption. Moreover, emplacement of this magma into the southwest rift zone may be possible only when compressive stress across the rift is reduced by some unknown critical amount owing either to seaward displacement of the terrane south-southeast of the rift zone or to a deflated condition of Mauna Loa Volcano adjacent to the northwest, or both. The former condition arises when the forceful emplacement of dikes into the east rift zone wedges the south flank of Kilauea seaward. Such controls on the potential for eruption along the southwest rift zone may be related to the topographic and geophysical constrasts between the two rift zones.