The effect of methanogenesis on the geochemistry of low temperature water–Fe0–basalt reactions

Hydrogen gas produced in the subsurface from the hydration of mafic rocks is known to be a major energy source for chemolithotrophic life in extreme environments such as hydrothermal vents. The possibility that in situ anaerobic microorganisms present in the deep subsurface are sustained by low temperature H₂-generating water–rock reactions taking place around them is being investigated. Whether the growth and activity of H₂-utilizing microbes directly influences aqueous geochemistry, rates of mineral dissolution, and the chemical composition of the alteration products is also being quantitatively evaluated.To explore how microorganisms are affected by water–rock reactions, and how their activity may in turn affect reaction progress, laboratory experiments have been conducted to monitor the growth of a methanogenic Archaea in the presence of H_2(g) produced from low temperature water–Fe⁰–basalt reactions. In these systems, the conversion of Fe(II) to Fe(III) and subsequent hydrolysis of water is responsible for the production of H_2(g). To characterize key components of the geochemical system, time series measurements of H₂ and CH₄ gas concentrations, Fe and Si aqueous concentrations, and spatially resolved synchrotron-based analyses of microscale Fe distribution and speciation were conducted. Culture experiments were compared with an abiotic control to document changes in the geochemistry both in the presence and absence of the methanogen.In the control abiotic batch experiment, H₂ was continuously produced, until the headspace became saturated, while in the biotic experiments, microbial consumption of H₂ for methanogenesis draws H₂ down and produces CH₄. Purging the headspace gas reinitiates H₂ and CH₄ production in abiotic and culture experiments, respectively. Mass balance analysis of the amount of CH₄ produced suggests that the total H₂ production in microbial experiments does not exceed the abiotic experiment. Soluble Si concentrations, while buffered to relatively constant values, were higher in culture experiments than the abiotic control.Iron_(aq) concentrations appear to respond to perturbations of H₂ and CH₄ gas concentrations in both culture experiments and the abiotic control. A pulse of Fe preceded the rise in either H₂ or CH₄ production, and as the gas concentrations increased the Fe_(aq) decreased. Iron-bearing mineral assemblages change with increasing reaction time and mineral assemblages vary between culture experiments and the abiotic control. These geochemical trends suggest that there are different reaction paths between the culture experiments and the abiotic control.The hydration of mafic rocks is a common geologic reaction and one that has taken place on Earth for the majority of its history and is postulated to occur on Mars. These reactions are important because of their effect on the rheology and geochemistry of the ocean crust. While most often studied at temperatures of ～250 °C, this work suggests that at lower temperatures microorganisms may have a profound effect on what has long been thought to be solely an abiotic reaction, and may produce diagnostic mineral assemblages that will be preserved in the geological record.     

Simulations of the 2004 lava flow at Etna volcano using the magflow cellular automata model

Since the mechanical properties of lava change over time, lava flows represent a challenge for physically based modeling. This change is ruled by a temperature field which needs to be modeled. MAGFLOW Cellular Automata (CA) model was developed for physically based simulations of lava flows in near real-time. We introduced an algorithm based on the Monte Carlo approach to solve the anisotropic problem. As transition rule of CA, a steady-state solution of Navier-Stokes equations was adopted in the case of isothermal laminar pressure-driven Bingham fluid. For the cooling mechanism, we consider only the radiative heat loss from the surface of the flow and the change of the temperature due to mixture of lavas between cells with different temperatures. The model was applied to reproduce a real lava flow that occurred during the 2004–2005 Etna eruption. The simulations were computed using three different empirical relationships between viscosity and temperature.     

Microtextural constraints on the interplay between fluid–rock reactions and deformation

Schists from two mylonitic localities in the footwall of a low-angle normal fault in the eastern Alps record different degrees of embrittlement during exhumation, depending on the extent to which fluid–rock reactions proceeded. At one site, graphitic schists preserve textural evidence for two metamorphic reactions that modified and/or fluid volume: (1) reaction between graphite and aqueous fluid that increased without changing the molar amount of fluid, and (2) replacement of titanite by rutile, calcite, and quartz. The latter reaction involved net consumption of increasingly CO₂-rich fluid. Areas where the first reaction proceeded are associated with abundant Mode I microcracks. Fluid inclusion arrays within the microcracks show that increased from ∼0.1 to 0.6 during decompression from 4.75 to 2 kbar at a reference temperature of 500°C. Titanite consumption is most pronounced within transgranular Mode I microcracks, but microcracks do not crosscut products of this reaction; fluid consumption during reaction was coeval with the end of microcracking, at least on a local scale. At the other site, graphitic schists lack small-scale Mode I cracks as well as evidence for graphite consumption during decompression. SEM imaging shows that graphite is anhedral and pitted at the first site, but occurs in clusters of euhedral grains at the second site. Mass balance calculations demonstrate that rocks with partially consumed graphite were infiltrated by an externally derived, H₂O-rich fluid that drove subsequent graphite-fluid reaction. Evidence for similar fluid infiltration is absent at the second site. Variations in the degree of reaction progress indicate that fluid pathways and deformation style were heterogeneous on the scale of millimeters to kilometers during exhumation from mid-crustal depths.     

Petrological evidence for stepwise accretion of metamorphic soles during subduction infancy (Semail ophiolite,Oman and UAE)

Metamorphic soles are tectonic slices welded beneath most large‐scale ophiolites. These slivers of oceanic crust metamorphosed up to granulite facies conditions are interpreted as forming during the first million years of intraoceanic subduction following heat transfer from the incipient mantle wedge towards the top of the subducting plate. This study reappraises the formation of metamorphic soles through detailed field and petrological work on three key sections from the Semail ophiolite (Oman and United Arab Emirates). Based on thermobarometry and thermodynamic modelling, it is shown that metamorphic soles do not record a continuous temperature gradient, as expected from simple heating by the upper plate or by shear heating as proposed in previous studies. The upper, high‐T metamorphic sole is subdivided in at least two units, testifying to the stepwise formation, detachment and accretion of successive slices from the down‐going slab to the mylonitic base of the ophiolite. Estimated peak pressure–temperature conditions through the metamorphic sole, from top to bottom, are 850°C and 1 GPa, 725°C and 0.8 GPa and 530°C and 0.5 GPa. These estimates appear constant within each unit but differing between units by 100–200°C and ~0.2 GPa. Despite being separated by hundreds of kilometres below the Semail ophiolite and having contrasting locations with respect to the ridge axis position, metamorphic soles show no evidence for significant petrological variations along strike. These constraints allow us to refine the tectonic–petrological model for the genesis of metamorphic soles, formed via the stepwise stacking of several homogeneous slivers of oceanic crust and its sedimentary cover. Metamorphic soles result not so much from downward heat transfer (ironing effect) as from progressive metamorphism during strain localization and cooling of the plate interface. The successive thrusts originate from rheological contrasts between the sole, initially the top of the subducting slab, and the peridotite above as the plate interface progressively cools. These findings have implications for the thickness, the scale and the coupling state at the plate interface during the early history of subduction/obduction systems.     

Typecasting prospective Au-bearing sedimentary lithologies using sedimentary geochemistry and Nd isotopes in poorly exposed Proterozoic basins of the Tanami region, Northern Australia

The development of a regional stratigraphy in Palaeoproterozoic basins within the Tanami region, Northern Australia has been hindered by the difficulty of discriminating sedimentary units and facies across this isolated and poorly exposed basin. A regional stratigraphy is important as it provides constraints on sedimentary basin evolution and assists in gold exploration. Gold is known to be more concentrated in certain rock formations. Based on Nd isotopes and whole rock geochemistry, five main sedimentary events have been identified in the Tanami region. Some sedimentary units were derived from homogeneous local sources, whereas others contain evidence of a well-mixed fine-grained remote provenance. Within the basins, major gold-bearing lithologies are characterised by mafic source indicators: (1) high Cr/Th ratios; (2) low Th/Sc ratios; (3) low (La/Yb)_PAAS ratios relative to Post-Archaean Average Shale (Taylor and McLennan 1985); (4) Eu anomalies equal to ∼1; and (5) distinctive ranges in initial ε _Nd values. Potential future exploration target areas have been identified in the Tanami region at the Cashel and Sunline prospects using these geochemical parameters.     

Precursors and fluid flows in the case of the 1996, ML = 5.2 Saint-Paul-de-Fenouillet earthquake (Pyrenees,France): A complete pre-, co- and post-seismic scenario

Earthquake precursors are now regularly described but often detected only after a major or moderate seismic event. Presence and influence of fluids in the seismogenic processes are often observed at the time of earthquake studies. Even today, the understanding of the physical processes involved in the source region is a real challenge for seismic hazard assessment. Here, the aftershock sequence of the M_L = 5.2, 1996 Saint-Paul-de-Fenouillet (Eastern Pyrenees, France) earthquake is first re-examined with P-wave cross-correlations, resulting in extracting three multiplets and in determining new locations. Multiplets and spatio-temporal distribution analysis of the aftershocks allow for quantifying the hydraulic diffusivity D at a maximum value of 5 m²/s and the permeability K at 10^? 15 m² in the upper Pyrenean crust. Second, a model is established in order to explain the hydrogeochemical transient anomalies, which occurred during the 15 day-period preceding the 1996 earthquake. These anomalies consist on a temporal and spatial sequence of gas emissions in the epicentral area and on chloride and lead concentration variations in a bottled mineral water 25 km north to the main shock epicenter. The proposed model processed in a standard elastic half-space, consists of creep on a low-angle crustal normal-fault, generating volumetric strain field changes over a distance of 25 km from the epicentral area. This model is able to constrain not only the mechanisms and the locations of the geochemical anomalies, but also their timing and probable casual links to the triggering of the impending major event. Also, the active extension proposed here is compatible with seismological observations in the Pyrenees. Thus, the possibility of such creep, which can be considered as a slow-slip event, is discussed in the Pyrenean tectonic and geological context. The model is discussed and compared to previous proposed models on precursor processes of earthquakes, especially concerning the preparation zone concept. Finally, a complete seismic scenario over the period beginning 15 days before the quake and ending 5 days after is proposed and discussed.     

Multi-tracer tests to evaluate the hydraulic setting of a complex aquifer system (Brévilles spring catchment, France)

For good management of groundwater resources, and to comply with European and national regulations, a detailed understanding of an aquifer’s hydraulic setting is required. In order to better characterize a sandy aquifer that is affected by diffuse pollution (Brévilles spring catchment, Val d’Oise, France), and to quantify the transfer time in the saturated zone, a multi-tracer test involving a new technique, the ‘finite volume point dilution method’, has been performed in natural flow conditions. In November 2005, injections of four different tracers took place in four piezometers involving different locations and depths in the aquifer. Recovery of the tracers was observed at two different places near the aquifer outlet. A particularly long and unusual monitoring exercise (27 months) demonstrated the existence of several different velocities within the sandy layer, which seems to be linked to the decrease of hydraulic conductivity with depth. The new insight and parameter quantification brought by interpretation of these tests contribute to a better characterization of the saturated zone. The particularly long-term monitoring exercise also gives new information to understand and forecast the trend and persistence of groundwater contamination by pesticides in the catchment.     

Application of MODIS satellite products to the air pollution research in Beijing

The direct correlation between NASA MODIS aerosol optical depth (AOD) products and the air pollution index (API) in Beijing was found relatively low based on the long-term comparison analysis. The correlation improved to some extent after taking account of the seasonal variation of scale height and the vertical distribution of aerosols. The correlation coefficient further improved significantly after considering the influencing factor of Relative Humidity (RH). This study concluded that satellite remote-sensing could serve as an efficient tool for monitoring the spatial distribution of particulate pollutants on the ground-level, as long as corrections have been made in the two aforementioned processes. Taking advantage of the MODIS information, we analyzed a pollution episode occurring in October 2004 in Beijing. It indicated that satellite remote-sensing could describe the formation process of the ground-level pollution episode in detail, and showed that regional transport and the topography were crucial factors to air quality in Beijing. The annual averaged distribution in the urban area of Beijing and its surroundings could be also obtained from the high-resolution retrieval results, implicating that high-resolution satellite remote-sensing might be potential in monitoring the source distribution of particulate pollutants.